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Environmental Pollution (Barking, Essex... Feb 2023Projected water temperature increases based on predicted climate change scenarios and concomitant pesticide exposure raises concern about the responses of aquatic...
Projected water temperature increases based on predicted climate change scenarios and concomitant pesticide exposure raises concern about the responses of aquatic organisms. To better understand the effect of pesticide mixtures and influence of water temperature to fish, juvenile Chinook salmon (Oncorhynchus tshawytscha) were dietarily exposed to a mixture of legacy and current use pesticides (p,p'-DDE, bifenthrin, chlorpyrifos, esfenvalerate, and fipronil) at concentrations detected from field-collected prey items in the Sacramento-San Joaquin Delta, California (Delta) and exposed under current and predicted future water temperature scenarios, 11, 14, or 17 °C, for 14 days. The expression of a subset of genes (deiodinase 2-dio2, gonadotropin releasing hormone 2-gnrh2, and catechol-o-methyltransferase-comt) involved in neuroendocrine, dopaminergic, and olfactory function previously shown to be altered by individual pesticide exposures germane to this study were determined and olfactory function assessed using a Y-maze behavioral assay. When total body burdens of pesticides were measured, a significant decrease in dio2 expression was observed in Chinook salmon exposed at 14 °C compared to fish kept at 11 °C. Increases in gnrh2 expression were also observed in fish exposed to 14 °C. Similarly, increases in comt expression was noted at 14 and 17 °C. Additionally, altered expression of all transcripts was observed, showing interactions between temperature and individual pesticide concentrations. Chinook salmon spent significantly more time actively avoiding the odorant arm at baseline conditions of 11 °C in the Y-maze. At higher temperatures, Chinook spent significantly more time not making a choice between the odorant or clean arm following exposure to the low pesticide mixture, relative to 11 °C. These results suggest that dietary exposure to pesticide mixtures can potentially induce neuroendocrine effects and behavior. Impaired olfactory responses exhibited by Chinook salmon could have implications for predator avoidance in the wild under increased temperature scenarios and impact populations in the future.
Topics: Animals; Pesticides; Salmon; Temperature; Catechol O-Methyltransferase; Dietary Exposure
PubMed: 36572271
DOI: 10.1016/j.envpol.2022.120938 -
Molecules (Basel, Switzerland) Jul 2022Pesticides are among the most important contaminants worldwide due to their wide use, persistence, and toxicity. Their presence in soils is not only important from an... (Review)
Review
Pesticides are among the most important contaminants worldwide due to their wide use, persistence, and toxicity. Their presence in soils is not only important from an environmental point of view, but also for food safety issues, since such residues can migrate from soils to food. However, soils are extremely complex matrices, which present a challenge to any analytical chemist, since the extraction of a wide range of compounds with diverse physicochemical properties, such as pesticides, at trace levels is not an easy task. In this context, the QuEChERS method (standing for quick, easy, cheap, effective, rugged, and safe) has become one of the most green and sustainable alternatives in this field due to its inherent advantages, such as fast sample preparation, the minimal use of hazardous reagents and solvents, simplicity, and low cost. This review is aimed at providing a critical revision of the most relevant modifications of the QuEChERS method (including the extraction and clean-up steps of the method) for pesticide-residue analysis in soils.
Topics: Pesticide Residues; Pesticides; Soil; Solvents
PubMed: 35807567
DOI: 10.3390/molecules27134323 -
Molecules (Basel, Switzerland) Mar 2023Pesticides are compounds applied on crops to eliminate or control pests, diseases and weeds and it is known that their use provides unquestionable benefits in increasing...
Pesticides are compounds applied on crops to eliminate or control pests, diseases and weeds and it is known that their use provides unquestionable benefits in increasing agricultural production [...].
