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Environmental Technology Apr 2022It is urgent to develop a high-efficient process for recycling the spent mercuric chlorides catalyst (SMC) from vinyl chloride monomer (VCM) production with the...
It is urgent to develop a high-efficient process for recycling the spent mercuric chlorides catalyst (SMC) from vinyl chloride monomer (VCM) production with the implementation of the 'Minamata Convention on mercury'. A ultrasound and microwave-assisted technology were developed to treat SMC in this study. Firstly, organic carbon deposition was separated from SMC by pretreatment (ultrasonic-assisted ethanol extraction). The optimized extraction conditions were: ultrasonic time 2 h, ultrasonic power 700 W, extraction temperature 65°C, and liquid-solid ratio 7:1. Under these conditions, 90% of hazardous Cl-containing organics were separated from SMC. Then the pretreated SMC was treated by microwave heating for mercury removal. Residual mercury concentration of SMC decreased from original 1.33% to only 11.92 mg/kg at the preferred conditions of 500°C for 60 min and the treated SMC passed the Toxicity Characteristics Leaching Procedure (TCLP) test. Simultaneously, catalyst support activated carbon (AC) was regenerated with specific surface area increasing from original 263.85 to 627.5 m/g. The organics from macropores and surface of AC was removed by pretreatment, intensifying the subsequent Hg removal and regeneration of AC as revealed by the comparative studies. Finally, SMC was subjected to water leaching for recovering metal values. 88.7% of Ba and 95.3% of Ce were leached with ultrasonic power 500 W and ultrasonic time 120 min. SMC was detoxified and valuable components Hg, AC, Ba, Ce were recovered by this new process, which may provide a new idea for industrial treatment of SMC.
Topics: Catalysis; Mercuric Chloride; Metals; Microwaves; Recycling
PubMed: 33001744
DOI: 10.1080/09593330.2020.1831618 -
Environmental Science & Technology Jan 2023Chlorinated organic chemicals are produced and used extensively worldwide, and their risks to the biology and environment are of increasing concern. However, chlorinated...
Chlorinated organic chemicals are produced and used extensively worldwide, and their risks to the biology and environment are of increasing concern. However, chlorinated byproducts [e.g., polychlorinated dibenzo--dioxins and dibenzofurans (PCDD/Fs)] formed during the commercial manufacturing processes and present in organochlorine products are rarely reported. The knowledge on the occurrences and fate of unintentional persistent organic chemicals in the manufacturing of organochlorine chemical is necessary for accurate assessment of the risks of commercial chemicals and their production. Here, PCDD/Fs were tracked throughout chlorobenzene and chloroethylene production processes (from raw materials to final products) by target analysis. Other byproducts that can further transform into PCDD/Fs were also identified by performing non-target screening. As a result, the PCDD/F concentrations were mostly the highest in bottom residues, and the octachlorinated congeners were dominant. Alkali/water washing stages may cause the formation of oxygen-containing byproducts including PCDD/Fs and acyl-containing compounds, so more attention should be paid to these stages. PCDD/Fs were of 0.17 and 0.21-1.2 ng/mL in monochlorobenzene and chloroethylene products, respectively. Annual PCDD/F emissions (17 g toxic equivalent in 2018) during chlorobenzene and chloroethylene production were estimated using PCDD/F emission factors. The results can contribute to the improvement of PCDD/F inventories for the analyzed commercial chemicals.
Topics: Dibenzofurans; Polychlorinated Dibenzodioxins; Vinyl Chloride; Dibenzofurans, Polychlorinated; Environmental Monitoring; Chlorobenzenes
PubMed: 36681930
DOI: 10.1021/acs.est.2c07322 -
Journal of Colloid and Interface Science Jun 2021The nonsolvent induced phase separation (NIPS) method for ultrafiltration (UF) membrane fabrication relies on the extensive use of traditional solvents, thus ranking...
The nonsolvent induced phase separation (NIPS) method for ultrafiltration (UF) membrane fabrication relies on the extensive use of traditional solvents, thus ranking first in terms of ecological impacts among all the membrane fabrication steps. Methyl-5-(dimethylamino)-2-methyl-5-oxopentanoate (PolarClean), as a green solvent, was utilized in this study to fabricate poly(vinyl chloride) (PVC) UF membranes. Subsequently, in post-treatment process, zwitterionic polymer, [2-(methacryloyloxy) ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide (DMAPS), was grafted onto the membrane surface to enhance its anti-fouling properties using a greener surface-initiated activator regenerated by electron transfer-atom transfer radical polymerization (ARGET-ATRP) reaction. This novel method used low toxicity chemicals, avoiding the environmental hazards of traditional ATRP, and greatly improving the reaction efficiency. We systematically studied the grafting time effect on the resulted membranes using sodium alginate as the foulant, and found that short grafting time (30 min) achieved excellent membrane performance: pure water permeability of 2872 L m h bar, flux recovery ratio of 86.4% after 7-hour fouling test, and foulant rejection of 96.0%. This work discusses for the first time the greener procedures with lower environmental impacts in both fabrication and modification processes of PVC UF membranes.
