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Journal of Hazardous Materials Sep 2023The current study investigated the chemical complexity of fifty plastic (36) and elastomer/rubber (14) methanol extracts from consumer products, focusing on the...
The current study investigated the chemical complexity of fifty plastic (36) and elastomer/rubber (14) methanol extracts from consumer products, focusing on the association with toxicity in two screening assays (bacteria luminescence and marine microalgae). The chemical composition varied considerably between the products and polymers. The most complex sample (car tire rubber) contained 2456 chemical features and the least complex (disposable water bottle) only 39 features, with a median of 386 features across all products. Individual extract toxicity also varied significantly across the products and polymers, with the two toxicity assays showing comparable results in terms of defining low and high toxicity extracts, and correlation between medium toxicity extracts. Chemical complexity and abundance both correlated with toxicity in both assays. However, there were strong differences in toxicity between plastic and elastomer extracts. Overall, 86-93 % of the 14 elastomer extracts and only 33-36 % of other polymer extracts (n = 36) were more toxic than the median. A range of compounds were tentatively identified across the sample set, with several concerning compounds being identified, mostly in the elastomers. While the current focus on plastic chemicals is towards thermoplastics, we show that elastomers may be of more concern from an environmental and human health perspective.
Topics: Humans; Rubber; Plastics; Organic Chemicals; Polymers; Elastomers; Bacteria
PubMed: 37336109
DOI: 10.1016/j.jhazmat.2023.131810 -
Chemosphere Oct 2023Occupational exposure to airborne particles can increase the development of morbidity, also because of the chemical composition of particulate matter (PM). In workplace,...
Concentrations and co-occurrence of 101 emerging and legacy organic pollutants in the ultrafine, fine and coarse fractions of airborne particulates associated with treatment of waste from electrical and electronic equipment.
Occupational exposure to airborne particles can increase the development of morbidity, also because of the chemical composition of particulate matter (PM). In workplace, where manual and mechanical disassembly of electric and electronic equipment (EEE) take place, there are evident risks of respiratory exposure to a great number of different toxic organic compounds present in the electrical and plastic materials of which the equipment is made. Airborne particles are numerous, cover a wide range of sizes and are rich in toxic organic compounds. In the present work, a sampling program was conducted and ultrafine, fine and coarse airborne particles were collected in three EEE waste treatment plants. Afterwards, the extraction and analysis of polycyclic aromatic hydrocarbons (PAHs), their nitro and oxygenated derivatives (nitroPAHs, oxyPAHs), organophosphorus compounds (OPEs), Brominated Flame Retardants (BFRs), polychlorinated biphenyls (PCBs), Polybrominated Diphenyl Ethers (PBDEs), and polyfluoralkyl substances (PFASs) was performed. The percentage ratio of the mass of organic compounds and the mass of the ultrafine fraction of PM (PM) was higher than those of the fine and coarse fractions. Even with low concentrations, the co-occurrence of numerous potentially toxic compounds capable of easily reaching other organs passing by the lung vasculature, through the lymph makes the working environment unhealthy.
Topics: Environmental Pollutants; Dust; Particulate Matter; Occupational Exposure; Organic Chemicals; Flame Retardants; Halogenated Diphenyl Ethers; Electronics; Environmental Monitoring; Electronic Waste
PubMed: 37453523
DOI: 10.1016/j.chemosphere.2023.139443 -
Ultrasonics Sonochemistry Oct 2023In this study, the effects of organic acid-soaking (malic, citric, tartaric, and succinic acid) and sonication on the formation of flavor and α-dicarbonyl compounds in...
In this study, the effects of organic acid-soaking (malic, citric, tartaric, and succinic acid) and sonication on the formation of flavor and α-dicarbonyl compounds in Robusta (C. canephora syn. Coffea robusta) green beans were investigated. A total of 20 volatile compounds were identified in Robusta coffee. Furfural and 5-methyl furfural, two dominant volatile compounds in Arabica coffee, increased after organic acid pretreatment. In Robusta coffee processed from 3% malic acid-soaked coffee beans, furfural and 5-methyl furfural increased by 90.99% and 24.92%, respectively, compared to the control. In Robusta coffee processed from 3% malic acid-sonicated (280 W, 1 h) coffee beans, furfural and 5-methyl furfural increased by 236.03% and 114.77%, respectively. α-Dicarbonyls (glyoxal, methylglyoxal, and diacetyl) were significantly (p < 0.05) decreased in all Robusta coffees after organic acid pretreatment. In Robusta coffee processed from coffee beans soaked and sonicated in tartaric acid solution, the α-dicarbonyls decreased by up to 44% and 58%, respectively, compared to the control. This study suggested the pretreatment methods to enhance the flavor substances and reduce the α-DCs in Robusta coffee.
