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Nanomaterials (Basel, Switzerland) Jun 2024Supercritical carbon dioxide (CO) has extremely important applications in the extraction of unconventional oil and gas, especially in fracturing and enhanced oil... (Review)
Review
Supercritical carbon dioxide (CO) has extremely important applications in the extraction of unconventional oil and gas, especially in fracturing and enhanced oil recovery (EOR) technologies. It can not only relieve water resource wastage and environmental pollution caused by traditional mining methods, but also effectively store CO and mitigate the greenhouse effect. However, the low viscosity nature of supercritical CO gives rise to challenges such as viscosity fingering, limited sand-carrying capacity, high filtration loss, low oil and gas recovery efficiency, and potential rock adsorption. To overcome these challenges, low-rock-adsorption thickeners are required to enhance the viscosity of supercritical CO. Through research into the literature, this article reviews the solubility and thickening characteristics of four types of polymer thickeners, namely surfactants, hydrocarbons, fluorinated polymers, and silicone polymers in supercritical CO. The thickening mechanisms of polymer thickeners were also analyzed, including intermolecular interactions, LA-LB interactions, hydrogen bonding, and functionalized polymers, and so on.
PubMed: 38921872
DOI: 10.3390/nano14120996 -
Journal of Environmental Sciences... Oct 2024Electrochemical methods are increasingly favored for remediating polluted environments due to their environmental compatibility and reagent-saving features. However, a...
Electrochemical methods are increasingly favored for remediating polluted environments due to their environmental compatibility and reagent-saving features. However, a comprehensive understanding of recent progress, mechanisms, and trends in these methods is currently lacking. Web of Science (WoS) databases were utilized for searching the primary data to understand the knowledge structure and research trends of publications on electrochemical methods and to unveil certain hotspots and future trends of electrochemical methods research. The original data were sampled from 9080 publications in those databases with the search deadline of June 1, 2022. CiteSpace and VOSviewer software facilitated data visualization and analysis of document quantities, source journals, institutions, authors, and keywords. We discussed principles, influencing factors, and progress related to seven major electrochemical methods. Notably, publications on this subject have experienced significant growth since 2007. The most frequently-investigated areas in electrochemical methods included novel materials development, heavy metal remediation, organic pollutant degradation, and removal mechanism identification. "Advanced oxidation process" and "Nanocomposite" are currently trending topics. The major remediation mechanisms are adsorption, oxidation, and reduction. The efficiency of electrochemical systems is influenced by material properties, system configuration, electron transfer efficiency, and power density. Electro-Fenton exhibits significant advantages in achieving synergistic effects of anodic oxidation and electro-adsorption among the seven techniques. Future research should prioritize the improvement of electron transfer efficiency, the optimization of electrode materials, the exploration of emerging technology coupling, and the reduction in system operation and maintenance costs.
Topics: Environmental Restoration and Remediation; Electrochemical Techniques; Bibliometrics; Environmental Pollutants
PubMed: 38802224
DOI: 10.1016/j.jes.2023.08.003 -
Chemosphere Jul 2024Hexavalent chromium (Cr(VI)) contamination of groundwater has traditionally been an environmental issue of great concern due to its bioaccumulative and highly toxic... (Review)
Review
Hexavalent chromium (Cr(VI)) contamination of groundwater has traditionally been an environmental issue of great concern due to its bioaccumulative and highly toxic nature. This paper presents a review and bibliometric analysis of the literature on the interest area "Cr(VI) in groundwater" published in the Web of Science Core Collection from 1999 to 2022. First, information on 203 actual Cr(VI)-contaminated groundwater sites around the world was summarized, and the basic characteristics of the sources and concentrations of contamination were derived. 68.95% of the sites were due to human causes and 56.43% of these sites had Cr(VI) concentrations in the range of 0-10 mg/L. At groundwater sites with high Cr(VI) contamination due to natural causes, 75.00% of the sites had Cr(VI) concentrations less than 0.2 mg/L. A total of 936 papers on "Cr(VI) in groundwater" were retrieved for bibliometric analysis: interest in research on Cr(VI) in groundwater has grown rapidly in recent years; 59.4% of the papers were published in the field of environmental sciences. A systematic review of the progress of studies on the Cr(VI) removal/remediation based on reduction, adsorption and biological processes is presented. Out of 666 papers on Cr(VI) removal/remediation, 512, 274, and 75 papers dealt with the topics of reduction, adsorption, and bioremediation, respectively. In addition, several studies have demonstrated the potential applicability of natural attenuation in the remediation of Cr(VI)-contaminated groundwater. This paper will help researchers to understand and investigate methodological strategies to remove Cr(VI) from groundwater in a more targeted and effective manner.
