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Environmental Monitoring and Assessment Aug 2023The possibility of using Opuntia ficus indica fruit juice (OFIFJ) as a bioflocculant for conditioning the synthetic kaolin sludge and sewage sludge (region Oran,...
The possibility of using Opuntia ficus indica fruit juice (OFIFJ) as a bioflocculant for conditioning the synthetic kaolin sludge and sewage sludge (region Oran, Algeria, and Pau, France) was studied. Turbidity of the supernatant, dryness of the sludge cake, and total time of filtration (TTF) were examined parameters. Using vacuum filtration, lime was also tested as a chemical conditioner and gives good results on Lescar (France) sewage sludge in terms of cake's dryness, filtrate quality, turbidity (13.54%), and total time of filtration (TTF = 85.29%), comparing to the industrial polymer (Sedifloc 408C; turbidity; 8.33% and TTF: 2.94%). For the sewage sludge of Oran (Algeria), the results obtained with OFIFJ were compared to those obtained with the cladodes juice of the same plant OFIC, and also with a cationic polymer (Superfloc 8396). For an optimum dosage, it showed that OFIFJ has a flocculation activity as same as the cladodes juice OFIC for sludge conditioning and gives better results in terms of turbidity (dosage of 22.4 g/kg DM: 3.7 NTU for OFIC, dosage of 8.36: 3.63 NTU for OFIFJ. Dryness was enhanced from 14.91 to 22.93% (OFIC 16 g/kg DM) and to 24.48% (OFIF 20.9 g/kg DM) but for TTF, we found the opposite. In fact, this plant showed to be an available, biodegradable, and non-toxic flocculant. For kaolin synthetic sludge (30%), the optimum dosages of those conditioners were found to be 0.066 g kg for OFIC, comparing between vacuum filtration and filtration compression; turbidity was enhanced for both techniques, contrary to dryness. Concerning the Oran city sewage sludge, both turbidity and dryness were optimized. Same thing for the France sewage sludge, all the studied parameters were enhanced with the two studied bioflocculants.
Topics: Opuntia; Sewage; Fruit and Vegetable Juices; Kaolin; Environmental Monitoring; Polymers
PubMed: 37651056
DOI: 10.1007/s10661-023-11766-w -
Journal of the Air & Waste Management... Feb 2024Indoor air pollution remains a major concern, with formaldehyde (HCHO) a primary contributor due to its long emission period and associated health risks, including skin...
Indoor air pollution remains a major concern, with formaldehyde (HCHO) a primary contributor due to its long emission period and associated health risks, including skin allergies, coughing, and bronchitis. This study evaluated the adsorption performance and economic efficiency of various adsorbents (biochar, activated carbon, zeolites A, X, and Y) selected for HCHO removal. The impact of thermal treatment on adsorbent regeneration was also assessed. The experimental apparatus featured an adsorption column and HCHO concentration meter with an electrochemical sensor designed for adsorption analysis. Zeolite X exhibited the highest adsorption performance, followed by zeolite A, zeolite Y, activated carbon, and biochar. All adsorbents displayed increased HCHO removal rates with an extended length/diameter (L/D) ratio of the adsorption column. Zeolite A demonstrated the highest economic efficiency, followed by zeolite X, activated carbon, zeolite Y, and biochar. Higher L/D ratios improved economic efficiency and prolonged the replacement cycle (the optimal timing for adsorbent replacement to maintain high adsorption performance). Sensitivity analysis of adsorbent regeneration under varying thermal treatment conditions (150, 120, and 80°C) and durations (60, 45, and 30 min) revealed minimal changes in adsorption efficiency (±3%). The results indicated the potential of adsorbent regeneration under energy-efficient thermal treatment conditions (80°C, 30 min). In conclusion, this study underscores the importance of a comprehensive assessment, considering factors such as adsorption performance, replacement cycle, economic efficiency, and regeneration performance for the selection of optimal adsorbents for HCHO adsorption and removal.: This study underscores the importance of adsorption technology for the removal of formaldehyde and similar volatile organic compounds (VOCs), highlighting the potential of alternative adsorbents, such as environmentally friendly biochar, in addition to traditional strategies, such as activated carbon and zeolites. Our findings demonstrate the feasibility of adsorbent regeneration under energy-efficient thermal treatment conditions. These results hold promise for improving indoor air quality, reducing environmental pollutants, and enhancing responses to air contaminants like fine dust and VOCs.