Topics: Coffea; Sonication; Furaldehyde; Malates; Organic Chemicals
PubMed: 37673014
DOI: 10.1016/j.ultsonch.2023.106580 -
Biosensors Jul 2023In many fields, such as environmental monitoring, food safety, and medical diagnostics, the identification of organic compounds is essential. It is crucial to create...
In many fields, such as environmental monitoring, food safety, and medical diagnostics, the identification of organic compounds is essential. It is crucial to create exceptionally sensitive and selective sensors for the detection of organic compounds in order to safeguard the environment and human health. Due to its outstanding electrical, mechanical, and chemical characteristics, the two-dimensional carbon substance graphene has recently attracted much attention for use in sensing applications. The purpose of this research is to create an organic material sensor made from graphene for the detection of organic substances like phenol, ethanol, methanol, chloroform, etc. Due to its high surface-to-volume ratio and potent interactions with organic molecules, graphene improves the sensor's performance while the metasurface structure enables the design of highly sensitive and selective sensing elements. The suggested sensor is highly sensitive and accurate at detecting a broad spectrum of organic molecules, making it appropriate for a number of applications. The creation of this sensor has the potential to have a substantial impact on the field of organic sensing and increase the safety of food, medicine, and the environment. The graphene metasurface organic material sensor (GMOMS) was categorized into three types denoted as GMOMS1, GMOMS2, and GMOMS3 based on the specific application of the graphene chemical potential (GCP). In GMOMS1, GCP was applied on both the CSRR and CS surfaces. In GMOMS2, GCP was applied to the CS surface and the surrounding outer region of the CSRR. In GMOMS3, GCP was applied to the CSRR and the surrounding outer region of the CSRR surface. The results show that all three designs exhibit high relative sensitivity, with the maximum values ranging from 227 GHz/RIU achieved by GMOMS1 to 4318 GHz/RIU achieved by GMOMS3. The FOM values achieved for all the designs range from 2.038 RIU achieved by GMOMS2 to 31.52 RIU achieved by GMOMS3, which is considered ideal in this paper.
Topics: Humans; Graphite; Wastewater; Organic Chemicals; Phenol; Phenols
PubMed: 37622845
DOI: 10.3390/bios13080759 -
Water Science and Technology : a... May 2024In the face of growing global freshwater scarcity, the imperative to recycle and reuse water becomes increasingly apparent across industrial, agricultural, and domestic... (Review)
Review
In the face of growing global freshwater scarcity, the imperative to recycle and reuse water becomes increasingly apparent across industrial, agricultural, and domestic sectors. Eliminating a range of organic pollutants in wastewater, from pesticides to industrial byproducts, presents a formidable challenge. Among the potential solutions, membrane technologies emerge as promising contenders for treating diverse organic contaminants from industrial, agricultural, and household origins. This paper explores cutting-edge membrane-based approaches, including reverse osmosis, nanofiltration, ultrafiltration, microfiltration, gas separation membranes, and pervaporation. Each technology's efficacy in removing distinct organic pollutants while producing purified water is scrutinized. This review delves into membrane fouling, discussing its influencing factors and preventative strategies. It sheds light on the merits, limitations, and prospects of these various membrane techniques, contributing to the advancement of wastewater treatment. It advocates for future research in membrane technology with a focus on fouling control and the development of energy-efficient devices. Interdisciplinary collaboration among researchers, engineers, policymakers, and industry players is vital for shaping water purification innovation. Ongoing research and collaboration position us to fulfill the promise of accessible, clean water for all.
Topics: Membranes, Artificial; Water Purification; Water Pollutants, Chemical; Waste Disposal, Fluid; Filtration; Ultrafiltration; Organic Chemicals
PubMed: 38747950
DOI: 10.2166/wst.2024.117 -
Science (New York, N.Y.) Jun 2024The world is facing an interconnected crisis caused by a variety of factors including climate change, water scarcity, biodiversity loss, and chemical waste. One of most...
