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PloS One 2023Gas drainage materials are one critical aspect of preventing coal mine gas explosions. Here, a novel dual-liquid gas sealing material was developed to improve gas...
Gas drainage materials are one critical aspect of preventing coal mine gas explosions. Here, a novel dual-liquid gas sealing material was developed to improve gas extraction. The mechanical properties and hydration mechanism of the proposed material were determined. The novel dual-liquid gas sealing material's performance was verified experimentally and with field testing, with practical application explored in the YunGaiShan 2 coal mine. The results showed that the main factor responsible for gas drainage leakage was the poor sealing effect of the sealing materials on the cracks around the borehole. The novel dual-liquid gas sealing material reduced damage to the rock surrounding the borehole and significantly improved the gas drainage performance. The initial and final setting times of the novel dual-liquid material were shown to be controllable, and the slurry exhibited good fluidity, with a 28-day uniaxial compressive strength of 11.06 MPa. The analysis of the microscopic hydration mechanism showed that the production of ettringite (AFt) in the dual-liquid material increased significantly, forming a denser network interlace that functioned as a network skeleton, improving the compressive strength of the material and achieving the characteristics of plastic deformation. Field-based analysis was performed to verify the practical applicability of the proposed material, showing that the gas drainage concentration increased by 200.5% compared to the original sealing material. Moreover, the average gas drainage negative pressure increased from 7.8 kPa (using the conventional sealing technique) to 16.6 kPa using the proposed material. Overall, the proposed materials are suitable for sealing materials for effective gas drainage performance and can help control gas disasters.
Topics: Mining; Coal
PubMed: 37043500
DOI: 10.1371/journal.pone.0284140 -
Polymers Aug 2022With the first use of ETFE foils in building structures in the 1980s at the Burgers' Zoo in Arnhem, Netherlands, the implementation of ETFE foils in roof and façade...
With the first use of ETFE foils in building structures in the 1980s at the Burgers' Zoo in Arnhem, Netherlands, the implementation of ETFE foils in roof and façade systems in large-span structures has become steadily more prominent. To safely design ETFE foil structures, their mechanical behaviour has to be fundamentally understood. Until now, several research studies have been published investigating this material's behaviour. However, the parameters influencing these plastic's mechanical behaviour, such as the strain rate or the test temperature, have only been investigated separately but not simultaneously. In this contribution, an analytical model is presented which describes the mechanical behaviour of ETFE foils under varying test temperatures and strain rates simultaneously. The material model has been checked against experimental results achieved for materials from three different international producers and two different commonly used foil thicknesses with significant differences in their mechanical responses (so that it can be assumed that the international market is represented). In the first step, uniaxial tensile tests on strip specimens were performed to describe the nonlinear and viscoelastic temperature- and strain rate-dependent material behaviour under uniaxial tension. The achieved stress-strain curves exhibited, as expected, the two commonly so-called yield points, which can be taken as separators for three different material stages: viscoelastic, viscoelastic-plastic, and viscoplastic. In the second step, by separating the uniaxial tensile response into these three stages, two interdependent functions could be derived based on the well-known Ramberg-Osgood material model to simulate the viscoelastic and viscoelastic-plastic material behaviour of ETFE foils. For this purpose, analytical functions were developed to calculate the model parameters considering the influence of the test temperature and the test speed. It can be shown that the newly developed analytical material model fits well with the experimental results. With the use of the derived nonlinear material model, design engineers can predict the material's mechanical behaviour considering the environmental conditions on site while maintaining independence from the material's supplier.
PubMed: 35956669
DOI: 10.3390/polym14153156 -
Micromachines Jun 2022The machining of micro/nano periodic surface structures using a femtosecond laser has been an academic frontier and hotspot in recent years. With an ultrahigh laser... (Review)
Review
The machining of micro/nano periodic surface structures using a femtosecond laser has been an academic frontier and hotspot in recent years. With an ultrahigh laser fluence and an ultrashort pulse duration, femtosecond laser machining shows unique advantages in material processing. It can process almost any material and can greatly improve the processing accuracy with a minimum machining size and heat-affected zone. Meanwhile, it can fabricate a variety of micro/nano periodic surface structures and then change a material's surface performance dramatically, such as the material's wetting performance, corrosive properties, friction properties, and optical properties, demonstrating great application potential in defense, medical, high-end manufacturing, and many other fields. In recent years, the research is gradually deepening from the basic theory to optimization design, intelligent control, and application technology. Nowadays, while focusing on metal structure materials, especially on stainless steel, research institutions in the field of micro and nano manufacturing have conducted systematic and in-depth experimental research using different experimental environments and laser-processing parameters. They have prepared various surface structures with different morphologies and periods with sound performance, and are one step closer to many civilian engineering applications. This paper reviews the study of micro/nano periodic surface structures and the performance of stainless steel machined using a femtosecond laser, obtains the general evolution law of surface structure and performance with the femtosecond laser parameters, points out several key technical challenges for future study, and provides a useful reference for the engineering research and application of femtosecond laser micro/nano processing technology.
