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Environment International Dec 2019In this study, the occurrence of 8 polybrominated diphenyl ethers (PBDEs), 5 alternative flame retardants (AFRs), and 7 organophosphate flame retardants (OPFRs) was...
In this study, the occurrence of 8 polybrominated diphenyl ethers (PBDEs), 5 alternative flame retardants (AFRs), and 7 organophosphate flame retardants (OPFRs) was determined in 50 pairs of human fingernail and indoor dust samples. The concentrations in fingernail were 9.79-242 ng/g, 17.7-926 ng/g, and 58.0-590 ng/g for PBDEs, AFRs, and OPFRs. Male fingernail showed significantly (p < 0.05) higher ΣPBDE concentrations than female fingernails, while no significant gender differences were observed for AFRs and OPFRs. Lower ratios of BDE209 to ΣPBDE and DBDPE to ΣAFRs were found in fingernails than in dust. Due to their relatively rapid in vivo debromination, BDE 209 and DBDPE in fingernails were most likely from external sources rather than internal exposure (such as through blood circulation). Similar composition profiles between fingernail and dust were observed for PBDEs (excluding BDE209), AFRs (excluding DBDPE), and OPFRs, indicating that indoor dust may be a significant source for these FRs in human fingernails. Significant correlations between fingernail and dust were observed for BDE 47 (p < 0.01; r = 0.50), TBPH (p < 0.01; r = 0.37) and TBOEP (p < 0.01; r = 0.53). Results in this study provided information about contamination levels and exposure sources of FRs, which is important for long-term biomonitoring and health risk assessment of FRs.
Topics: Air Pollution, Indoor; Dust; Female; Flame Retardants; Humans; Male; Nails
PubMed: 31639601
DOI: 10.1016/j.envint.2019.105227 -
The Science of the Total Environment Jan 2022Dust storm particles have been one of the important contributors to global aerosol loading, affecting human health and climate system. Beijing, a megapolitan city,...
Dust storm particles have been one of the important contributors to global aerosol loading, affecting human health and climate system. Beijing, a megapolitan city, experienced two severe dust storms in spring of 2015, with maximum hourly-mean PM mass concentrations exceeding 1000 μg/m. The first dust storm (Dust 1) was from east area of Gobi Desert about 850 km in the north of Beijing and the second (Dust 2) was from west area of Gobi Desert about 1500 km in the northwest of Beijing. Morphologies and elemental compositions of dust particles were identified using high-resolution electron microscopy. The statistical analysis showed that the number fractions of mineral dust particles during the two dust storm episodes were 85.3% and 95.4%, respectively. Clay minerals were the most abundant among mineral particles, with a number fraction larger than 50%, followed by quartz particles (17.3% and 14.8%) and feldspar. Feldspar and carbonate particles accounted for 14.8% and 3.4% of mineral particles in Dust 1, and 9.9% and 13.6% in Dust 2, with the difference due to the different source areas. When the dust storms directly migrated to Beijing, the occurrence of S-containing mineral particles and the relative weight ratio of S in individual mineral particles were extremely low, indicating limited production of sulfate on the dust-storm particles in the atmosphere, regardless of the differences of source areas, migration paths, and mineralogical components. After the peaks of dust storms passed, the occurrence of S on the mineral particles were much higher, although the relative weight ratios of S in the mineral particles was still very small. This result suggests that most of the mineral particles underwent heterogeneous reactions, but the reaction rates were low.
Topics: Aerosols; Air Pollutants; Beijing; Dust; Environmental Monitoring; Humans; Minerals; Particle Size
PubMed: 34525764
DOI: 10.1016/j.scitotenv.2021.149980 -
Environmental Monitoring and Assessment Nov 2023Natural mineral dust episodes elevate particle concentrations and eventually decrease air quality. Air pollutant emissions from aircraft, airport ground operations, and...
Natural mineral dust episodes elevate particle concentrations and eventually decrease air quality. Air pollutant emissions from aircraft, airport ground operations, and long-range dust transport are producing problems for the aviation sector. Dust transport from the Sahara Desert, one of the primary dust sources globally, significantly affects the eastern Mediterranean basin, including Türkiye. This study investigates the effect of long-range dust transport on particulate matter (PM) concentrations at Turkish airports. Three different approaches were used to analyse dust episodes in the study area. Firstly, routine reports of meteorological conditions at the airports were investigated. For this purpose, airport routine meteorological reports (Metar) and aviation-selected special weather report (Speci) codes, recorded at 11 airports from 2012 to 2021, were used to determine the dust episode days. Secondly, the hourly PM measurement dataset was analyzed from the closest air quality monitoring stations to the airports. Finally, regional atmospheric model results and backward-trajectory analysis were used to validate the dust episodes and determine the dust origin. Results showed that 163 dust episodes occurred during the study period, 17% from North Africa and 12% from the Mediterranean region.
