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Journal of Agricultural and Food... Apr 2022Synthetic pesticides are often associated with issues such as pest resistance, persistent residue, nontarget toxicity, and environmental issues. Therefore, the research... (Review)
Review
Synthetic pesticides are often associated with issues such as pest resistance, persistent residue, nontarget toxicity, and environmental issues. Therefore, the research and development of novel, safe, and effective pesticides has become a focus in pesticide discovery. Monoterpenes are secondary plant metabolites that commonly have multiple action targets and have been used in aromatherapy, alternative medicine, and food industries. Some are highly potent and stereoselective. They can potentially be botanical pesticides and serve as lead candidates for the design and synthesis of new monoterpenoid pesticides for agricultural applications. This article reviews publications and patents found in SciFinder Scholar between 2000 and May 2021 on monoterpenes and mainly focuses on pesticidal activities of frequently studied monoterpenes and their modes of action. The presented information and our views are hopefully useful for the development of monoterpenes as biopesticides and monoterpenoid pesticides.
Topics: Agriculture; Biological Control Agents; Monoterpenes; Pesticides; Plants
PubMed: 35380824
DOI: 10.1021/acs.jafc.2c00635 -
Journal of Insect Science (Online) Nov 2023Pesticide applications are often made as tank mixes containing multiple pesticide products and may include spray adjuvants to enhance pesticidal activities. The primary... (Review)
Review
Pesticide applications are often made as tank mixes containing multiple pesticide products and may include spray adjuvants to enhance pesticidal activities. The primary aim of adjuvant products is to increase the spreading and sticking of spray droplets and to increase the penetration of active ingredients through the cuticles of leaves or targeted pests, which can reduce the amount of active ingredient needed for effective pest control. Adjuvants are made up of compounds drawn from the "inert ingredient" list maintained by EPA but are identified as "principal functioning agents" when used in adjuvant products. These inert compounds do not undergo the same testing and risk assessment process that is required of pesticide active ingredients and generally have no mitigation measures that prevent application onto crops during bloom at times of day when bees are foraging. Honey bees (Apis mellifera;Hymenoptera:Apidae) are at an increased risk of exposure to adjuvant tank mixtures while providing agricultural pollination services. Colony losses attributed to pesticide applications thought to have low risk to honey bees have been reported, highlighting the need to better understand the toxicity of adjuvants included in pesticide tank mixtures. This review summarizes current literature on the risks posed to honey bees by agricultural adjuvants and tank mix combinations of adjuvants with pesticides. Based on the current state of knowledge, we make recommendations to pesticide applicators, product manufacturers, regulatory agencies, and researchers regarding adjuvant toxicity to honey bees with the goal of reducing risks that adjuvants pose to honey bees and other beneficial insects.
Topics: Bees; Animals; Pesticides; Hymenoptera; Agriculture; Risk Assessment; Pollination; Insecticides
PubMed: 38055940
DOI: 10.1093/jisesa/iead100 -
Journal of Environmental Management Nov 2023Clarifying the influences of biochar input on the rhizosphere dissipation and plant absorption of pesticides is a crucial prerequisite for utilizing biochar in the... (Meta-Analysis)
Meta-Analysis Review
Clarifying the influences of biochar input on the rhizosphere dissipation and plant absorption of pesticides is a crucial prerequisite for utilizing biochar in the restoration of pesticide-contaminated soils. Nevertheless, the application of biochar to pesticide-contaminated soils does not always achieve consistent results on the rhizosphere dissipation and plant absorption of pesticides. Under the new situation of vigorously promoting the application of biochar in soil management and carbon sequestration, a timely review is needed to further understand the key factors affecting biochar remediation of pesticide-contaminated soil. In this study, a meta-analysis was conducted utilizing variables from three dimensions of biochar, remediation treatment, and pesticide/plant type. The pesticide residues in soil and the pesticide uptake by plant were used as response variables. Biochar with high adsorption capacity can impede the dissipation of pesticides in soil and mitigate their absorption by plants. The specific surface area of biochar and the type of pesticide are critical factors that affect pesticide residues in soil and plant uptake, respectively. Applying biochar with high adsorption capacity, based on specific dosages and soil characteristics, is recommended for the remediation of continuously cultivated soil contaminated with pesticides. This article aims to provide a valuable reference and understanding for the application of biochar-based soil remediation technology and the treatment of pesticide pollution in soil.