Topics: Pesticide Residues; Pesticides; Agriculture; Crops, Agricultural
PubMed: 37049839
DOI: 10.3390/molecules28073074 -
Pesticide Biochemistry and Physiology Nov 2022Optimization of crop production in recent times has become essential to fulfil food demands of constantly increasing human populations worldwide. To address this... (Review)
Review
Optimization of crop production in recent times has become essential to fulfil food demands of constantly increasing human populations worldwide. To address this formidable challenge, application of agro-chemicals including synthetic pesticides in intensive farm practices has increased alarmingly. The excessive and indiscriminate application of pesticides to foster food production however, leads to its exorbitant deposition in soils. After accumulation in soils beyond threshold limits, pesticides harmfully affect the abundance, diversity and composition and functions of rhizosphere microbiome. Also, the cost of pesticides and emergence of resistance among insect-pests against pesticides are other reasons that require attention. Due to this, loss in soil nutrient pool cause a substantive reduction in agricultural production which warrant the search for newer environmentally friendly technology for sustainable crop production. Rhizosphere microbes, in this context, play vital roles in detoxifying the polluted environment making soil amenable for cultivation through detoxification of pollutants, rhizoremediation, bioremediation, pesticide degradation, and stress alleviation, leading to yield optimization. The response of soil microorganisms to range of chemical pesticides is variable ranging from unfavourable to the death of beneficial microbes. At cellular and biochemical levels, pesticides destruct the morphology, ultrastructure, viability/cellular permeability, and many biochemical reactions including protein profiles of soil bacteria. Several classes of pesticides also disturb the molecular interaction between crops and their symbionts impeding the overall useful biological processes. The harmful impact of pesticides on soil microbes, however, is poorly researched. In this review, the recent findings related with potential effects of synthetic pesticides on a range of soil microbiota is highlighted. Emphasis is given to find and suggest strategies to minimize the chemical pesticides usage in the real field conditions to preserve the viability of soil beneficial bacteria and soil quality for safe and sustainable crop production even in pesticide contaminated soils.
Topics: Humans; Soil; Pesticides; Bacteria; Rhizosphere; Microbiota
PubMed: 36464377
DOI: 10.1016/j.pestbp.2022.105272 -
The Science of the Total Environment Feb 2023Inadequate pesticide application practices have many implications on human and environmental health. This research aimed at assessing pesticide risks on bees, non-target...
Inadequate pesticide application practices have many implications on human and environmental health. This research aimed at assessing pesticide risks on bees, non-target arthropods (NTAs) and earthworms, using PRIMET (Pesticide Risks in the Tropics to Man, Environment and Trade), a pesticide risk model, in the western highlands agro-ecological zone of Cameroon. For this purpose, information on pesticide usage stratagem (dosage, application interval and number of applications) and ecotoxicological properties (median lethal doses, persistence and no observable effect concentration) were gathered and entered into PRIMET to acquire the Predicted Exposure Concentration (PEC), No Effect Concentration (NEC) and Exposure Toxicity Ratio, ETR = PEC / NEC). The risk assessment revealed that the riskiest pesticides for earthworms were acetamiprid, glyphosate and imidacloprid with ETR values of 2963, 1667 and 419 respectively. For bees, acetamiprid, cypermethrin, emamectin benzoate, imidacloprid, and lambda-cyhalothrin were highly risky, with respective ETR values of 3252, 487, 278, 1383 and 295. The model predicted NTAs to be predominantly defenceless against cypermethrin and imidacloprid, as these compounds exhibited the topmost values of ETR of, 4.3 × 10 and 4.4 × 10, respectively. Other pesticides that were modelled to be highly risky to NTAs comprised chlorothalonil (ETR = 2076), cymoxanil (ETR = 1133), emamectin benzoate (ETR = 1700), lambda-cyhalothrin (ETR = 4900) and metalaxyl (ETR = 2303). Some compounds gave evidence of multi-level risks: imidacloprid exhibited high risk to all the organisms (earthworms, bees and NTAs); acetamiprid was risky to earthworms and bees, while cypermethrin, emamectin benzoate and lambda-cyhalothrin, were modelled to pose a risk to bees and NTAs. Regulating the use of these perilous pesticides should be encouraged in agroecosystems to protect environmental and human health.
