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Journal of Breast Imaging Nov 2023
Topics: Humans; Cryosurgery; Calcification, Physiologic; Calcinosis
PubMed: 38141242
DOI: 10.1093/jbi/wbad076 -
Nature Communications Aug 2023Modern conceptual models of soil organic carbon (SOC) cycling focus heavily on the microbe-mineral interactions that regulate C stabilization. However, the formation of...
Modern conceptual models of soil organic carbon (SOC) cycling focus heavily on the microbe-mineral interactions that regulate C stabilization. However, the formation of 'stable' (i.e. slowly cycling) soil organic matter, which consists mainly of microbial residues associated with mineral surfaces, is inextricably linked to C loss through microbial respiration. Therefore, what is the net impact of microbial metabolism on the total quantity of C held in the soil? To address this question, we constructed artificial root-soil systems to identify controls on C cycling across the plant-microbe-mineral continuum, simultaneously quantifying the formation of mineral-associated C and SOC losses to respiration. Here we show that root exudates and minerals interacted to regulate these processes: while roots stimulated respiratory C losses and depleted mineral-associated C pools in low-activity clays, root exudates triggered formation of stable C in high-activity clays. Moreover, we observed a positive correlation between the formation of mineral-associated C and respiration. This suggests that the growth of slow-cycling C pools comes at the expense of C loss from the system.
Topics: Soil; Clay; Carbon; Carbon Cycle; Minerals
PubMed: 37587139
DOI: 10.1038/s41467-023-40768-y -
Plant Science : An International... Sep 2023The concept of mineral plant nutrient has been the subject of a long debate. Here, we suggest that an updated discussion on this issue requires considering three... (Review)
Review
The concept of mineral plant nutrient has been the subject of a long debate. Here, we suggest that an updated discussion on this issue requires considering three dimensions. The first one is ontological as it refers to the fundamentals that underlie the category of being a mineral plant nutrient, the second one refers to the practical rules helping to assign a given element to that category, while the third dimension implies the consequences of those rules for human activities. We highlight the idea that the definition of what is a mineral plant nutrient can be enriched by incorporating an evolutionary perspective, thus giving biological insight and helping to integrate information from different disciplines. Following this perspective, mineral nutrients can be contemplated as the elements adopted and/or retained, along evolution, for survival and successful reproduction. We suggest that the operational rules stated in both early and recent works, while highly valuable for their original purposes, will not necessarily account for fitness under the conditions prevailing in natural ecosystems where elements were adopted and are retained -as a result of natural selection processes- covering a wide spectrum of biological activities. We outline a new definition that considers the mentioned three dimensions.
Topics: Humans; Ecosystem; Plants; Minerals; Nutrients; Reproduction
PubMed: 37230191
DOI: 10.1016/j.plantsci.2023.111747 -
Small (Weinheim An Der Bergstrasse,... Aug 2023Cancer is one of the deadliest diseases, and current treatment regimens suffer from limited efficacy, nonspecific toxicity, and chemoresistance. With the advantages of... (Review)
Review
Cancer is one of the deadliest diseases, and current treatment regimens suffer from limited efficacy, nonspecific toxicity, and chemoresistance. With the advantages of good biocompatibility, large specific surface area, excellent cation exchange capacity, and easy availability, clay minerals have been receiving ever-increasing interests in cancer treatment. They can act as carriers to reduce the toxic side effects of chemotherapeutic drugs, and some of their own properties can kill cancer cells, etc. Compared with other morphologies clays, layered clay minerals (LCM) have attracted more and more attention due to adjustable interlayer spacing, easier ion exchange, and stronger adsorption capacity. In this review, the structure, classification, physicochemical properties, and functionalization methods of LCM are summarized. The state-of-the-art progress of LCM in antitumor therapy is systematically described, with emphasis on the application of montmorillonite, kaolinite, and vermiculite. Furthermore, the property-function relationships of LCM are comprehensively illustrated to reveal the design principles of clay-based antitumor systems. Finally, foreseeable challenges and outlook in this field are discussed.
