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Environmental Science and Pollution... Jun 2024Phenanthrene (PHE) is a polycyclic aromatic hydrocarbon categorized as a high priority organic pollutant being toxic for the ecosystem and human health, and its sorption...
Phenanthrene (PHE) is a polycyclic aromatic hydrocarbon categorized as a high priority organic pollutant being toxic for the ecosystem and human health, and its sorption on natural organic or inorganic substances seems a well-promising method for its removal from water streams. The goals of the present work are (i) to assess the capacity of low-cost adsorbents fabricated by treating coffee wastes and diatomaceous earth to remove PHE from water; (ii) to elucidate the role of the pore structure on PHE sorption dynamics; and (iii) to assess the potential to regenerate adsorbents loaded with PHE, by using the novel technology of cold atmospheric plasma (CAP). Diatomaceous earth (DE) and DE pre-treated with sodium hydroxide (NaOH) or phosphoric acid (HPO) were chosen as inorganic adsorbents. Coffee waste (CW) and activated carbons (AC) produced from its pyrolysis at 800 °C (CWAC), either untreated (CWAC-800) or pre-treated with NaOH (CWAC-NaOH-800) and HPO (CWAC-HPO-800), were chosen as organic adsorbents. The adsorbents were characterized with nitrogen adsorption-desorption isotherms, attenuated total reflectance-Fourier transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy, and mercury intrusion porosimetry. Based on the PHE sorption capacity and pore structure/surface characteristics, the CWAC-NaOH-800 was chosen as the most efficient adsorbent for further equilibrium and kinetic sorption studies. The multi-compartment model was used to describe the PHE sorption dynamics in CWAC-NaOH-800 by accounting for the pore/surface diffusion and instantaneous sorption. The CWAC-NaOH-800 exhibited remarkable values for (i) the specific surface area (S = 676.5 m/g) and meso- and micro-pore volume determined by nitrogen sorption (V = 0.415 cm/g); (ii) the macro- and meso-pore volume determined by mercury intrusion porosimetry (V = 3.134 cm/g); and (iii) the maximum PHE sorption capacity (q = 142 mg/g). The percentage of adsorbent recovery after its regeneration with CAP was found to be ~ 35%. From the simulation of sorption dynamics, it was found that at early times, the sorption kinetics is governed by the film diffusion towards the external surface of grains, but at late times, most of the adsorbed mass is transferred primarily to meso-/macro-pores via diffusion, and secondarily to micro-porosity via surface diffusion. Based on the adsorbent characteristics, effect of pH on sorption efficiency, and numerical analysis of sorption dynamics, it was concluded that probably the dominant adsorption mechanism is the π-π interactions between hydrophobic PHE aromatic rings and CWAC-NaOH-800 graphene layers. The high PHE removal efficiency of CWAC-NaOH-800, the successful interpretation of sorption dynamics with the multi-compartment model, and the potential to regenerate PHE-loaded adsorbents with the green and economic technology of CAP motivate a strategy for testing CWACs towards the adsorption of other PAHs, application of adsorbents to real wastewaters, and scaling-up to pilot units.
Topics: Adsorption; Phenanthrenes; Coffee; Diatomaceous Earth; Water Pollutants, Chemical; Plasma Gases
PubMed: 37166734
DOI: 10.1007/s11356-023-27381-8 -
Journal of Economic Entomology Oct 2023Insecticidal grain protectants can provide control of pest insects during grain storage, but studies which directly compare the efficacy of insecticides in rough rice...
Insecticidal grain protectants can provide control of pest insects during grain storage, but studies which directly compare the efficacy of insecticides in rough rice are few. We examined methoprene, deltamethrin, commercial formulations of methoprene + deltamethrin, β-cyfluthrin, and diatomaceous earth applied to rough rice over a 6-month period for control of lesser grain borers, Rhyzopertha dominica (F.) (Coleoptera: Bostrichidae), and rice weevils, Sitophilus oryzae (L.) (Coleoptera: Curculionidae). We found that methoprene, deltamethrin, or a combination of the 2 were the most effective controls of both beetles in 22.7-liter metal containers. Damage mass and beetle mass in methoprene-treated rice were reduced by 38% and 55%, respectively, when compared to the nontreated control. Similarly, the mixture of deltamethrin and methoprene reduced damage mass by 32% and total beetle mass by 45% below that of the nontreated control. Deltamethrin reduced total beetle mass by 38% relative to the nontreated rice. In vial assays, only the combination of deltamethrin and methoprene provided control of R. dominica. Diatomaceous earth had the greatest impact upon S. oryzae, but it did not affect R. dominica. Based on these results, a commercial formulation of deltamethrin and methoprene is likely to provide the best overall control of stored grain beetles, though diatomaceous earth may be effective when use of chemical insecticides is undesirable or when S. oryzae is the sole pest present.