PubMed: 35744590
DOI: 10.3390/mi13060976 -
BioMed Research International 2022Many synthetic routes manufacture zirconium nanoparticles in metal oxide, nitride, and other combination forms. Coupled with other variables such as concentration, pH,... (Review)
Review
Many synthetic routes manufacture zirconium nanoparticles in metal oxide, nitride, and other combination forms. Coupled with other variables such as concentration, pH, and form of precursor used, the various synthetic methods support synthesizing the zirconium metal oxide nanoparticles with changed features. Various synthetic methods were studied, such as sol-gel, hydrothermal, laser ablation, and precipitation. All have different synthetic routes, different precursors and solvents were sued, and the product was characterized by SEM, TEM, photo luminance spectroscopy, UV-absorption spectroscopy, and powder X-ray diffraction. X-ray diffraction determined the crystal structure by identifying the crystal shape, arrangement of atoms, and spacing between them. SEM and TEM studied the particle size and morphology of nanoparticles. UV-visible absorption spectroscopy and PL spectroscopy were used for the determination of optical properties of nanoparticles. Zirconium oxide nanoparticles have many applications in the medical field. The review study primarily focuses on the efficient combination of zirconium dioxide with other additive materials and functionalization techniques used to improve the material's properties, assisting the use of the material in hip arthroplasty and bone tissue applications. The development of sophisticated near-infrared (NIR) absorbing small molecules for useful phototheranostic applications was discussed in this paper.
Topics: Metal Nanoparticles; Nanoparticles; Oxides; Powders; Solvents; X-Ray Diffraction; Zirconium
PubMed: 36147638
DOI: 10.1155/2022/4910777 -
Pharmaceutics Aug 2021Continuous manufacturing (CM) is defined as a process in which the input material(s) are continuously fed into and transformed, and the processed output materials are... (Review)
Review
Continuous manufacturing (CM) is defined as a process in which the input material(s) are continuously fed into and transformed, and the processed output materials are continuously removed from the system. CM can be considered as matching the FDA's so-called 'Desired State' of pharmaceutical manufacturing in the twenty-first century as discussed in their 2004 publication on 'Innovation and Continuous Improvement in Pharmaceutical Manufacturing'. Yet, focused attention on CM did not really start until 2014, and the first product manufactured by CM was only approved in 2015. This review describes some of the benefits and challenges of introducing a CM process with a particular focus on small molecule solid oral dosage forms. The review is a useful introduction for individuals wishing to learn more about CM.
PubMed: 34452272
DOI: 10.3390/pharmaceutics13081311 -
Frontiers in Bioengineering and... 2021The integrity of soft tissue seal is essential for preventing peri-implant infection, mainly induced by established bacterial biofilms around dental implants. Nowadays,...
The integrity of soft tissue seal is essential for preventing peri-implant infection, mainly induced by established bacterial biofilms around dental implants. Nowadays, graphene is well-known for its potential in biocompatibility and antisepsis. Herein, a new titanium biomaterial containing graphene (Ti-0.125G) was synthesized using the spark plasma sintering (SPS) technique. After material characteristics detection, the subsequent responses of human gingival fibroblasts (HGFs) and multiple oral pathogens (including , , and ) to the graphene-reinforced sample were assessed, respectively. Also, the dynamic change of the bacterial multispecies volume in biofilms was evaluated using absolute quantification PCR combined with Illumina high-throughput sequencing. Ti-0.125G, in addition to its particularly pronounced inhibitory effect on at 96 h, was broadly effective against multiple pathogens rather than just one strain. The reinforced material's selective responses were also evaluated by a co-culture model involving HGFs and multiple strains. The results disclosed that the graphene-reinforced samples were highly effective in keeping a balance between the favorable fibroblast responses and the suppressive microbial growth, which could account for the optimal soft tissue seal in the oral cavity. Furthermore, the underlying mechanism regarding new material's bactericidal property in the current study has been elucidated as the electron transfer, which disturbed the bacterial respiratory chain and resulted in a decrease of microbial viability. According to the Kyoto Encyclopedia of Genes and Genomes (KEGG) database, the PICRUSt tool was conducted for the prediction of microbial metabolism functions. Consequently, it is inferred that Ti-0.125G has promising potentials for application in implant dentistry, especially in enhancing the integrity of soft tissue and improving its resistance against bacterial infections around oral implants.