Topics: Clay; Aluminum Silicates; Minerals; Kaolin; Bentonite; Adsorption; Neoplasms
PubMed: 37093210
DOI: 10.1002/smll.202300842 -
Environmental Science and Pollution... Jan 2024Mineral fertilizers are a new type of sustainable fertilizers, containing natural ores as the primary raw material with various nutrients and organic matters. This study... (Review)
Review
Mineral fertilizers are a new type of sustainable fertilizers, containing natural ores as the primary raw material with various nutrients and organic matters. This study combines two methods of bibliometric analysis to comprehensively review the progress of mineral fertilizers from 2000 to 2021. The results showed that the research on mineral fertilizers has increased in the past 21 years, especially after 2014. Developed countries studied mineral fertilizers more extensively than developing countries, but some developing countries, such as China and India, are also paying attention to this area in recent years. Chinese Academic of Sciences, Agriculture and Agri-Food Canada, and Chinese Academy of Agricultural Sciences were the main publishing institutions. Nutrient elements, changes in soil properties, and the effects on promoting crop growth were the main contents of the research. Still, such issues as bioremediation, soil environment improvement, and crop resistance are becoming hot spots. The field of mineral fertilizers showed a strong interdisciplinary nature and an increasingly comprehensive research perspective. The goal is that this synthesis will be used as a starting point for a broader study on responsible environmental management and research on improving fertilizer use efficiency.
Topics: Fertilizers; Soil; Agriculture; Minerals; Bibliometrics
PubMed: 38017216
DOI: 10.1007/s11356-023-31209-w -
Acta Biomaterialia Apr 2024Vertebrate mineralized tissues, present in bones, teeth and scales, have complex 3D hierarchical structures. As more of these tissues are characterized in 3D using... (Review)
Review
Vertebrate mineralized tissues, present in bones, teeth and scales, have complex 3D hierarchical structures. As more of these tissues are characterized in 3D using mainly FIB SEM at a resolution that reveals the mineralized collagen fibrils and their organization into collagen fibril bundles, highly complex and diverse structures are being revealed. In this perspective we propose an approach to analyzing these tissues based on the presence of modular structures: material textures, pore shapes and sizes, as well as extents of mineralization. This modular approach is complimentary to the widely used hierarchical approach for describing these mineralized tissues. We present a series of case studies that show how some of the same structural modules can be found in different mineralized tissues, including in bone, dentin and scales. The organizations in 3D of the various structural modules in different tissues may differ. This approach facilitates the framing of basic questions such as: are the spatial relations between modular structures the same or similar in different mineralized tissues? Do tissues with similar sets of modules carry out similar functions or can similar functions be carried out using a different set of modular structures? Do mineralized tissues with similar sets of modules have a common developmental or evolutionary pathway? STATEMENT OF SIGNIFICANCE: 3D organization studies of diverse vertebrate mineralized tissues are revealing detailed, but often confusing details about the material textures, the arrangements of pores and differences in the extent of mineralization within a tissue. The widely used hierarchical scheme for describing such organizations does not adequately provide a basis for comparing these tissues, or addressing issues such as structural components thought to be characteristic of bone, being present in dermal tissues and so on. The classification scheme we present is based on identifying structural components within a tissue that can then be systematically compared to other vertebrate mineralized tissues. We anticipate that this classification approach will provide insights into structure-function relations, as well as the evolution of these tissues.
Topics: Animals; Vertebrates; Calcification, Physiologic; Bone and Bones; Tooth; Humans; Dentin; Animal Scales
PubMed: 38561073
DOI: 10.1016/j.actbio.2024.03.026 -
Environmental Geochemistry and Health Jul 2023Mining activities have often been associated with the issues of waste generation, while mining is considered a carbon-intensive industry that contributes to the...