Topics: Pesticides; Pesticide Residues; Rhizosphere; Soil Pollutants; Soil; Charcoal
PubMed: 37385197
DOI: 10.1016/j.jenvman.2023.118518 -
Chemosphere Jan 2022Bee health is declining on a global scale, yet the exact causes and their interactions responsible for the decline remain unknown. To more objectively study bee health,...
Bee health is declining on a global scale, yet the exact causes and their interactions responsible for the decline remain unknown. To more objectively study bee health, recently biomarkers have been proposed as an essential tool, because they can be rapidly quantified and standardized, serving as a comparable measure across bee species and varying environments. Here, we used a systems biology approach to draw associations between endogenous and exogenous chemical profiles, with pesticide exposure, or the abundance of the 21 most common honey bee diseases. From the analysis we identified chemical biomarkers for both pesticide exposure and bee diseases along with the mechanistic biological pathways that may influence disease onset and progression. We found a total of 2352 chemical features, from 30 different hives, sampled from seven different locations. Of these, a total of 1088 significant associations were found that could serve as chemical biomarker profiles for predicting both pesticide exposure and the presence of diseases in a bee colony. In almost all cases we found novel external environmental exposures within the top seven associations with bee diseases and pesticide exposures, with the majority having previously unknown connections to bee health. We highlight the exposure-outcome paradigm and its ability to identify previously uncategorized interactions from different environmental exposures associated with bee diseases, pesticides, mechanisms, and potential synergistic interactions of these that are responsible for honey bee health decline.
Topics: Animals; Bees; Biomarkers; Environmental Exposure; Pesticides
PubMed: 34426277
DOI: 10.1016/j.chemosphere.2021.131948 -
Reviews of Environmental Contamination... 2021The lure of increased productivity and crop yield has caused the imprudent use of pesticides in great quantity that has unfavorably affected environmental health.... (Review)
Review
The lure of increased productivity and crop yield has caused the imprudent use of pesticides in great quantity that has unfavorably affected environmental health. Pesticides are chemicals intended for avoiding, eliminating, and mitigating any pests that affect the crop. Lack of awareness, improper management, and negligent disposal of pesticide containers have led to the permeation of pesticide residues into the food chain and other environmental pathways, leading to environmental degradation. Sufficient steps must be undertaken at various levels to monitor and ensure judicious use of pesticides. Development of prediction models for optimum use of pesticides, pesticide management, and their impact would be of great help in monitoring and controlling the ill effects of excessive use of pesticides. This paper aims to present an exhaustive review of the prediction models developed and modeling strategies used to optimize the use of pesticides.
Topics: Pesticide Residues; Pesticides
PubMed: 33932184
DOI: 10.1007/398_2020_64 -
Archives of Toxicology Feb 2017Endocrine disruptors are chemical substances that can interfere with the endocrine system. They include pesticides, metals, additives or contaminants in food, and...
Endocrine disruptors are chemical substances that can interfere with the endocrine system. They include pesticides, metals, additives or contaminants in food, and personal care products. Pesticides are the only substances intentionally released into our environment to kill living things (herbicides, insecticides, fungicides, rodenticides). There is scientific evidence that exposure to pesticides produces a growing number of human pathological conditions; among these, stillbirth is an emerging issue.
Topics: Endocrine Disruptors; Fungicides, Industrial; Gas Chromatography-Mass Spectrometry; Herbicides; Humans; Insecticides; Pesticide Residues; Pesticides
PubMed: 28032145
DOI: 10.1007/s00204-016-1920-7 -
Journal of Controlled Release :... Jan 2019The incorporation of nanotechnology as a means for nanopesticides is in the early stage of development. The main idea behind this incorporation is to lower the... (Review)
Review
The incorporation of nanotechnology as a means for nanopesticides is in the early stage of development. The main idea behind this incorporation is to lower the indiscriminate use of conventional pesticides to be in line with safe environmental applications. Nanoencapsulated pesticides can provide controlled release kinetics, while efficiently enhancing permeability, stability, and solubility. Nanoencapsulation can enhance the pest-control efficiency over extended durations by preventing the premature degradation of active ingredients (AIs) under harsh environmental conditions. This review is thus organized to critically assess the significant role of nanotechnology for encapsulation of AIs for pesticides. The smart delivery of pesticides is essential to reduce the dosage of AIs with enhanced efficacy and to overcome pesticide loss (e.g., due to leaching and evaporation). The future trends of pesticide nanoformulations including nanomaterials as AIs and nanoemulsions of biopesticides are also explored. This review should thus offer a valuable guide for establishing regulatory frameworks related to field applications of these nano-based pesticides in the near future.
