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Crystal Growth & Design Jul 2023Magnesium is a critical raw material and its recovery as Mg(OH) from saltwork brines can be realized via precipitation. The effective design, optimization, and scale-up...
Magnesium is a critical raw material and its recovery as Mg(OH) from saltwork brines can be realized via precipitation. The effective design, optimization, and scale-up of such a process require the development of a computational model accounting for the effect of fluid dynamics, homogeneous and heterogeneous nucleation, molecular growth, and aggregation. The unknown kinetics parameters are inferred and validated in this work by using experimental data produced with a T-mixer and a T-mixer, guaranteeing fast and efficient mixing. The flow field in the T-mixers is fully characterized by using the - turbulence model implemented in the computational fluid dynamics (CFD) code OpenFOAM. The model is based on a simplified plug flow reactor model, instructed by detailed CFD simulations. It incorporates Bromley's activity coefficient correction and a micro-mixing model for the calculation of the supersaturation ratio. The population balance equation is solved by exploiting the quadrature method of moments, and mass balances are used for updating the reactive ions concentrations, accounting for the precipitated solid. To avoid unphysical results, global constrained optimization is used for kinetics parameters identification, exploiting experimentally measured particle size distribution (PSD). The inferred kinetics set is validated by comparing PSDs at different operative conditions both in the T-mixer and the T-mixer. The developed computational model, including the kinetics parameters estimated for the first time in this work, will be used for the design of a prototype for the industrial precipitation of Mg(OH) from saltwork brines in an industrial environment.
PubMed: 37426548
DOI: 10.1021/acs.cgd.2c01179 -
Water Research Jul 2023Chemical dosing is the most used strategy for sulfide and methane abatement in urban sewer systems. Although conventional physicochemical methods, such as sulfide... (Review)
Review
Chemical dosing is the most used strategy for sulfide and methane abatement in urban sewer systems. Although conventional physicochemical methods, such as sulfide oxidation (e.g., oxygen/nitrate), precipitation (e.g., iron salts), and pH elevation (e.g., magnesium hydroxide/sodium hydroxide) have been used since the last century, the high chemical cost, large environmental footprint, and side-effects on downstream treatment processes demand a sustainable and cost-effective alternative to these approaches. In this paper, we aimed to review the currently used chemicals and significant progress made in sustainable sulfide and methane abatement technology, including 1) the use of bio-inhibitors, 2) in situ chemical production, and 3) an effective dosing strategy. To enhance the cost-effectiveness of chemical applications in urban sewer systems, two research directions have emerged: 1) online control and optimization of chemical dosing strategies and 2) integrated use of chemicals in urban sewer and wastewater treatment systems. The integration of these approaches offers considerable system-wide benefits; however, further development and comprehensive studies are required.
Topics: Sewage; Sulfides; Nitrates; Water Purification; Methane
PubMed: 37257296
DOI: 10.1016/j.watres.2023.120108 -
Polymers Oct 2023Simultaneously high-rate and high-safety lithium-ion batteries (LIBs) have long been the research focus in both academia and industry. In this study, a multifunctional...
Simultaneously high-rate and high-safety lithium-ion batteries (LIBs) have long been the research focus in both academia and industry. In this study, a multifunctional composite membrane fabricated by incorporating poly(vinylidene fluoride) (PVDF) with magnesium carbonate hydroxide (MCH) nanofibers was reported for the first time. Compared to commercial polypropylene (PP) membranes and neat PVDF membranes, the composite membrane exhibits various excellent properties, including higher porosity (85.9%) and electrolyte wettability (539.8%), better ionic conductivity (1.4 mS·cm), and lower interfacial resistance (93.3 Ω). It can remain dimensionally stable up to 180 °C, preventing LIBs from fast internal short-circuiting at the beginning of a thermal runaway situation. When a coin cell assembled with this composite membrane was tested at a high temperature (100 °C), it showed superior charge-discharge performance across 100 cycles. Furthermore, this composite membrane demonstrated greatly improved flame retardancy compared with PP and PVDF membranes. We anticipate that this multifunctional membrane will be a promising separator candidate for next-generation LIBs and other energy storage devices, in order to meet rate and safety requirements.
PubMed: 37896363
DOI: 10.3390/polym15204120 -
Caspian Journal of Internal Medicine 2024Flaxseed powder seems to improve bowel movements in these patients. Therefore, this study compares the effects of flaxseed powder and magnesium hydroxide on bowel...
BACKGROUND
Flaxseed powder seems to improve bowel movements in these patients. Therefore, this study compares the effects of flaxseed powder and magnesium hydroxide on bowel movements of acute myocardial infarction patients hospitalized in ICU.
METHODS
The population of the present parallel randomized controlled clinical trial included 70 acute myocardial infarction patients hospitalized in ICU who had no history of chronic constipation. The patients in the intervention group were given three sachets of flaxseed powder (each sachet was 3 g) twice a day for four days. The patients in the control group were given 20 cc of magnesium hydroxide syrup each morning. The Bristol scale was used to describe stool consistency.
RESULTS
The mean and standard deviation of the number of bowel movements within five days after intervention are 1.86 ± 1.08 and 1.6 ± 0.65 in the intervention and the control groups, respectively. The frequency of normal stool consistency of the first bowel movement is 94.3% for the intervention group and 85.7% for the control group, which shows no significant differences between the two groups in terms of stool consistency and bowel movement frequency (P=0.510). The bowel movements started on average after 35.2±97.97 hours in the flaxseed group and 24.771±2.677 hours in the magnesium hydroxide group (P=0.023).