The world is facing an interconnected crisis caused by a variety of factors including climate change, water scarcity, biodiversity loss, and chemical waste. One of most prominent factors is the exploitation of limited resources to convert them into chemical products based on the traditional linear approach. This has been provocatively described as rubbish chemistry, a "bad, old-school" system that needs to be revised globally. Representing one of the largest and most complex industrial sectors around the globe and accounting for $4 trillion USD in sales in 2019, the chemical industry generates fundamental components to produce agrochemicals, plastics, paints, adhesives, coatings, electronics, and pharmaceuticals. However, most of these chemicals are made using oil and natural gas, corresponding to 99% of the feedstocks for downstream organic chemical production. Over 80% of the producing companies assert that sustainability has become as important to them as revenue growth, and both increasingly depend on recent advancements in digitalization.
PubMed: 38870287
DOI: 10.1126/science.adq3537 -
International Journal of Biological... Jun 2024This Review presents an overview of all-organic nanocomposites, a sustainable alternative to organic-inorganic hybrids. All-organic nanocomposites contain nanocellulose,... (Review)
Review
This Review presents an overview of all-organic nanocomposites, a sustainable alternative to organic-inorganic hybrids. All-organic nanocomposites contain nanocellulose, nanochitin, and aramid nanofibers as highly rigid reinforcing fillers. They offer superior mechanical properties and lightweight characteristics suitable for diverse applications. The Review discusses various methods for preparing the organic nanofillers, including top-down and bottom-up approaches. It highlights in situ polymerization as the preferred method for incorporating these nanomaterials into polymer matrices to achieve homogeneous filler dispersion, a crucial factor for realizing desired performance. Furthermore, the Review explores several applications of all-organic nanocomposites in diverse fields including food packaging, performance-advantaged plastics, and electronic materials. Future research directions-developing sustainable production methods, expanding biomedical applications, and enhancing resistance against heat, chemicals, and radiation of all-organic nanocomposites to permit their use in extreme environments-are explored. This Review offers insights into the potential of all-organic nanocomposites to drive sustainable growth while meeting the demand for high-performance materials across various industries.
Topics: Nanocomposites; Polymers; Organic Chemicals; Food Packaging; Nanofibers; Inorganic Chemicals
PubMed: 38718994
DOI: 10.1016/j.ijbiomac.2024.132129 -
Chemosphere Aug 2023With the advent of the industrial revolution, the accumulation of persistent organic pollutants (POPs) in the environment has become ubiquitous. POPs are... (Review)
Review
With the advent of the industrial revolution, the accumulation of persistent organic pollutants (POPs) in the environment has become ubiquitous. POPs are halogen-containing organic molecules that accumulate, and remain in the environment for a long time, thus causing toxic effects in living organisms. POPs exhibit a high affinity towards biological macromolecules such as nucleic acids, proteins and lipids, causing genotoxicity and impairment of homeostasis in living organisms. Proteins are essential members of the biological assembly, as they stipulate all necessary processes for the survival of an organism. Owing to their stereochemical features, POPs and their metabolites form energetically favourable complexes with proteins, as supported by biological and dose-dependent toxicological studies. Although individual studies have reported the biological aspects of protein-POP interactions, no comprehensive study summarizing the structural mechanisms, thermodynamics and kinetics of protein-POP complexes is available. The current review identifies and classifies protein-POP interaction according to the structural and functional basis of proteins into five major protein targets, including digestive and other enzymes, serum proteins, transcription factors, transporters, and G-protein coupled receptors. Further, analysis detailing the molecular interactions and structural mechanism evidenced that H-bonds, van der Waals, and hydrophobic interactions essentially mediate the formation of protein-POP complexes. Moreover, interaction of POPs alters the protein conformation through kinetic and thermodynamic processes like competitive inhibition and allostery to modulate the cellular signalling processes, resulting in various pathological conditions such as cancers and inflammations. In summary, the review provides a comprehensive insight into the critical structural/molecular aspects of protein-POP interactions.
Topics: Persistent Organic Pollutants; Organic Chemicals; Environmental Pollutants
PubMed: 37164191
DOI: 10.1016/j.chemosphere.2023.138877 -
Environmental Technology Nov 2023To overcome the low catalytic efficiency, insufficient catalyst strength, and poor ozone circulation in the advanced treatment of secondary wastewater, a hollow...