PubMed: 33928075
DOI: 10.3389/fbioe.2021.665305 -
Materials (Basel, Switzerland) Jul 2023Numerous studies have been conducted on fiber-reinforced concrete; however, comparative investigations specifically focusing on the utilization of fibers in CLSM remain...
Numerous studies have been conducted on fiber-reinforced concrete; however, comparative investigations specifically focusing on the utilization of fibers in CLSM remain limited. In this study, we conducted a systematic investigation into the mechanical properties of controlled low-strength material (CLSM) by manipulating the length and doping amount of fibers as control variables. The 7-day compressive strength (7d-UCS), 28-day compressive strength (28d-UCS), and 28-day splitting strength of CLSM were employed as indicators to evaluate the material's performance. Based on our comprehensive analysis, the following conclusions were drawn: (1) A positive correlation was observed between fiber length and material strength within the range of 0-6 mm, while conversely, a negative correlation was evident. Similarly, when the fiber doping was within the range of 0-0.3%, a positive correlation was identified between material strength and fiber doping. However, the strength of CLSM decreased when fiber doping exceeded 0.3%. (2) SEM and PCAS analyses provided further confirmation that the incorporation of fibers effectively reduced the porosity of the material by filling internal pores and interacting with hydration products, thereby forming a mesh structure. Overall, this study offers valuable insights into the manipulation of fiber length and doping amount to optimize the mechanical properties of CLSM. The findings have important implications for the practical application of CLSM, particularly in terms of enhancing its strength through fiber incorporation.
PubMed: 37569988
DOI: 10.3390/ma16155287 -
Science Advances Dec 2019Disordered materials are often out of equilibrium and evolve very slowly in a rugged and tortuous energy landscape. This slow evolution, referred to as aging, is deemed...
Disordered materials are often out of equilibrium and evolve very slowly in a rugged and tortuous energy landscape. This slow evolution, referred to as aging, is deemed undesirable as it often leads to material degradation. However, we show that aging also encodes a memory of the stresses imposed during preparation. Because of inhomogeneous local stresses, the material itself decides how to evolve by modifying stressed regions differently from those under less stress. Because material evolution occurs in response to stresses, aging can be "directed" to produce sought-after responses and unusual functionalities that do not inherently exist. Aging obeys a natural "greedy algorithm" as, at each instant, the material simply follows the path of most rapid and accessible relaxation. Our experiments and simulations illustrate directed aging in examples in which the material's elasticity transforms as desired because of an imposed deformation.
PubMed: 32064313
DOI: 10.1126/sciadv.aax4215 -
Advanced Science (Weinheim,... Jul 2023Information processing using material's own properties has gained increasing interest. Mechanical metamaterials, due to their diversity of deformation modes and wide...
Information processing using material's own properties has gained increasing interest. Mechanical metamaterials, due to their diversity of deformation modes and wide design space, can be used to realize information processing, such as computing and storage. Here a mechanical metamaterial system is demonstrated for material-based encoding and storage of data through programmed reconfigurations of the metamaterial's structured building blocks. Sequential encoding and decoding are achieved in the three-dimensional (3D) printed pixelated mechanical metamaterial via kirigami-based "pixels" with programmable, temperature-dependent bistability. The mechanical metamaterial is demonstrated via a multistep deformation of encoding messages of texts and surfaces with arrays of binary data, and then decoding them by applying a predetermined stretching and heating regimen to sequentially retrieve layers of stored information and display them on its surface. This approach serves as a general framework to enable the encoding and storage of data with mechanical metamaterials.
PubMed: 37083263
DOI: 10.1002/advs.202301581 -
Proceedings of the National Academy of... Mar 2023Graphite is one of the most chemically inert materials. Its elementary constituent, monolayer graphene, is generally expected to inherit most of the parent material's...
Graphite is one of the most chemically inert materials. Its elementary constituent, monolayer graphene, is generally expected to inherit most of the parent material's properties including chemical inertness. Here, we show that, unlike graphite, defect-free monolayer graphene exhibits a strong activity with respect to splitting molecular hydrogen, which is comparable to that of metallic and other known catalysts for this reaction. We attribute the unexpected catalytic activity to surface corrugations (nanoscale ripples), a conclusion supported by theory. Nanoripples are likely to play a role in other chemical reactions involving graphene and, because nanorippling is inherent to atomically thin crystals, can be important for two-dimensional (2D) materials in general.
PubMed: 36913585
DOI: 10.1073/pnas.2300481120