Topics: Airports; Environmental Monitoring; Air Pollutants; Particulate Matter; Air Pollution; Dust
PubMed: 38012423
DOI: 10.1007/s10661-023-12135-3 -
The Science of the Total Environment Sep 2022Airborne dust represents a hazard to the environment and human health. The outflow of air masses carrying dust from northern Africa, the world's largest active dust...
Airborne dust represents a hazard to the environment and human health. The outflow of air masses carrying dust from northern Africa, the world's largest active dust source, to the North Atlantic and Mediterranean regions is modulated by atmospheric conditions. However, how global warming-driven changes on atmospheric circulation have influenced North African air outflow in the recent past is not well understood. Here, we explore the Saharan air outflow from northwestern Africa over the 1980 to 2020 period. We find a decrease in the transport to the Atlantic Ocean and the Iberian Peninsula of -0.29 ± 0.16% dec and -0.66 ± 0.18% dec, respectively, and an increasing trend to the Mediterranean Sea (0.24 ± 0.18% dec) and Europe (0.60 ± 0.18% dec). The results indicate that the strengthening of the Atlantic high pressure system and the Saharan thermal low, both associated with the narrowing of the Intertropical Convergence Zone and the Hadley Cell expansion under global warming, could be favoring the Saharan outflow to the Mediterranean Sea and Europe in detriment of transport to the Atlantic Ocean. The results also show that present-day Saharan air arrives at these regions at higher altitudes and in shorter timescales than decades ago. This is associated to the increase in surface heating conditions in the Sahara, 0.41 ± 0.02 °C dec, that can inject air into windier upper atmospheric levels, thereby allowing higher and faster air transport. Our results suggest a change in the Saharan air outflow likely associated with global warming and with potentially significant implications for the temporal and spatial patterns of North African dust export.
Topics: Africa, Northern; Climate; Dust; Humans; Mediterranean Region; Wind
PubMed: 35643146
DOI: 10.1016/j.scitotenv.2022.156268 -
Journal of Hazardous Materials Jan 2021Though ingestion and inhalation of dust have been suggested as important exposure routes contributing chlorinated paraffins (CPs) build-up in humans, the...
Evaluating oral and inhalation bioaccessibility of indoor dust-borne short- and median-chain chlorinated paraffins using in vitro Tenax-assisted physiologically based method.
Though ingestion and inhalation of dust have been suggested as important exposure routes contributing chlorinated paraffins (CPs) build-up in humans, the bioaccessibility of dust-borne CPs in the organ environment has not been well-studied, which may hinder an accurate estimation of exposure risks. In this study, the ingestion and inhalation bioaccessibility of dust-borne short- and median-chain CPs (SCCPs and MCCPs) was assessed using (colon-extended) physiologically based extraction test with the addition of Tenax. The ingestion bioaccessibility of SCCPs 51.5 %Cl, SCCPs 63 %Cl, MCCPs 42 %Cl, and MCCPs 57 %Cl was in ranges of 21.1-44.0 %, 11.7-45.8 %, 21.9-36.6 %, and 7.9-32.9 %, respectively. Multiple linear regression analysis demonstrated statistically significant associations of ingestion bioaccessibility with carbon chain length and chlorine substitution. The ingestion bioaccessibility of CPs also increased with co-existence of carbohydrate/protein. The inhalation bioaccessibility of SCCPs (16.7-38.7 % in artificial lysosomal fluid and 15.5-34.1 % in modified Gamble solution) was significantly higher than MCCPs (<5 %), and varied with dust particle size/total organic carbon content. Our study indicates that modest bioaccessible fractions of CPs in dust should be taken into account to refine the estimation of human exposure, and their bioaccessibility may be affected by CP molecular size, nutritional content and dust property.
Topics: Air Pollution, Indoor; China; Dust; Environmental Monitoring; Humans; Hydrocarbons, Chlorinated; Paraffin
PubMed: 32683154
DOI: 10.1016/j.jhazmat.2020.123449 -
Chemosphere May 2022Following the restriction of bisphenol A (BPA) in certain products, a number of bisphenol analogues (BPs) have been used as BPA replacements in different applications,...