Topics: Groundwater; Chromium; Water Pollutants, Chemical; Environmental Restoration and Remediation; Environmental Monitoring; Biodegradation, Environmental; Adsorption
PubMed: 38797207
DOI: 10.1016/j.chemosphere.2024.142395 -
Chemosphere Jul 2024Biochar is a carbon-rich material produced from the partial combustion of different biomass residues. It can be used as a promising material for adsorbing pollutants...
Biochar is a carbon-rich material produced from the partial combustion of different biomass residues. It can be used as a promising material for adsorbing pollutants from soil and water and promoting environmental sustainability. Extensive research has been conducted on biochars prepared from different feedstocks used for pollutant removal. However, a comprehensive review of biochar derived from non-woody feedstocks (NWF) and its physiochemical attributes, adsorption capacities, and performance in removing heavy metals, antibiotics, and organic pollutants from water systems needs to be included. This review revealed that the biochars derived from NWF and their adsorption efficiency varied greatly according to pyrolysis temperatures. However, biochars (NWF) pyrolyzed at higher temperatures (400-800 °C) manifested excellent physiochemical and structural attributes as well as significant removal effectiveness against antibiotics, heavy metals, and organic compounds from contaminated water. This review further highlighted why biochars prepared from NWF are most valuable/beneficial for water treatment. What preparatory conditions (pyrolysis temperature, residence time, heating rate, and gas flow rate) are necessary to design a desirable biochar containing superior physiochemical and structural properties, and adsorption efficiency for aquatic pollutants? The findings of this review will provide new research directions in the field of water decontamination through the application of NWF-derived adsorbents.
Topics: Charcoal; Water Pollutants, Chemical; Adsorption; Metals, Heavy; Water Purification
PubMed: 38763397
DOI: 10.1016/j.chemosphere.2024.142368 -
BMC Cardiovascular Disorders May 2024Extracorporeal blood purification has been widely used in intensive care medicine, nephrology, toxicology, and other fields. During the last decade, with the emergence...
BACKGROUND
Extracorporeal blood purification has been widely used in intensive care medicine, nephrology, toxicology, and other fields. During the last decade, with the emergence of new adsorptive blood purification devices, hemoadsorption has been increasingly applied during CPB in cardiac surgery, for patients at different inflammatory risks, or for postoperative complications. Clinical evidence so far has not provided definite answers concerning this adjunctive treatment. The current systematic review aimed to critically assess the role of perioperative hemoadsorption in cardiac surgery, by summarizing the current knowledge in this clinical setting.
METHODS
A literature search of PubMed, Cochrane library, and the database provided by CytoSorbents was conducted on June 1st, 2023. The search terms were chosen by applying neutral search keywords to perform a non-biased systematic search, including language variations of terms "cardiac surgery" and "hemoadsorption". The screening and selection process followed scientific principles (PRISMA statement). Abstracts were considered for inclusion if they were written in English and published within the last ten years. Publications were eligible for assessment if reporting on original data from any type of study (excluding case reports) in which a hemoadsorption device was investigated during or after cardiac surgery. Results were summarized according to sub-fields and presented in a tabular view.
RESULTS
The search resulted in 29 publications with a total of 1,057 patients who were treated with hemoadsorption and 988 control patients. Articles were grouped and descriptively analyzed due to the remarkable variability in study designs, however, all reported exclusively on CytoSorb therapy. A total of 62% (18/29) of the included articles reported on safety and no unanticipated adverse events have been observed. The most frequently reported clinical outcome associated with hemoadsorption was reduced vasopressor demand resulting in better hemodynamic stability.
CONCLUSIONS
The role of hemoadsorption in cardiac surgery seems to be justified in selected high-risk cases in infective endocarditis, aortic surgery, heart transplantation, and emergency surgery in patients under antithrombotic therapy, as well as in those who develop a dysregulated inflammatory response, vasoplegia, or septic shock postoperatively. Future large randomized controlled trials are needed to better define proper patient selection, dosing, and timing of the therapy.
Topics: Humans; Cardiac Surgical Procedures; Treatment Outcome; Risk Factors; Postoperative Complications; Cardiopulmonary Bypass; Male; Female; Risk Assessment; Aged; Middle Aged
PubMed: 38762715
DOI: 10.1186/s12872-024-03938-4 -
Biophysical Chemistry Jul 2024Quantum dots (QDs) are semiconductor nanocrystals (2-10 nm) with unique optical and electronic properties due to quantum confinement effects. They offer high...