Topics: Charcoal; Zeolites; Adsorption; Formaldehyde
PubMed: 38059786
DOI: 10.1080/10962247.2023.2292205 -
Talanta Aug 2024The rapid developments in the field of zeolitic imidazolate frameworks (ZIFs) in recent years have created unparalleled opportunities for the development of unique... (Review)
Review
The rapid developments in the field of zeolitic imidazolate frameworks (ZIFs) in recent years have created unparalleled opportunities for the development of unique bioactive ZIFs for a range of biosensor applications. Integrating bioactive molecules such as DNA, aptamers, and antibodies into ZIFs to create bioactive ZIF composites has attracted great interest. Bioactive ZIF composites have been developed that combine the multiple functions of bioactive molecules with the superior chemical and physical properties of ZIFs. This review thoroughly summarizes the ZIFs as well as the novel strategies for incorporating bioactive molecules into ZIFs. They are used in many different applications, especially in biosensors. Finally, biosensor applications of bioactive ZIFs were investigated in optical (fluorescence and colorimetric) and electrochemical (amperometric, conductometric, and impedance) fields. The surface of ZIFs makes it easier to immobilize bioactive molecules like DNA, enzymes, or antibodies, which in turn enables the construction of cutting-edge, futuristic biosensors.
Topics: Zeolites; Biosensing Techniques; Imidazoles; Metal-Organic Frameworks; Humans; Electrochemical Techniques
PubMed: 38631266
DOI: 10.1016/j.talanta.2024.126097 -
Journal of Environmental Management Feb 2024Laying hen manure (LHM) is a major source of pollution due to its high nitrogen (N) and moisture content (MC). Therefore, reducing the MC of LHM is necessary to retain...
Laying hen manure (LHM) is a major source of pollution due to its high nitrogen (N) and moisture content (MC). Therefore, reducing the MC of LHM is necessary to retain its recyclable value and reduce environmental pollution. One effective way is by incorporating sodium bentonite (SB) and wheat straw (WS) as amendments in the LHM. This work aimed to optimize the drying conditions of LHM and investigate the effect of SB and WS utilization on the dehydration rate, reduction of crude protein (CP), and reduction of ammonium-N (N [Formula: see text] -N). The response surface methodology (RSM) was used to optimize these processes. For this purpose, two sets of experiments (drying of LHM with and without SB and Ws) were designed. The independent parameters were air temperature (70, 80, and 90 °C), air velocity (1, 1.5, and 2 m s), layer thickness (5, 10, and 15 mm), SB (2%, 4%, and 6%), and WS (3%, 7.5%, and 12%). The results indicated that temperature and WS had the most significant influence on all responses. To maximize the dehydration rate and minimize the reduction of CP and N [Formula: see text] -N, the optimal conditions were a temperature of 78 °C, air velocity of 1 m s, and layer thickness of 5 mm in the first set of experiments, and a temperature of 80 °C, air velocity of 1.5 m s, layer thickness of 11 mm, 6% SB, and 12% WS in the second set of experiments. Under the optimum conditions, LHM treated with 6% SB and 12% WS retained 10% more CP and 58% more N [Formula: see text] -N than untreated LHM. Therefore, according to the obtained results, SB and WS are recommended as additives to reduce the CP and N [Formula: see text] -N losses of LHM during the drying process.
Topics: Animals; Female; Manure; Ammonium Compounds; Triticum; Bentonite; Chickens; Dehydration; Sodium
PubMed: 38056333
DOI: 10.1016/j.jenvman.2023.119668 -
ACS Nano Jul 2024Aluminum salts still remain as the most popular adjuvants in marketed human prophylactic vaccines due to their capability to trigger humoral immune responses with a good...