Following the restriction of bisphenol A (BPA) in certain products, a number of bisphenol analogues (BPs) have been used as BPA replacements in different applications, raising environmental and health concerns. The present study determined a total of 13 bisphenol analogues in house dust and children urine from South China families (n = 46). Among all BPs, BPA, bisphenol S (BPS) and bisphenol F (BPF) were frequently detected in house dust, with concentrations ranging from 0.54 to 26.2 μg/g (median: 2.60 μg/g), 0.07-11.5 μg/g (median: 0.32 μg/g) and 0.02-2.4 μg/g (median: 0.29 μg/g), respectively. BPA (median: 2.43 ng/mL) was also the dominant BP in children urine samples, accounting for 75.2 ± 27.4% of the total concentrations of urinary BPs, followed by BPS (0.23 ng/mL), whereas BPF was only detected in less than 30% of urine samples. Children's daily intake of bisphenols through dust ingestion and total daily intakes were estimated based on the dust and urine concentrations, respectively. The estimated intake of BPA, BPS and BPF via house dust ingestion accounted for 9%, 12% and 38% of the total intakes predicted based on urinary concentrations, respectively, and exhibited very low exposure risks.
Topics: Benzhydryl Compounds; Child; China; Dust; Humans; Phenols
PubMed: 35065180
DOI: 10.1016/j.chemosphere.2022.133701 -
Environmental Monitoring and Assessment May 2023Climate and land use changes together are altering the particle content of desert dust storms on regional and local scales. These storms now carry a wide variety of... (Review)
Review
Climate and land use changes together are altering the particle content of desert dust storms on regional and local scales. These storms now carry a wide variety of pollutants and pathogens arising from urbanization, industrialization, mass transportation, warfare, or aerosolized waste in locations worldwide where deserts are intertwined with built infrastructure, transportation centers, and high-density human habitation. Accordingly, the modern desert dust storm has an anthropogenic particle load which presumably sets it apart from pre-industrial dust storms. Evidence for how particle content for modern dust storms is changing over the Arabian Peninsula holds relevance because dust storms are now more frequent and more severe. Furthermore, the Arabian Peninsula has asthma rates which are the highest worldwide. How the modern desert dust storm contributes to asthma and human health is a nascent issue. Meanwhile, public health decisions can benefit from a climate × health framework for dust storms, as proposed here. An imperative is testing each dust storm's particle content type, and for this, we propose the A-B-C-X model. Sampling a dust storm for its particle content data and then archiving samples for future analyses is advised. A storm's particle content data, once combined with its atmospheric data, allows a particle's source, transport, and deposition to be determined. In closing, the modern desert dust storm's changing particle content has far-reaching consequences for public health, transboundary issues, and international climate dialog. SIGNIFICANCE : Locally and regionally sourced particle pollution is a growing problem in deserts worldwide. Proposed here is a climate × health framework for studying how dust storm particles, entrained from both natural and engineered systems, may be contributing to declining human respiratory health.
Topics: Humans; Environmental Monitoring; Climate; Dust; Asthma; Air Pollutants; Desert Climate
PubMed: 37212940
DOI: 10.1007/s10661-023-11287-6 -
Environmental Geochemistry and Health Jul 2023In order to solve the problem of environmental pollution caused by the escape of coal dust in open-pit coal mines, a composite dust suppressant was prepared from...
In order to solve the problem of environmental pollution caused by the escape of coal dust in open-pit coal mines, a composite dust suppressant was prepared from Enteromorpha, and the preparation factors (water-soluble polymer, temperature, solid content and surfactant) were optimized. The mechanism of dust suppression and the possibility of large-scale field application were discussed. The research results on the related properties of dust suppressants showed that the performance of Enteromorpha-based dust suppressants prepared by this method was excellent compared with similar studies. Among them, polyacrylamide (PAM) Enteromorpha-based dust suppressant had the best performance, with viscosity of 25.1 mPa s and surface tension of 27.05 mN/m. Moreover, PAM Enteromorpha-based dust suppressant had the best effect, with the mass loss of 2.94% under the wind speed of 10 m/s and the coal dust loss rate of 4.6% after rain erosion, and it had strong water retention performance. Through the discussion of dust suppression mechanism, it was found that the mechanical entangled network structure with hydrogen bonds as nodes was formed after the graft copolymerization of PAM and Enteromorpha. It had high permeability and good adhesion. After quickly wetting coal dust, it formed a dense package for coal dust. The field experiment also showed that the use of Enteromorpha-based dust suppressant can effectively inhibit the escape of coal dust. From the point of view of economy and efficiency, Enteromorpha can save 30% of the material cost and the dust suppression efficiency can reach 89-94%. Therefore, the Enteromorpha-based dust suppressant may stably suppress coal dust on the basis of reducing the cost.