Topics: Animals; Coleoptera; Insecticides; Diatomaceous Earth; Methoprene; Weevils; Edible Grain
PubMed: 37748015
DOI: 10.1093/jee/toad169 -
Materials (Basel, Switzerland) Feb 2023The clarity of the beer is essential to its marketability and good consumer approval. Moreover, the beer filtration aims to remove the unwanted constituents that cause...
The clarity of the beer is essential to its marketability and good consumer approval. Moreover, the beer filtration aims to remove the unwanted constituents that cause beer haze formation. Natural zeolite, an inexpensive and widespread material, was tested as a substitute filter media for diatomaceous earth in removing the haze constituents in beer. The zeolitic tuff samples were collected from two quarries in Northern Romania: Chilioara, in which the zeolitic tuff has a clinoptilolite content of about 65%, and the Valea Pomilor quarry, containing zeolitic tuff with a clinoptilolite content of about 40%. Two-grain sizes, <40 and <100 µm, from each quarry were prepared and thermally treated at 450 °C in order to improve their adsorption properties and remove organic compounds and for physico-chemical characterization. The prepared zeolites were used for beer filtration in different mixtures with commercial filter aids (DIF BO and CBL3) in laboratory-scale experiments, and the filtered beer was characterized in terms of pH, turbidity, color, taste, flavor, and concentrations of the major and trace elements. The results showed that the taste, flavor, and pH of the filtered beer were generally not affected by filtration, while turbidity and color decreased with an increase in the zeolite content used in the filtration. The concentrations of Na and Mg in the beer were not significantly altered by filtration; Ca and K slowly increased, while Cd and Co were below the limits of quantification. Our results show that natural zeolites are promising aids for beer filtration and can be readily substituted for diatomaceous earth without significant changes in brewery industry process equipment and protocols for preparation.
PubMed: 36903029
DOI: 10.3390/ma16051914 -
Pathogens (Basel, Switzerland) May 2023This study determined the efficacy of (Bals. -Criv.) Vuill., (Metchnikoff) Sorokin, and diatomaceous earth mixed with abamectin (DEA) alone and in their combinations...
The Potential of Two Entomopathogenic Fungi and Enhanced Diatomaceous Earth Mixed with Abamectin: A Comprehensive Study on Mortality, Progeny Production, Application Method, and Surface Application against .
This study determined the efficacy of (Bals. -Criv.) Vuill., (Metchnikoff) Sorokin, and diatomaceous earth mixed with abamectin (DEA) alone and in their combinations for the integrated management of larvae and adults of (Herbst) from three field populations of Pakistan (Multan, Rawalpindi, and Rahim Yar Khan) and one laboratory population (Faisalabad). Treatments were applied on three surfaces, namely, viz. steel, concrete, and jute bags, implementing two application methods, dusting and spraying. The combined treatments were more effective in comparison with single treatments for both larvae and adults. Overall, the highest mortality rates were recorded in the Faisalabad population, followed by the Rehaim Yar Khan, Rawalpindi, and Multan populations. Progeny production was suspended 21 days after exposure to the combined treatment of DEA and both fungi in all populations except Rawalpindi. Larvae were found to be more susceptible than adults in all treatments and intervals. Dusting was more efficient than spraying for both larvae and adults and for all the populations studied. The present study provides a wholistic understanding of the impact of different factors on the success of the combined treatments using DEA and entomopathogenic fungi, supporting their use as surface treatments.
PubMed: 37375463
DOI: 10.3390/pathogens12060773 -
Polymers Aug 2022Amorphous diatomite was used as a filler for a thermoplastic polymer of polyamide 11 obtained from natural sources. The diatomite particles of different sizes were...
Amorphous diatomite was used as a filler for a thermoplastic polymer of polyamide 11 obtained from natural sources. The diatomite particles of different sizes were previously fractionated by sedimentation to obtain powders with varying particle size distribution, including powders with or without frustule particles, crushed, uncrushed or agglomerated. Biocomposites containing 2.5, 5, 10 and 20% filler were tested for their mechanical properties, including tensile strength, flexural strength and impact strength. In addition, a particle size analysis (by Dynamic Light Scattering, DLS) was performed and the dispersion of the filler in the polymer matrix (Scanning Electron Microscopy, SEM), thermal parameters (Differential Scanning Calorimetry, DSC, and Dynamic Mechanical Analysis, DMA) were determined. Testing showed that biocomposites modified with diatomaceous earth have a higher mechanical strength than the reference system, especially with larger amounts of the filler (10 and 20%), e.g., the tensile strength of pure PA11 is about 46 MPa, while 20OB and 20OF 47.5 and 47 MPa, respectively, while an increase in max. flexural strength and flexural modulus is also observed compared to pure PA11 by a maximum of 63 and 54%, respectively Diatomaceous earth can be obtained in various ways-it is commercially available or it is possible to breed diatoms in laboratory conditions, while the use of commercially available diatomite, which contains diatoms of different sizes, eliminates the possibility of controlling mechanical parameters by filling biocomposites with a filler with the desired particle size distribution, and diatom breeding is not possible on an industrial scale. Our proposed biocomposite based on fractionated diatomaceous earth using a sedimentation process addresses the current need to produce biocomposite materials from natural sources, and moreover, the nature of the process, due to its simplicity, can be successfully used on an industrial scale.