Aluminum salts still remain as the most popular adjuvants in marketed human prophylactic vaccines due to their capability to trigger humoral immune responses with a good safety record. However, insufficient induction of cellular immune responses limits their further applications. In this study, we prepare a library of silicon (Si)- or calcium (Ca)-doped aluminum oxyhydroxide (AlOOH) nanoadjuvants. They exhibit well-controlled physicochemical properties, and the dopants are homogeneously distributed in nanoadjuvants. By using Hepatitis B surface antigen (HBsAg) as the model antigen, doped AlOOH nanoadjuvants mediate higher antigen uptake and promote lysosome escape of HBsAg through lysosomal rupture induced by the dissolution of the dopant in the lysosomes in bone marrow-derived dendritic cells (BMDCs). Additionally, doped nanoadjuvants trigger higher antigen accumulation and immune cell activation in draining lymph nodes. In HBsAg and varicella-zoster virus glycoprotein E (gE) vaccination models, doped nanoadjuvants induce high IgG titer, activations of CD4 and CD8 T cells, cytotoxic T lymphocytes, and generations of effector memory T cells. Doping of aluminum salt-based adjuvants with biological safety profiles and immunostimulating capability is a potential strategy to mediate robust humoral and cellular immunity. It potentiates the applications of engineered adjuvants in the development of vaccines with coordinated immune responses.
Topics: Adjuvants, Immunologic; Animals; Silicon; Mice; Hepatitis B Surface Antigens; Calcium; Aluminum Hydroxide; Mice, Inbred C57BL; Female; Vaccines; Dendritic Cells; Nanoparticles; Humans; Aluminum Oxide
PubMed: 38899978
DOI: 10.1021/acsnano.4c02685 -
International Journal of Biological... Dec 2023Flocculation is a common process for wastewater treatment. However, the most commonly used organic synthetic flocculants such as polyacrylamide are petroleum-based. In...
Flocculation is a common process for wastewater treatment. However, the most commonly used organic synthetic flocculants such as polyacrylamide are petroleum-based. In this work, biomass lignin was grafted with cationic starch to synthesize low-cost, green and fully biomass-based multifunctional flocculants. The cationic polyacrylamide was replaced by cheap industrial cationic starch. Hyperbranched multifunctional lignin-grafted cationic starch flocculant (CS-L) was successfully prepared via ring-opening reaction with epichlorohydrin. The mass content of lignin in the grafted product was between 16.6 % and 70.1 %. With the dosage of CS-L between 4.0 and 7.5 mg/l, the turbidity removal rate for 500 mg/l kaolin suspension reached more than 97 %. When the dosage of CS-L was 24 mg/l, the removal rate of 50 mg/l Cu reached 85.7 %. Importantly, when the mixed solution of kaolin particles and Cu was treated, the synchronous removal rates of kaolin and Cu reached 90 % and 72 % respectively in the range of 8.0-12.0 mg/l flocculant addition. The synthesized lignin-grafted cationic starch flocculant showed an excellent multifunctional flocculation function.
Topics: Starch; Lignin; Kaolin; Biomass; Water Purification; Flocculation; Cations
PubMed: 37806418
DOI: 10.1016/j.ijbiomac.2023.127287 -
Analytical Sciences : the International... Nov 2023Imidaclothiz (IMZ) is a class of neonicotinoid insecticide which can pose potential threat to human health and be frequently detected in water and foods. Herein, a...
Imidaclothiz (IMZ) is a class of neonicotinoid insecticide which can pose potential threat to human health and be frequently detected in water and foods. Herein, a zeolitic imidazolate framework-8/polyaniline (ZIF-8/PANI) nanocomposite has been modified on the surface of glassy carbon electrode (GCE) for the electrochemical determination of IMZ, and the electrochemical detection performance of the modified electrode was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV). With the large surface area of ZIF-8 and great electric conductivity of PANI, the ZIF-8/PANI-modified electrode showed a high catalytic performance towards IMZ reduction in PBS. Under the optimized conditions, the linear range was from 1.0 × 10 to 1.0 × 10 mol/L and the limit of detection was as low as 2.5 × 10 mol/L (S/N = 3). In addition, the developed sensor displayed high reproducibility, excellent stability, and applicability in real vegetable sample analysis, indicating that the proposed method offered an alternative approach for IMZ residues analysis.
Topics: Humans; Zeolites; Reproducibility of Results; Limit of Detection; Nanocomposites; Electrochemical Techniques
PubMed: 37875721
DOI: 10.2116/analsci.21P063 -
Journal of Nanobiotechnology Oct 2023Current protein or glucose based biomemristors have low resistance-switching performance and require complex structural designs, significantly hindering the development...