Mining activities have often been associated with the issues of waste generation, while mining is considered a carbon-intensive industry that contributes to the increasing carbon dioxide emission to the atmosphere. This study attempts to evaluate the potential of reusing mining waste as feedstock material for carbon dioxide sequestration through mineral carbonation. Characterization of mining waste was performed for limestone, gold and iron mine waste, which includes physical, mineralogical, chemical and morphological analyses that determine its potential for carbon sequestration. The samples were characterized as having alkaline pH (7.1-8.3) and contain fine particles, which are important to facilitate precipitation of divalent cations. High amount of cations (CaO, MgO and FeO) was found in limestone and iron mine waste, i.e., total of 79.55% and 71.31%, respectively, that are essential for carbonation process. Potential Ca/Mg/Fe silicates, oxides and carbonates have been identified, which was confirmed by the microstructure analysis. The limestone waste composed majorly of CaO (75.83%), which was mainly originated from calcite and akermanite minerals. The iron mine waste consisted of FeO (56.60%), mainly from magnetite and hematite, and CaO (10.74%) which was derived from anorthite, wollastonite and diopside. The gold mine waste was attributed to a lower cation content (total of 7.71%), associated mainly with mineral illite and chlorite-serpentine. The average capacity for carbon sequestration was between 7.73 and79.55%, which corresponds to 383.41 g, 94.85 g and 4.72 g CO that were potentially sequestered per kg of limestone, iron and gold mine waste, respectively. Therefore, it has been learned that the mine waste might be utilized as feedstock for mineral carbonation due to the availability of reactive silicate/oxide/carbonate minerals. Utilization of mine waste would be beneficial in light of waste restoration in most mining sites while tackling the issues of CO emission in mitigating the global climate change.
Topics: Carbon Dioxide; Carbon Sequestration; Minerals; Calcium Carbonate; Carbonates; Iron; Gold
PubMed: 36811700
DOI: 10.1007/s10653-023-01513-y -
Journal of Dental Research Jan 2024Biomimetic mineralization of dentin collagen appears to be a promising strategy to optimize dentin bonding durability. However, traditional postbonding mineralization...
Biomimetic mineralization of dentin collagen appears to be a promising strategy to optimize dentin bonding durability. However, traditional postbonding mineralization strategies based on Ca/P ion release still have some drawbacks, such as being time-consuming, having a spatiotemporal mismatch, and having limited intrafibrillar minerals. To tackle these problems, a prebonding rapid intrafibrillar mineralization strategy was developed in the present study. Specifically, polyacrylic acid-stabilized amorphous calcium fluoride (PAA-ACF) was found to induce rapid intrafibrillar mineralization of the single-layer collagen model and dentin collagen at just 1 min and 10 min, as identified by transmission electron microscopy, scanning electron microscopy, and atomic force microscopy. This strategy has also been identified to strengthen the mechanical properties of demineralized dentin within a clinically acceptable timeframe. Significantly, the bonding strength of the PAA-ACF-treated groups outperformed the control group irrespective of aging modes. In addition, the endogenous matrix metalloproteinases as well as exogenous bacterial erosion were inhibited, thus reducing the degradation of dentin collagen. High-quality integration of the hybrid layer and the underlying dentin was also demonstrated. On the basis of the present results, the concept of "prebonding rapid intrafibrillar mineralization" was proposed. This user-friendly scheme introduced PAA-ACF-based intrafibrillar mineralization into dentin bonding for the first time. As multifunctional primers, PAA-ACF precursors have the potential to shed new light on prolonging the service life of adhesive restorations, with promising significance.
Topics: Dental Cements; Dentin; Collagen; Minerals; Microscopy, Electron, Transmission
PubMed: 37990799
DOI: 10.1177/00220345231205492 -
Environmental Research Aug 2023This article proposes an initial model of natural asbestiform minerals growing in four stages. Structures dating from the early stages of the development were observed...