PubMed: 35956665
DOI: 10.3390/polym14153153 -
Pest Management Science Jun 2024Over the past two decades, bed bugs (Cimex spp.) have resurged as common urban pests around the world. The search for efficient and safe control measures has become a...
BACKGROUND
Over the past two decades, bed bugs (Cimex spp.) have resurged as common urban pests around the world. The search for efficient and safe control measures has become a key interest among researchers, manufacturers, and pest control professionals. In this study, we evaluated and compared the efficacy of steam, diatomaceous earth (DE) dust, and a combination of both against tropical bed bugs (Cimex hemipterus (F.)) under laboratory and field conditions.
RESULTS
In the laboratory study, the mortality of bed bugs after 2 days of exposure to DE dust was 100%. When bed bugs stayed on the surface of an object or in cracks, a brief steam treatment (1 s) caused 100% mortality. However, when bed bugs were hidden under a fabric cover, steam application for 10 s only caused 89 ± 6% mortality. Bed bugs that survived steam treatment exhibited reduced feeding activity. In a 14-week long study, there was no significant difference in the reduction rate of bed bugs between steam treatment and DE dust treatment. A 37-week long control study showed that steam and steam plus DE dust treatments eliminated 97-100% of the infestations.
CONCLUSION
Applying steam and DE dust are effective strategies for eliminating natural tropical bed bug infestations. Continuous follow-up monitoring and treatment until no bed bugs are found are crucial in completely eliminating the infestation of tropical bed bugs. © 2024 Society of Chemical Industry.
PubMed: 38847149
DOI: 10.1002/ps.8227 -
Radiation Protection Dosimetry Dec 2019Diatomaceous earth is found in various locations around the planet. It is caused by the deposited exoskeleton material formed by the death of large concentrated...
Diatomaceous earth is found in various locations around the planet. It is caused by the deposited exoskeleton material formed by the death of large concentrated populations of diatoms. The exoskeleton is effectively pure silicate and as such becomes a prospective material for retrospective dosimetry and dating. This work investigated the thermoluminescence (TL) and optically stimulated luminescence properties of commercially obtained diatomaceous earth. The material was not found to have useful dosimetric properties with conventional TL methodologies but did provide large dose estimates using the Single Aliquot Regeneration technique on some subset samples. These findings for organic silicate did suggest some mechanisms explaining the sensitization process in geological silicate materials utilized in dosimetry and dating. Electron paramagnetic resonance was identified as a potential future method for evaluating this material as it revealed unique signal components not found in igneous or commercially produced silicates.
Topics: Diatomaceous Earth; Electron Spin Resonance Spectroscopy; Materials Testing; Radiation Dosage; Retrospective Studies; Thermoluminescent Dosimetry
PubMed: 30806457
DOI: 10.1093/rpd/ncz013 -
Environmental Science and Pollution... Nov 2022The olive oil industry generates considerable amounts of olive mill wastewater (OMW) which is treated and used in agriculture, energy production, or discharged into...
The olive oil industry generates considerable amounts of olive mill wastewater (OMW) which is treated and used in agriculture, energy production, or discharged into evaporating ponds where OMW contaminated soil (OMWS) is formed. Due to the extremely high phenol content, untreated OMWS is not suitable for plants and soil organisms. This study aimed to determine the adverse effects of OMWS on Enchytraeus albidus and whether the addition of clay and diatomaceous earth can reduce these effects. Without additives, reproduction was reduced up to 35%, with high number of unhatched cocoons, indicated hatching impairment. Furthermore, acetylcholinesterase (AChE) activity decreased significantly at the highest OMWS ratio (40%), as did glutathione-S-transferase (GST) activity at two ratios (40%), indicating neurotoxic effects and oxidative stress. The application of additives (clay and diatomaceous earth) decreased phenol concentration up to 35 and 45%, respectively. Consequently, the number of juveniles increased significantly compared to the control and AChE and GST activities were not affected. However, an increased number of unhatched cocoons and lipid peroxidation were observed after diatomaceous earth treatment, indicating the occurrence of stress. Although additives can bind phenols, neutralize harmful effects and allow the use of OMWS as a fertilizer in agriculture, they should be carefully selected taking into account soil organisms as well. The use of additives to reduce the adverse effects of OMWS can be a turning point in the remediation of olive contaminated soil.