PubMed: 33618292
DOI: 10.1016/j.jcis.2021.01.107 -
Nature Chemistry Feb 2023New approaches are needed to both reduce and reuse plastic waste. In this context, poly(vinyl chloride) (PVC) is an appealing target as it is the least recycled...
New approaches are needed to both reduce and reuse plastic waste. In this context, poly(vinyl chloride) (PVC) is an appealing target as it is the least recycled high-production-volume polymer due to its facile release of plasticizers and corrosive HCl gas. Herein, these limitations become advantageous in a paired-electrolysis reaction in which HCl is intentionally generated from PVC to chlorinate arenes in an air- and moisture-tolerant process that is mediated by the plasticizer. The reaction proceeds efficiently with other plastic waste present and a commercial plasticized PVC product (laboratory tubing) can be used directly. A simplified life-cycle assessment reveals that using PVC waste as the chlorine source in the paired-electrolysis reaction has a lower global warming potential than HCl. Overall, this method should inspire other strategies for repurposing waste PVC and related polymers using electrosynthetic reactions, including those that take advantage of existing polymer additives.
PubMed: 36376389
DOI: 10.1038/s41557-022-01078-w -
Cancers Dec 2021Malignant vascular tumors of the head and neck are rare neoplasms with variable clinical presentation, wide age distribution, and variable clinical courses. The... (Review)
Review
Malignant vascular tumors of the head and neck are rare neoplasms with variable clinical presentation, wide age distribution, and variable clinical courses. The heterogeneous presentation of angiosarcomas and epithelioid hemangioendothelioma often leads to misdiagnosis and unsuitable treatment. While risk factors for angiosarcomas are previous radiation, chronic lymphedema, and exposure to arsenic, thorium oxide, or vinyl chloride, there are only limited and retrospective data available on prognostic factors in EHE. In both angiosarcomas and EHE, surgery is the mainstay of treatment. There is limited evidence regarding the role of radiotherapy in EHE, although EHE is considered relatively radiosensitive. In angiosarcomas, adjuvant radiotherapy is recommended according to retrospective case series. A standard medical therapy for metastasized malignant vascular tumors is lacking. Chemotherapy, which is effective in angiosarcoma, is mostly ineffective in EHE. Targeted therapy, antiangiogenetic drugs and immunotherapy have been studied as new treatment options. The goal of this review is to summarize the current data regarding malignant vascular tumors along with their diagnosis and management.
PubMed: 34944821
DOI: 10.3390/cancers13246201 -
Polymers Sep 2021Poly(vinyl chloride) (PVC) is an important synthetic plastic that is produced in large quantities (millions of tons) annually. Additives to PVC are necessary to allow...
Poly(vinyl chloride) (PVC) is an important synthetic plastic that is produced in large quantities (millions of tons) annually. Additives to PVC are necessary to allow its use in many applications, particularly in harsh conditions. In regard to this, investigation of the synthesis of trimethoprim-tin complexes and their use as PVC additives is reported. Trimethoprim-tin complexes were obtained from the reaction of trimethoprim and tin chlorides using simple procedures. Trimethoprim-tin complexes (0.5% by weight) were added to PVC to produce homogenous mixtures and thin films were made. The effect of ultraviolet irradiation on the surface and properties of the PVC films was investigated. The level of both photodecomposition and photo-oxidation of PVC films containing trimethoprim-tin complexes was observed to be lower than for the blank film. The effectiveness of tin complexes as PVC photostabilizers reflects the aromaticity of the additives. The complex containing three phenyl groups attached to the tin cation showed the most stabilizing effect on PVC. The complex containing two phenyl groups was next, with the one containing butyl substituents resulting in the least stabilization of PVC. A number of mechanisms have been proposed to explain the role of the synthesized complexes in PVC photostabilization.
PubMed: 34641080
DOI: 10.3390/polym13193264 -
Frontiers in Chemistry 2023Poly (vinyl chloride) (PVC) is commonly used to manufacture biomedical devices and hospital components, but it does not present antimicrobial activity enough to prevent...
Poly (vinyl chloride) (PVC) is commonly used to manufacture biomedical devices and hospital components, but it does not present antimicrobial activity enough to prevent biofouling. With the emergence of new microorganisms and viruses, such as Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) that was responsible for the global pandemic caused by Coronavirus Disease 2019 (COVID-19), it is evident the importance of the development of self-disinfectant PVC for hospital environments and medical clinics where infected people remain for a long time. In this contribution, PVC nanocomposites with silver nanoparticles (AgNPs) were prepared in the molten state. AgNPs are well-known as antimicrobial agents suitable for designing antimicrobial polymer nanocomposites. Adding 0.1 to 0.5 wt% AgNPs significantly reduced Young's modulus and ultimate tensile strength of PVC due to the emergence of microstructural defects in the PVC/AgNP nanocomposites, but the impact strength did not change significantly. Furthermore, nanocomposites have a higher yellowness index (YI) and lower optical bandgap values than PVC. The PVC/AgNP nanocomposites present virucidal activity against SARS-CoV-2 (B.1.1.28 strain) within 48 h when the AgNP content is at least 0.3 wt%, suitable for manufacturing furniture and hospital equipment with self-disinfectant capacity to avoid secondary routes of COVID-19 contagion.