Quantum dots (QDs) are semiconductor nanocrystals (2-10 nm) with unique optical and electronic properties due to quantum confinement effects. They offer high photostability, narrow emission spectra, broad absorption spectrum, and high quantum yields, making them versatile in various applications. Due to their highly reactive surfaces, QDs can conjugate with biomolecules while being used, produced, or unintentionally released into the environment. This systematic review delves into intricate relationship between QDs and proteins, examining their interactions that influence their physicochemical properties, enzymatic activity, ligand binding affinity, and stability. The research utilized electronic databases like PubMed, WOS, and Proquest, along with manual reviews from 2013 to 2023 using relevant keywords, to identify suitable literature. After screening titles and abstracts, only articles meeting inclusion criteria were selected for full text readings. This systematic review of 395 articles identifies 125 articles meeting the inclusion criteria, categorized into five overarching themes, encompassing various mechanisms of QDs and proteins interactions, including adsorption to covalent binding, contingent on physicochemical properties of QDs. Through a meticulous analysis of existing literature, it unravels intricate nature of interaction, significant influence on nanomaterials and biological entities, and potential for synergistic applications harnessing both specific and nonspecific interactions across various fields.
Topics: Humans; Nanotechnology; Protein Binding; Proteins; Quantum Dots
PubMed: 38733645
DOI: 10.1016/j.bpc.2024.107238 -
Chemosphere Jun 2024In this comprehensive study, highlights emerging environmentally friendly methods to eliminating hazardous heavy metals from contaminated water, with an emphasis on...
In this comprehensive study, highlights emerging environmentally friendly methods to eliminating hazardous heavy metals from contaminated water, with an emphasis on bioremediation and biosorption. Breakthroughs, such as the combination of biological remediation and nanotechnology to improve the elimination of metals effectiveness and the use of genetically modified microbes for targeted pollutant breakdown. Developing biosorption materials made from agricultural waste and biochar, this indicates interesting areas for future research and emphasizes the necessity of sustainable practices in tackling heavy metal contamination in water systems. There seems to be a surge in enthusiasm for the utilization of biological remediation and biosorption methods as sustainable and viable options for eliminating heavy metals from contaminated water in the past couple of decades. The present review intends to offer an in-depth review of the latest understanding and advances in the discipline of biological remediation methods like bioaccumulation, biofiltration, bio-slurping, and bio-venting. Biosorption is specifically explained and includes waste biomass as biosorbent with the removal mechanisms and the hindrances caused in the process are detailed. Advances in biosorption like microbes as biosorbents and the mechanism involved in it. Additionally, novel enhancement techniques like immobilization, genetic modification, and ultrasound-assisted treatment in microbial sorbent are clarified. However, the review extended with analyzing the future advances in the overall biological methods and consequences of heavy metal pollution.
Topics: Adsorption; Biodegradation, Environmental; Charcoal; Metals, Heavy; Water Pollutants, Chemical; Water Purification
PubMed: 38615953
DOI: 10.1016/j.chemosphere.2024.141933 -
The Science of the Total Environment May 2024The pervasive presence of poly- and perfluoroalkyl substances (PFAS) in diverse products has led to their introduction into wastewater systems, making wastewater... (Review)
Review
The pervasive presence of poly- and perfluoroalkyl substances (PFAS) in diverse products has led to their introduction into wastewater systems, making wastewater treatment plants (WWTPs) significant PFAS contributors to the environment. Despite WWTPs' efforts to mitigate PFAS impact through physicochemical and biological means, concerns persist regarding PFAS retention in generated biosolids. While numerous review studies have explored the fate of these compounds within WWTPs, no study has critically reviewed their presence, transformation mechanisms, and partitioning within the sludge. Therefore, the current study has been specifically designed to investigate these aspects. Studies show variations in PFAS concentrations across WWTPs, highlighting the importance of aqueous-to-solid partitioning, with sludge from PFOS and PFOA-rich wastewater showing higher concentrations. Research suggests biological mechanisms such as cytochrome P450 monooxygenase, transamine metabolism, and beta-oxidation are involved in PFAS biotransformation, though the effects of precursor changes require further study. Carbon chain length significantly affects PFAS partitioning, with longer chains leading to greater adsorption in sludge. The wastewater's organic and inorganic content is crucial for PFAS adsorption; for instance, higher sludge protein content and divalent cations like calcium and magnesium promote adsorption, while monovalent cations like sodium impede it. In conclusion, these discoveries shed light on the complex interactions among factors affecting PFAS behavior in biosolids. They underscore the necessity for thorough considerations in managing PFAS presence and its impact on environmental systems.