Topics: Animals; Wastewater; Olea; Industrial Waste; Phenol; Diatomaceous Earth; Clay; Acetylcholinesterase; Oligochaeta; Olive Oil; Soil; Phenols; Waste Disposal, Fluid
PubMed: 35761138
DOI: 10.1007/s11356-022-21668-y -
Environmental Science and Pollution... Mar 2023The current study evaluates the efficacy of the entomopathogenic fungus Beauveria bassiana (Balsamo-Crivelli) Vuillemin (Hypocreales: Cordycipitaceae), diatomaceous...
The current study evaluates the efficacy of the entomopathogenic fungus Beauveria bassiana (Balsamo-Crivelli) Vuillemin (Hypocreales: Cordycipitaceae), diatomaceous earth (DE) (Protect-It), and the oxadiazine indoxacarb, at single or combined applications on wheat kernels, for the management of the rusty grain beetle, Cryptolestes ferrugineus (Stephens) (Coleoptera: Laemophloeidae), the red flour beetle, Tribolium castaneum (Herbst) (Coleoptera: Tenebrionidae), the khapra beetle, Trogoderma granarium Everts (Coleoptera: Dermestidae), and the lesser grain borer, Rhyzopertha dominica (F.) (Coleoptera: Bostrychidae). The study was conducted between November 2020 and August 2021 in Faisalabad under a complete randomized block design. The combination of DE + indoxacarb was the most efficient as it caused higher overall mortalities ranging between 59.34 and 100%, and lower overall progeny production ranging between 8.35 and 33.70 individuals per vial, than all other treatments. Beauveria bassiana alone exhibited the lowest mortality rates ranging between 22.33 and 47.76%, and the highest offspring emergence, ranging between 51.33 and 78.55 individuals per vial. Similar pattern was observed when persistence bioassays were conducted. For a period of 120 days, the DE + indoxacarb was the most powerful combination against all tested species, providing overall mortality rates between 17.06 and 63.80%. The overall progeny production was lower for the insect individuals exposed on wheat treated with the DE + indoxacarb combination, ranging between 13.66 and 52.23 individuals per vial, and higher for those exposed to B. bassiana alone, ranging between 44.03 and 107.67 individuals per vial, for the entire duration of storage. However, the efficacy of all treatments decreased gradually during the course of storage. The findings of the current study indicate that the combinations of entomopathogenic fungi, DE, and indoxacarb can be used for the prolonged protection of stored wheat from the tested noxious insect species of stored products. Further research, which will include other inert dusts in combination with entomopathogenic fungi and indoxacarb, may provide additional knowledge towards an effective management of noxious species occurring in storages.
Topics: Animals; Beauveria; Coleoptera; Diatomaceous Earth; Hypocreales; Insecta; Insecticides; Triticum
PubMed: 36640233
DOI: 10.1007/s11356-022-25075-1 -
Toxins Dec 2022Polydopamine (PDA) is a synthetic eumelanin polymer mimicking the biopolymer secreted by mussels to attach to surfaces with a high binding strength. It exhibits unique...
Improving the In Vitro Removal of Indoxyl Sulfate and p-Cresyl Sulfate by Coating Diatomaceous Earth (DE) and Poly-vinyl-pyrrolidone-co-styrene (PVP-co-S) with Polydopamine.
Polydopamine (PDA) is a synthetic eumelanin polymer mimicking the biopolymer secreted by mussels to attach to surfaces with a high binding strength. It exhibits unique adhesive properties and has recently attracted considerable interest as a multifunctional thin film coating. In this study, we demonstrate that a PDA coating on silica- and polymer-based materials improves the entrapment and retention of uremic toxins produced in specific diseases. The low-cost natural nanotextured fossil diatomaceous earth (DE), an abundant source of mesoporous silica, and polyvinylpyrrolidone-co-Styrene (PVP-co-S), a commercial absorbent comprising polymeric particles, were easily coated with a PDA layer by oxidative polymerization of dopamine at mild basic aqueous conditions. An in-depth chemical-physical investigation of both the resulting PDA-coated materials was performed by SEM, AFM, UV-visible, Raman spectroscopy and spectroscopic ellipsometry. Finally, the obtained hybrid systems were successfully tested for the removal of two uremic toxins (indoxyl sulfate and p-cresyl sulfate) directly from patients' sera.
Topics: Humans; Indican; Povidone; Diatomaceous Earth; Sulfates; Uremic Toxins; Polymers; Silicon Dioxide; Polyvinyl Chloride; Styrenes
PubMed: 36548761
DOI: 10.3390/toxins14120864