PubMed: 36993814
DOI: 10.3389/fchem.2023.1083399 -
Materials Science & Engineering. C,... Jan 2021Polyvinylidene fluoride (PVDF) porous membranes have been widely used as the filtration and separation industry. Herein, novel microfiltration membranes based on...
Polyvinylidene fluoride (PVDF) porous membranes have been widely used as the filtration and separation industry. Herein, novel microfiltration membranes based on 1-vinyl-3-butylimidazolium chloride ([VBIm][Cl]) grafted PVDF (PVDF-g-[VBIm][Cl]) were prepared via the non-solvent induced phase separation method. The chemical composition and microstructure of PVDF-g-[VBIm][Cl] membranes were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Scanning electron microscopy and Water contact angle measurements. The results showed that an increasing in [VBIm][Cl] grafting content leads to the increasing hydrophilicity and wetting capacity of the PVDF-g-[VBIm][Cl] porous membranes. The anti-biofouling properties of membranes were evaluated by measuring the water flux before and after Bovine serum albumin solution treatment. It was found that the modified membranes presented a good anti-biofouling property. The degree of irreversible flux loss caused by protein adsorption dramatically reduced from 42.1% to 2.9% compared with the pristine hydrophobic PVDF membranes. Meanwhile, these PVDF-g-[VBIm][Cl] membranes also exhibited excellent bactericidal properties against both gram-positive bacteria Staphylococcus saureus and gram-negative bacteria Escherichia coli, while PVDF membranes did not show any antibacterial activity. The vitro biocompatibility of the modified membranes was studied by hemolysis analysis, the platelet adhesion observation, thromboelastography assay and cytotoxicity assay. It was found that the incorporation of [VBIm][Cl] into PVDF membranes has less effect on the hemolysis and cytotoxicity of PVDF membranes. Furthermore, both hydrophilicity and charges of the membrane surface played important role in the adhesion and activation of platelet cells, which consequently affected the clotting process of whole blood. The membrane with appropriate [VBIm][Cl] grafting ratio (2.94 wt.%) exhibited good hemocompatibility with less blood coagulation effect. As an ultrafiltration membrane, PVDF-g-[VBIm][Cl] membranes have potential applications in the biomedical field due to the improved antibacterial property and biocompatibility.
Topics: Anti-Bacterial Agents; Chlorides; Membranes, Artificial; Polyvinyls; Vinyl Chloride
PubMed: 33255013
DOI: 10.1016/j.msec.2020.111411 -
International Journal of Environmental... Feb 2022Public complaints have raised concerns that some mattresses in the current marketplace may be potential sources of airborne fiberglass. Although mattress foam is often...
Public complaints have raised concerns that some mattresses in the current marketplace may be potential sources of airborne fiberglass. Although mattress foam is often marketed as chemical-free, their cover compositions are not as well understood by the general public. To fill these basic information gaps, the covers of four newly purchased mattresses were sampled and analyzed using polarized light microscopy, SEM-EDS, and FTIR microspectroscopy. Two of the mattress covers contained over 50% fiberglass in their inner sock layers. Up to 1% of the fiberglass had migrated to adjacent fabric layers, representing a potential risk of consumer exposure if the zipper on the outer cover is opened. The observed fiberglass fragments had calculated aerodynamic diameters ranging between 30 and 50 µm, suggesting they are potentially inhalable into the nose, mouth, and throat, but are likely too large to penetrate deeper into the lungs. No fiberglass was observed on the brand new mattresses' outer surfaces. Synthetic fibers also present in the sock layers were consistent with flame resistant modacrylic containing vinyl chloride and antimony. The use of fiberglass and other chemicals in mattress covers poses a potential health risk if these materials are not adequately contained. The apparent non-inclusion of mattress covers in chemical-free certifications suggests that further improvements are needed in mattress labeling and education of consumers.
Topics: Antimony; Beds; Glass
PubMed: 35162717
DOI: 10.3390/ijerph19031695 -
Polymers Mar 2021This study examined, the effect of chemically extracted raspberry pomace on the thermal stability, mechanical properties, flammability, chemical structure and processing...
This study examined, the effect of chemically extracted raspberry pomace on the thermal stability, mechanical properties, flammability, chemical structure and processing of poly(vinyl chloride). It was observed that the pomace in this study was used to extract naphtha, thereby permitting the removal of bio-oil as a factor preventing the obtaining of homogeneous composites. Furthermore, adding 20% raspberry pomace filler after extraction extended the thermal stability time for the composites by about 30%. It was observed that composite density, impact strength, and tensile strength values decreased significantly with increasing concentrations of filler in the PVC matrix. At the same time, their modulus of elasticity and Shore hardness increased. All tested composites were characterized by a good burning resistance with a flammability rating of V0 according to the UL94 test. Adding 20 to 40% of a natural filler to the PVC matrix made it possible to obtain composites for the production of flame resistant elements that emitted less hydrogen chloride under fire conditions while ensuring good rigidity.
PubMed: 33805463
DOI: 10.3390/polym13071079