Topics: Dust; Coal Mining; Environmental Pollution; Coal; Minerals; Water
PubMed: 36988854
DOI: 10.1007/s10653-023-01544-5 -
The Science of the Total Environment Mar 2022Microplastics (MPs) pollution is being increasingly recognized as a global concern in all environments. Wind-blown sand and dust contaminated by MPs are an important...
Microplastics (MPs) pollution is being increasingly recognized as a global concern in all environments. Wind-blown sand and dust contaminated by MPs are an important pathway of MPs transport across different environments, which can result in on-site and off-site potential MP pollution. Here, we designed field experiments to detect MPs in surface soil and wind-blown sand and dust in farmlands with and without film mulch in a semi-arid region of northern China. This study provides the first insights into MPs enrichment in wind-blown sand and dust deposited by natural storms. The results reveal that fibers, fragments, and films constitute the major types of MPs in farmland soil and wind-blown sand and dust. The MPs abundances of 1-3 mm, <1 mm, and 3-5 mm items kg successively decrease. The enrichment of MPs in wind-blown dust is one to two orders of magnitude higher than that in wind-blown sand. For the farmlands with (without) film mulch, the MPs enrichment ratios ranged from 0.22 (0.29) to 1.35 (2.26) in the wind-blown sand and that varied from 1.79 (1.01) to 16.6 (25.79) in the wind-blown dust. Fibers are preferentially transported by wind erosion compared to fragments and films. Soil aggregating processes, wind speed, and MPs shape may influence enrichment in wind-blown sand and dust. Film mulch debris and the application of manure may be the primary sources of MPs in farmland soils. This study further highlights the importance of the transport of airborne MPs from surface soil into the atmosphere. Future research is required to establish the quantitative relationships between the MPs shape, wind speed, and surface soil properties and the MPs enrichment in wind-blown sand and dust.
Topics: Dust; Microplastics; Plastics; Sand; Soil; Wind
PubMed: 34958841
DOI: 10.1016/j.scitotenv.2021.152490 -
PloS One 2023Assessing the economic impact of sand and dust storms provides critical insights to policy development and reforms; a subject that is gaining more attention as risk...
Assessing the economic impact of sand and dust storms provides critical insights to policy development and reforms; a subject that is gaining more attention as risk management becomes the dominant approach for hazard mitigation policies. To assess the causal impact of sand and dust storms on agriculture, specifically on crop and livestock revenue and physical production, random year-to-year variations in dust exposure were analyzed using a fixed effect regression. To complete this analysis, weather and climate data from the on-ground meteorological stations was combined with the household level socioeconomic surveys conducted by Mongolia's National Statistics Office (NSO) over a decade. The descriptive statistics of the meteorological data collected over the eight years period show that, on average, 29 dust events have occurred every year across the country, with greater variation among provinces (Aimags) and regions, reaching up to 108 events in a year in some provinces. The overall trend reveals a slight decrease in the dust events from 2009 to 2019. The econometric results show that value of crop and livestock production (gross income) and physical yields significantly decline in response to higher frequencies of sand and dust storms events. During this period, Mongolia experienced a 2.7% decline in crop revenue as a result of additional sand and dust storms. Assuming 2.7% constant decline in revenues across all agricultural sub-sectors and regions or Aimags, this could lead to about $37.8 million in losses to the economy, which is equivalent to about 0.27% of the national GDP of Mongolia. Increases in the frequency of sand and dust storms could reduce agricultural productivity by between 1.5% to 24%, depending on the crop. Estimates from the modelling exercise are robust to potential endogeneity bias in the measure of sand and dust storms; different specification and identification approaches accounting for the endogeneity bias consistently reveal negative and qualitatively similar impacts of sand and dust storms on crop and livestock productivity.
Topics: Sand; Mongolia; Dust; Weather; Agriculture
PubMed: 36745629
DOI: 10.1371/journal.pone.0269271