CONCLUSION
The results showed that flaxseed powder increases bowel movement frequency and improves the patients' stool consistency, but the differences between the two groups are insignificant. Finally, the time to the first defecation was shorter in the magnesium hydroxide group.
PubMed: 38807721
DOI: 10.22088/cjim.15.2.234 -
Electrolyte & Blood Pressure : E & BP Dec 2023Hypermagnesemia is a rare but potentially fatal electrolyte disorder often overlooked because of its unfamiliarity. Magnesium is regulated through a balance of bone,...
Hypermagnesemia is a rare but potentially fatal electrolyte disorder often overlooked because of its unfamiliarity. Magnesium is regulated through a balance of bone, intestinal absorption, and renal excretion. Hypermagnesemia typically arises from excessive magnesium intake or reduced renal excretion; however, it also occurs in patients with normal kidney function. Herein, we report two cases of hypermagnesemia in patients taking magnesium hydroxide for constipation. The first case involved an 82-year-old woman with end-stage renal disease who developed metabolic encephalopathy due to hypermagnesemia, after taking 3,000 mg of magnesium hydroxide daily for constipation. Her magnesium level was 9.9 mg/dL. Her treatment involved discontinuing magnesium hydroxide and continuing hemodialysis, which led to her recovery. In the second case, a 50-year-old woman with a history of cerebral hemorrhage and mental retardation developed hypermagnesemia despite having normal renal function. She was also taking magnesium hydroxide for constipation, and her magnesium level was 11.0 mg/dL. She experienced cardiac arrest while preparing for continuous renal replacement therapy (CRRT). After achieving return of spontaneous circulation, CRRT was initiated, and her magnesium level showed a decreasing trend. However, vital signs and lactate levels did not recover, leading to death. These cases highlight the importance of prompt diagnosis and intervention for hypermagnesemia and the need to regularly monitor magnesium levels in individuals receiving magnesium-containing preparations, especially those with impaired kidney function.
PubMed: 38152602
DOI: 10.5049/EBP.2023.21.2.66 -
Preventive Nutrition and Food Science Dec 2023We evaluated the efficacy of mixtures of lactulose with probiotic strains to ameliorate constipation and to identify suitable probiotic strains. Constipation was induced...
We evaluated the efficacy of mixtures of lactulose with probiotic strains to ameliorate constipation and to identify suitable probiotic strains. Constipation was induced in Institute of Cancer Research mice (6-week-old, male) by the administering loperamide (5 mg/kg, twice a day) orally for 5 days, whereas the control group was not treated. To evaluate the laxative effects of the lactulose-probiotic and lactulose-magnesium hydroxide mixtures, fecal parameters, the gastrointestinal (GI) transit ratio, and fecal short-chain fatty acid (SCFA) content were analyzed. The administration of lactulose and or significantly improved stool number and water content, which were reduced by loperamide. The GI transit ratio was significantly increased compared with that of the control group. The combined administration of lactulose and probiotics ( or ) increased total SCFA content, including that of acetate, more effectively compared with lactulose alone. Similarly, coadministration of lactulose and magnesium hydroxide improved the loperamide-induced changes in fecal parameters and GI transit as well as increased total SCFA content. Overall, the combination of lactulose and probiotics relieves the symptoms of constipation by increasing SCFA content and is more effective compared with lactulose alone.
PubMed: 38188082
DOI: 10.3746/pnf.2023.28.4.427 -
Polymers Nov 2023The thermal decomposition product of magnesium hydroxide (MH) is magnesium oxide (MgO), which serves as the foundational material for fireproof layer construction in the...
The thermal decomposition product of magnesium hydroxide (MH) is magnesium oxide (MgO), which serves as the foundational material for fireproof layer construction in the condensed phase. However, the weak interaction force between particles of MgO generated by thermal decomposition leads to the insufficient strength and poor adhesion ability of the fireproof layer. The fireproof layer was easily damaged and detached in this study, resulting in the low flame-retardant efficiency of MH. In this work, polycarbosilane (PCS) and divinyl benzene (DVB) were used to modify MH, and EVA/MH/PCS/DVB composites were made via melt blending. The flame-retardant properties of EVA/MH/PCS/DVB were evaluated using the limiting oxygen index (LOI), vertical combustion (UL-94), and a cone calorimeter (CONE). The thermal stability of the composites and flame retardants was analyzed using a thermogravimetric analyzer. The char layer structure was observed and analyzed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The results indicate that the LOI of the EVA/MH/PCS/DVB with 50 wt.% flame retardants in total was as high as 65.1, which increased by 160% in comparison with EVA/MH. Furthermore, the total smoke production (TSP) of the EVA/MH/PCS/DVB composite decreased by 22.7% compared to EVA/MH/PCS; the thermal stability of the MH/PCS/DVB and EVA/MH/PCS/DVB improved to some extent; and the compact residual char after the combustion of EVA/MH/PCS/DVB had fewer cracks due to the adhesive effect induced by PCS/DVB.
PubMed: 38006164
DOI: 10.3390/polym15224440