This article proposes an initial model of natural asbestiform minerals growing in four stages. Structures dating from the early stages of the development were observed in the damaged zone surrounding meso-fractures, more particularly in microfractures, microcavities and microcracks that lie in front of and along mesofractures. This study is limited to calcium amphiboles cross-fibers, which develop from altered calcium amphiboles. The observations were made using PLM, with some using TEM. The samples are amphibolites, dolerites and skarns from France. All these rocks have in common that they have been exposed to hydrothermal circulation which gives them a propylite character. The earliest phenomenon was the development of metasomatic veins. In these veins, actinolite form pseudomorphs after hornblendes. The new amphiboles preserve the original morphology of hornblende, in particular the appearance of the cleavages. In the second stage, hydrothermal Fluid circulation promotes the development of subgrains (DSG) with boundaries generally parallel to the cleavage. Some sub-grains become thinner and more and more individualized due to dissolution by the hydrothermal fluid. The third stage is fracturing. The irregular ends of DSGs and amphibole debris can form the substrate of asbestiform mineral nuclei. Further dissolution of DSGs can also lead to the creation of substrates. The last stage is the nucleation and growth. The nuclei have a conical shape and variable widths, from a few microns to about ten microns. The basal parts of the asbestos minerals (BPAMs) extend the DSGs along the c axis. BPAMs have variable widths and can divide during their development at the level of transverse microcracks. BPAMs when not dividing have a morphology comparable to that of whisker nanocrystals synthesized using the vapor-liquid-crystal mechanism. The shape of the fragments from BPMAs is close to that of DSGs as both have variable widths and both have lengths controlled by microcracks.
Topics: Asbestos; Asbestos, Amphibole; Calcium; Minerals
PubMed: 36965807
DOI: 10.1016/j.envres.2022.114940 -
Environmental Monitoring and Assessment Nov 2023Lake sediments can provide valuable insights into anthropogenic disturbances such as intensive aquaculture and land use changes. These disturbances often manifest as...
Lake sediments can provide valuable insights into anthropogenic disturbances such as intensive aquaculture and land use changes. These disturbances often manifest as elevated levels of nutrients and elements within the sediments. This paper uses several analytical techniques, i.e., FTIR (Fourier-transform infrared spectroscopy), XRD (X-ray diffraction), EDS (energy-dispersive X-ray spectroscopy), and SEM (scanning electron microscopy), to examine the elemental constituents of lake sediments, along with their relative mineral abundances and surface morphology. The selected freshwater lakes are from the Central Gangetic Plain. The analysis provides a "fingerprint" of geogenic and biogenic mineral constituents of the sediments. Physicochemical, mineralogical, and elemental analysis shows that intensive aquaculture activities in lake alter the sediment chemistry as evidenced by the increase in pH, organic carbon, organic matter, and total phosphorus which is not observed in the lake where aquaculture is prohibited. Freshwater lake sediment is characterized by a high content of biogenic silica and carbonate minerals. The variations in sediment nutrients and mineral fluxes of the selected lakes are mainly attributed to diverse anthropogenic pressures, differences in lake productivity, and the overall ecological condition of the lakes. In the selected three lakes, major variation was reported in the autochthonous sediments in comparison to the allochthonous sediments. The study concludes that catchment and biotic deposit variations in the lakes cannot be evened out by in-lake mixing mechanisms due to variations in the terrigenous and pelagic deposits of the lake. The results highlight the importance of studying annual fluctuations and spatial variations in geogenic and biogenic mineral particle fluxes in lakes. Such investigations provide valuable insights into the annual dynamics of minerals within lakes, contributing to a more comprehensive understanding of their behavior and distribution.
Topics: Lakes; Anthropogenic Effects; Environmental Monitoring; Phosphorus; Minerals; Geologic Sediments; China
PubMed: 37950807
DOI: 10.1007/s10661-023-12063-2