Topics: Agriculture; Animals; Humans; Nanostructures; Pesticides
PubMed: 30552953
DOI: 10.1016/j.jconrel.2018.12.012 -
Biosensors Mar 2018The intensive use of toxic and remanent pesticides in agriculture has prompted research into novel performant, yet cost-effective and fast analytical tools to control... (Review)
Review
The intensive use of toxic and remanent pesticides in agriculture has prompted research into novel performant, yet cost-effective and fast analytical tools to control the pesticide residue levels in the environment and food. In this context, biosensors based on enzyme inhibition have been proposed as adequate analytical devices with the added advantage of using the toxicity of pesticides for detection purposes, being more "biologically relevant" than standard chromatographic methods. This review proposes an overview of recent advances in the development of biosensors exploiting the inhibition of cholinesterases, photosynthetic system II, alkaline phosphatase, cytochrome P450A1, peroxidase, tyrosinase, laccase, urease, and aldehyde dehydrogenase. While various strategies have been employed to detect pesticides from different classes (organophosphates, carbamates, dithiocarbamates, triazines, phenylureas, diazines, or phenols), the number of practical applications and the variety of environmental and food samples tested remains limited. Recent advances focus on enhancing the sensitivity and selectivity by using nanomaterials in the sensor assembly and novel mutant enzymes in array-type sensor formats in combination with chemometric methods for data analysis. The progress in the development of solar cells enriched the possibilities for efficient wiring of photosynthetic enzymes on different surfaces, opening new avenues for development of biosensors for photosynthesis-inhibiting herbicides.
Topics: Biosensing Techniques; Environmental Monitoring; Pesticides
PubMed: 29565810
DOI: 10.3390/bios8020027 -
Zhongguo Zhong Yao Za Zhi = Zhongguo... Mar 2022Lonicera Japonica Flos is the dried bud or nascent flower of Lonicera japonica(Caprifoliaceae). The plant suffers from various diseases and pests in the growth period... (Review)
Review
Lonicera Japonica Flos is the dried bud or nascent flower of Lonicera japonica(Caprifoliaceae). The plant suffers from various diseases and pests in the growth period and thus pesticides are often used. As a result, the resultant pesticide residues in Lonicera Japonica Flos have aroused great concern. This review summarized the investigation, detection methods, content analysis, and risk assessment of pesticide residues in Lonicera Japonica Flos since 1996, and compared the maximum residue limits among different countries and regions. The results showed that the pesticide residues were detected in Lonicera Japonica Flos from different production areas, and only some exceeded the limits. The residual pesticides have changed from organochlorines to new types such as tebuconazole and nitenpyram. The detection method has upgraded from chromatography to chromatography-mass spectrometry. Most pesticide residues will not cause health risks, except carbofuran. Pesticide residues limit the development of Lonicera Japonica Flos industry in China. In practice, we should improve the drug registration of Lonicera Japonica Flos, promote ecological prevention and control technology, and formulate and promote pesticide residue limit standard of Lonicera Japonica Flos.
Topics: Flowers; Lonicera; Mass Spectrometry; Pesticide Residues; Pesticides
PubMed: 35347943
DOI: 10.19540/j.cnki.cjcmm.20211221.102 -
Journal of Environmental Science and... 2019Greenhouses are enclosed structures which have various characteristics that enhance crop productivity, but the implications for workers' pesticide exposure and uptake... (Review)
Review
Greenhouses are enclosed structures which have various characteristics that enhance crop productivity, but the implications for workers' pesticide exposure and uptake are not well understood. A narrative literature review was conducted to explore the mechanism/s of interactions between greenhouse characteristics and occupational pesticide exposure. Using a "work", "worker" and "workplace" conceptual framework, the greenhouse environment (hot and humid microclimate, limited space and dense crop arrangements) combines with work characteristics (high work and pesticide use intensity, multi-tasking, predominantly manual spraying techniques and quick reentry to treated farms) to potentially increase occupational pesticide exposure, compared with open field farming. Greenhouse environments, are variable but have been shown to influence pesticide availability, route, pathways and frequency of exposure, deposition and distribution on a worker's body as well as use and performance of exposure control methods. Training programs can emphasize the differences in exposure potential between greenhouse and open field farming. Development of tailored guidelines for exposure control strategies to better suit the level of uniqueness of greenhouse agriculture seems warranted.
Topics: Agriculture; Farmers; Farms; Humans; Occupational Exposure; Pesticides
PubMed: 31264928
DOI: 10.1080/03601234.2019.1634972