Topics: Humans; Male; Bees; Animals; Pesticides; Agriculture; Insecticides
PubMed: 36495778
DOI: 10.1016/j.scitotenv.2022.160715 -
Environmental Geochemistry and Health Oct 2022Given the background of current global initiatives for controlling persistent organic pollutants (POPs), an overview of the scientific knowledge about the POPs issues in... (Review)
Review
Given the background of current global initiatives for controlling persistent organic pollutants (POPs), an overview of the scientific knowledge about the POPs issues in Kuwait is presented in this study. Both acute and chronic exposure to POPs can be associated with a wide range of deleterious health effects, including illness and death. POPs have drawn significant political and scientific interest in their fate and actions, particularly where local releases have resulted in dispersed contamination far from the source regions. These concerns inevitably led to the establishment of the Stockholm Convention (SC) on POPs. In recent years, Kuwait has carried out a wide variety of environmental research, in particular, on the monitoring of POPs in different matrices. The technological development facilitated to achieve the opposite monitoring of pesticidal and industrial POPs. The majority of these POPs are from a point source. Kuwait does not have pesticide manufacturing facilities and has not produced pesticides for POPs in the past. In the agriculture sector, Kuwait primarily imports pesticides for pest and disease control. This review encompasses the historical presence and current status of (pesticidal) organochlorine pesticides (OCPs) and (industrial POPs) PCBs and PBDEs in Kuwait based on the export, import, consumption and usage. This research also contrasts pesticide and industrial POP data from various Kuwaiti environmental matrices with data from other parts of Asia, the EU, the USA and Africa.
Topics: Environmental Monitoring; Environmental Pollutants; Halogenated Diphenyl Ethers; Hydrocarbons, Chlorinated; Kuwait; Persistent Organic Pollutants; Pesticides; Polychlorinated Biphenyls
PubMed: 34661833
DOI: 10.1007/s10653-021-01113-8 -
Environmental Science and Pollution... May 2023The rise in the global population demands an increasing food supply and methods to boost agricultural production. Pesticides are necessary for agricultural production... (Meta-Analysis)
Meta-Analysis
The rise in the global population demands an increasing food supply and methods to boost agricultural production. Pesticides are necessary for agricultural production models, avoiding losses of close to 40%. Nevertheless, the extensive use of pesticides can cause their accumulation in the environment, causing problems for human health, biota, and ecosystems. Thus, new technologies have emerged to remove these wastes efficiently. In recent years, metal and metal oxide nanoparticles (MNPs) have been reported as promising catalysts to degrade pesticides; however, a systematic understanding of their effect on pesticide degradation is still required. Therefore, this study focused on a meta-analysis of articles available in Elsevier's Scopus and Thomas Reuters Web of Science, found by searching for "nanoparticle pesticide" and "pesticide contamination." After passing different filters, the meta-analysis was performed with 408 observations from 94 reviews, which comprise insecticides, herbicides, and fungicides, including organophosphates, organochlorines, carbamates, triazines, and neonicotinoids. Herein, 14 different MNPs (Ag, Ni, Pd, CoO, BiOBr, Au, ZnO, Fe, TiO, Cu, WO, ZnS, SnO, and Fe), improved pesticide degradation, with the highest degradation rates achieved by Ag (85%) and Ni (82.5%). Additionally, the impact of the MNP functionalization, size, and concentration on pesticide degradation was quantified and compared. In general, the degradation rate increased when the MNPs were functionalized (~ 70%) compared to naked (~ 49%). Also, the particle size significantly affected the degradation of pesticides. To our knowledge, this study is the first meta-analysis performed about the impact of MNPs on pesticide degradation, providing an essential scientific basis for future studies.
Topics: Humans; Pesticides; Ecosystem; Insecticides; Herbicides; Metal Nanoparticles; Oxides
PubMed: 37017842
DOI: 10.1007/s11356-023-26756-1 -
Food Chemistry Jul 2022Herbal teas have potential health benefits, but they also contain a variety of pesticides and pesticide transformation products (PTPs) that might brings health risks....