Current protein or glucose based biomemristors have low resistance-switching performance and require complex structural designs, significantly hindering the development of implantable memristor devices. It is imperative to discover novel candidate materials for biomemristor with high durability and excellent biosafety for implantable health monitoring. Herein, we initially demonstrate the resistance switching characteristics of a nonvolatile memristor in a configuration of Pt/AlOOH/ITO consisting of biocompatible AlOOH nanosheets sandwiched between a Indium Tin Oxides (ITO) electrode and a platinum (Pt) counter-electrode. The hydrothermally synthesized AlOOH nanosheets have excellent biocompatibility as confirmed through the Cell Counting Kit-8 (CCK-8) tests. Four discrete resistance levels are achieved in this assembled device in responsible to different compliance currents (I) for the set process, where the emerging multilevel states show high durability over 10 cycles, outperforming the protein-based biomemristors under similar conditions. The excellent performance of the Pt/AlOOH/ITO memristor is attributed to the significant role of hydrogen proton with pipe effect, as confirmed by both experimental results and density functional theory (DFT) analyses. The present results indicate the nonvolatile memristors with great potential as the next generation implantable multilevel resistive memories for long-term human health monitoring.
Topics: Humans; Aluminum Hydroxide; Aluminum Oxide; Biological Products
PubMed: 37833677
DOI: 10.1186/s12951-023-02117-5 -
Journal of Materials Chemistry. B Jan 2024This review delves into the potential of zeolitic imidazolate framework-8 (ZIF-8) nanoparticles in augmenting the efficacy of cancer immunotherapy, with a special focus... (Review)
Review
This review delves into the potential of zeolitic imidazolate framework-8 (ZIF-8) nanoparticles in augmenting the efficacy of cancer immunotherapy, with a special focus on the delivery of programmed cell death receptor 1 (PD-1) inhibitors. The multifunctional nature of ZIF-8 nanoparticles as drug carriers is emphasized, with their ability to encapsulate a range of therapeutic agents, including PD-1 inhibitors, and facilitate their targeted delivery to tumor locations. By manipulating the pore size and surface characteristics of ZIF-8 nanoparticles, controlled drug release can be realized. The strategic use of ZIF-8 nanoparticles to deliver PD-1 inhibitors presents a precise and targeted modality for cancer treatment, reducing off-target impacts and enhancing therapeutic effectiveness. This combined strategy addresses the existing challenges and constraints of current immunotherapy techniques, with the ultimate goal of enhancing patient outcomes in cancer therapy.
Topics: Humans; Immune Checkpoint Inhibitors; Zeolites; Drug Carriers; Nanoparticles; Neoplasms
PubMed: 38193564
DOI: 10.1039/d3tb02471g -
Journal of Hazardous Materials Sep 2023The coupling of modified nanoscale zero-valent iron (nZVI) with organohalide-degrading bacteria provides a promising solution for the remediation of...
The coupling of modified nanoscale zero-valent iron (nZVI) with organohalide-degrading bacteria provides a promising solution for the remediation of hexabromocyclododecane (HBCD)-contaminated environments. However, the interactions between modified nZVI and dehalogenase bacteria are intricate, and the mechanisms of synergistic action and electron transfer are not clear, and requires further specific investigation. In this study, HBCD was used as a model pollutant, and stable isotope analysis revealed that organic montmorillonite (OMt)-supported nZVI coupled with the degrading bacterial strain Citrobacter sp. Y3 (nZVI/OMt-Y3) can use [C]HBCD as the sole carbon source and degrade or even mineralise it into CO with a maximum conversion rate of 100% within approximately 5 days. Analysis of the intermediates showed that the degradation of HBCD mainly involves three different pathways: dehydrobromination, hydroxylation, and debromination. The proteomics results showed that nZVI introduction promoted the transport of electrons and debromination. Combining the results from XPS, FTIR, and Raman spectroscopy with the analysis results of proteinomics and biodegradation products, we verified the process of electron transport and proposed a metabolic mechanism of HBCD degradation by the nZVI/OMt-Y3. Moreover, this study provides insightful avenues and models for the further remediation of HBCD and other similar pollutants in the environment.
Topics: Iron; Bentonite; Hydrocarbons, Brominated; Biodegradation, Environmental; Environmental Pollutants; Bacteria; Water Pollutants, Chemical
PubMed: 37269562
DOI: 10.1016/j.jhazmat.2023.131739