To overcome the low catalytic efficiency, insufficient catalyst strength, and poor ozone circulation in the advanced treatment of secondary wastewater, a hollow cylindrical Fe-Cu-Ce-Mn/AlO catalyst was prepared by the step impregnation method. Compared with the common impregnation method, the step impregnation method produced a more uniform and compact distribution of each metal element, which was more conducive to generating the synergistic effect of various metals; thus, increasing the mineralization rate of organic matter. The hollow cylindrical design ensured the strength of the catalyst and the circulation of ozone. The reduction of the chemical oxygen demand (COD) was compared under different experimental conditions, with the optimal conditions found to be an ozone contact time of 40 min and ozone dosage of 40 mg/L. The average COD, ammonia nitrogen, and ultraviolet absorbance at 254 nm (UV254) removal rates were 36%, 19%, and 20%, respectively. After 3 weeks of continuous experiment, the removal rate was still high. Following analysis by three dimensional fluorescence, GC-MS, and the molecular weight detection of water samples before and after treatment, it was found that the catalyst enhanced the effect of ozone on wastewater treatment, with a significant removal of tryptophan-like aromatic proteins and soluble microbial metabolites, and the removal of most of the small molecular organic matter. In addition, part of the refractory organic matter could be converted into easily degradable organic matter, which greatly improved the biodegradability and mineralization rate of wastewater, and provided good conditions for subsequent treatment.
Topics: Wastewater; Ozone; Water Pollutants, Chemical; Organic Chemicals; Oxidation-Reduction; Catalysis; Water Purification
PubMed: 35574809
DOI: 10.1080/09593330.2022.2078673 -
PloS One 2024This field experiment aimed to investigate the effects of different ratios of organic and inorganic fertilizers with maintaining equal nitrogen application rates on the...
This field experiment aimed to investigate the effects of different ratios of organic and inorganic fertilizers with maintaining equal nitrogen application rates on the yield, quality, and nitrogen uptake efficiency of Dioscorea polystachya (yam). Six treatments were set, including a control without fertilizer (CK), sole application of chemical fertilizer (CF), sole application of organic fertilizer (OM), 25% organic fertilizer + 75% chemical fertilizer (25%OM + 75%CF), 50% organic fertilizer + 50% chemical fertilizer (50%OM + 50%CF), and 75% organic fertilizer + 25% chemical fertilizer (75%OM + 25%CF). The experiment followed a randomized complete block design with three replications. Various yield parameters, morphology, quality indicators, and nitrogen utilization were analyzed to assess the differences among treatments. The results indicated that all fertilizer treatments significantly increased the yield, morphology, quality indicators, and nitrogen utilization efficiency compared to the control. Specifically, 25%OM + 75%CF achieved the highest yield of 31.96 t hm-2, which was not significantly different from CF (30.18 t hm-2). 25%OM + 75%CF exhibited the highest values at 69.23 cm in tuber length and 75.86% in commodity rate, 3.14% and 1.57% higher than CF respectively. Tuber thickness and fresh weight of 25%OM + 75%CF showed no significant differences from CF, while OM and 50%OM+50%CF exhibited varying degrees of reduction compared to CF. Applying fertilizer significantly enhanced total sugar, starch, crude protein, total amino acid, and ash contents of D. polystachya (except ash content between CK and OM). Applying organic fertilizer increased the total sugar, starch, crude protein, total amino acid, and ash contents in varying degrees when compared with CF. The treatment with 25%OM+75%CF exhibited the highest increases of 6.31%, 3.78%, 18.40%, 29.70%, and 10%, respectively. Nitrogen content in different plant parts followed the sequence of tuber > leaves > stems > aerial stem, with the highest nitrogen accumulation observed in 25%OM + 75%CF treatment. Nitrogen harvest index did not show significant differences among treatments, fluctuating between 0.69 and 0.74. The nitrogen apparent utilization efficiency was highest in 25%OM + 75%CF (9.89%), followed by CF (9.09%), both significantly higher than OM (5.32%) and 50%OM + 50%CF (6.69%). The nitrogen agronomic efficiency varied significantly among treatments, with 25%OM + 75%CF (33.93 kg kg-1) being the highest, followed by CF (29.68 kg kg-1), 50%OM + 50%CF (21.82 kg kg-1), and OM (11.85 kg kg-1). Nitrogen partial factor productivity was highest in 25%OM + 75%CF treatment (76.37 kg kg-1), followed by CF (72.11 kg kg-1), both significantly higher than 50%OM + 50%CF (64.25 kg kg-1) and OM (54.29 kg kg-1), with OM exhibiting significantly lower values compared to other treatments. In conclusion, the combined application of organic and inorganic fertilizers can effectively enhance the yield, quality, and nitrogen utilization efficiency of D. polystachya. Particularly, the treatment with 25% organic fertilizer and 75% chemical fertilizer showed the most promising results.
Topics: Agriculture; Amino Acids; Dioscorea; Fertilizers; Nitrogen; Organic Chemicals; Soil; Starch; Sugars; Random Allocation
PubMed: 38603696
DOI: 10.1371/journal.pone.0301108