Herbal teas have potential health benefits, but they also contain a variety of pesticides and pesticide transformation products (PTPs) that might brings health risks. Our study maps the pesticides and PTPs in two herbal teas (chrysanthemum and Lusterleaf Holly) from two main producing areas in China. Almost all 122 samples contain pesticides, with concentration ranging from 0.0005 to 10.305 mg/kg. Nearly 40% carbendazim and imidacloprid in chrysanthemum teas and λ-cyhalothrin in Lusterleaf Holly have higher concentration levels than the values permitted in EC Regulation No. 396/2005. Distinct distributions of pesticides were found in different teas and production areas. Eight PTPs were identified along with their parents, and were confirmed using a biosynthetic strategy. Acute, chronic and cumulative health risk assessments of pesticides revealed acceptable results. Our study uncovers the profile of pesticides in herbal teas, and provides new insight into discovering the potential environmental pollution and food contaminants.
Topics: China; Chrysanthemum; Pesticide Residues; Pesticides; Risk Assessment; Teas, Herbal
PubMed: 35180605
DOI: 10.1016/j.foodchem.2022.132431 -
The Science of the Total Environment Dec 2022Application of agricultural pesticides poses health concerns for farmworkers and for local communities due to pesticide drift from spraying or fumigation, pesticide...
Application of agricultural pesticides poses health concerns for farmworkers and for local communities due to pesticide drift from spraying or fumigation, pesticide volatilization into the air, contamination of household dust, as well as direct exposure for people who work in agriculture and their families. In this analysis of pesticide use records for Ventura County, California (USA) from 2016 to 2018, we identified the most prevalent toxicological effects of the pesticides applied. We also developed a cumulative toxicity index that incorporates specific toxicity endpoints for individual pesticides, the severity and strength of association for each endpoint, and the reliability of the data sources. Combining the toxicity index for each pesticide with the pounds applied within each square mile section in Ventura County, we calculated the total toxicity-weighted pesticide use and identified pesticides associated with higher potential risk to health. Analysis of U.S. Census data for Ventura County found a greater percentage of Hispanic/Latino, African American and Asian community members in township sections with a greater volume of pesticides applied and higher toxicity-weighted pesticide use. Similarly, areas with limited economic and social resources had elevated pesticide application overall and elevated toxicity-weighted pesticide use. The combination of toxicological and demographic analyses presented in this study provides information that can support the development of policies to protect public health from excessive exposure to pesticides and better environmental health protection for socially vulnerable populations.
Topics: Humans; Pesticides; Reproducibility of Results; Agriculture; California; Dust; Environmental Exposure
PubMed: 36063919
DOI: 10.1016/j.scitotenv.2022.158399 -
Dalton Transactions (Cambridge, England... Oct 2020The large-scale use of pesticides such as organophosphate pesticides (OPPs) and organochlorine pesticides (OCPs) has led to serious environmental problems worldwide, and... (Review)
Review
The large-scale use of pesticides such as organophosphate pesticides (OPPs) and organochlorine pesticides (OCPs) has led to serious environmental problems worldwide, and their high toxicity could cause serious damage to human health. It is crucial to remove and track them precisely in the environment and food resources. As novel nanomaterials, metal-organic frameworks (MOFs) have attracted significant attention in the fields of adsorption and luminescence sensing due to their rich topology, tunable pore size and shape, high surface area, and abundant active sites. Luminescent metal-organic frameworks (LMOFs) have sprung up as great potential chemical sensors to detect pesticides with fast response, high sensitivity, high selectivity and easy operation. Therefore, in this highlight, we focus on recent progress of MOFs in sensing and adsorbing pesticides, as well as in the possible mechanism of sensing, so as to attract more attention to pesticide detection and adsorption.
Topics: Adsorption; Chemistry Techniques, Analytical; Metal-Organic Frameworks; Pesticides
PubMed: 33030153
DOI: 10.1039/d0dt02623a