Topics: Wastewater; Sewage; Biosolids; Fluorocarbons; Water Pollutants, Chemical; Water Purification
PubMed: 38458438
DOI: 10.1016/j.scitotenv.2024.171559 -
The Science of the Total Environment Apr 2024Synthetic musks (SMs) have served as cost-effective substitutes for natural musk compounds in personal care and daily chemical products for decades. Their widespread use... (Review)
Review
Synthetic musks (SMs) have served as cost-effective substitutes for natural musk compounds in personal care and daily chemical products for decades. Their widespread use has led to their detection in various environmental matrices, raising concerns about potential risks. Despite numerous studies on SM levels in different natural environments, a systematic review of their contemporary presence is lacking. This review aims to address this gap by summarising recent research developments on SMs in diverse natural environments, including river water, lake water, seawater, estuarine water, groundwater, snow, meltwater, sediments, aquatic suspended matter, soils, sands, outdoor air, and atmospheric particulate matter. Covering the period from 2010 to 2023, the review focuses on four SM categories: nitro, polycyclic, macrocyclic, and alicyclic. It systematically examines their sources, occurrences, concentrations, spatial and temporal variations, and fate. The literature reveals widespread detection of SMs in the natural environment (freshwater and sediments in particular), with polycyclic musks being the most studied group. Both direct (e.g., wastewater discharges) and indirect (e.g., human recreational activities) sources contribute to SM presence. Levels of SMs vary greatly among studies with higher levels observed in certain regions, such as sediments in Southeast Asia. Spatial and temporal variations are also evident. The fate of SMs in the environment depends on their physicochemical properties and environmental processes, including bioaccumulation, biodegradation, photodegradation, adsorption, phase exchange, hydro-dilution effects. Biodegradation and photodegradation can decrease SM levels, but may produce more persistent and eco-toxic products. Modelling approaches have been employed to analyse SM fate, especially for indirect processes like photodegradation or long-distance atmospheric transport. Future studies should further investigate the complex fate if SMs and their environmental influence. This review enhances understanding of SM status in the natural environment and supports efforts to control environmental contamination.
Topics: Humans; Fresh Water; Wastewater; Biodegradation, Environmental; Seawater; Water; Water Pollutants, Chemical; Benzopyrans; Tetrahydronaphthalenes
PubMed: 38432391
DOI: 10.1016/j.scitotenv.2024.171344 -
Journal of Hazardous Materials Apr 2024This systematic review addresses soil contamination by crude oil, a pressing global environmental issue, by exploring effective treatment strategies for sites... (Review)
Review
This systematic review addresses soil contamination by crude oil, a pressing global environmental issue, by exploring effective treatment strategies for sites co-contaminated with heavy metals and polycyclic aromatic hydrocarbons (PAHs). Our study aims to answer pivotal research questions: (1) What are the interaction mechanisms between heavy metals and PAHs in contaminated soils, and how do these affect the efficacy of different remediation methods? (2) What are the challenges and limitations of combined remediation techniques for co-contaminated soils compared to single-treatment methods in terms of efficiency, stability, and specificity? (3) How do various factors influence the effectiveness of biological, chemical, and physical remediation methods, both individually and combined, in co-contaminated soils, and what role do specific agents play in the degradation, immobilization, or removal of heavy metals and PAHs under diverse environmental conditions? (4) Do AI-powered search tools offer a superior alternative to conventional search methodologies for executing an exhaustive systematic review? Utilizing big-data analytics and AI tools such as Litmaps.co, ResearchRabbit, and MAXQDA, this study conducts a thorough analysis of remediation techniques for soils co-contaminated with heavy metals and PAHs. It emphasizes the significance of cation-π interactions and soil composition in dictating the solubility and behavior of these pollutants. The study pays particular attention to the interplay between heavy metals and PAH solubility, as well as the impact of soil properties like clay type and organic matter on heavy metal adsorption, which results in nonlinear sorption patterns. The research identifies a growing trend towards employing combined remediation techniques, especially biological strategies like biostimulation-bioaugmentation, noting their effectiveness in laboratory settings, albeit with potentially higher costs in field applications. Plants such as Medicago sativa L. and Solanum nigrum L. are highlighted for their effectiveness in phytoremediation, working synergistically with beneficial microbes to decompose contaminants. Furthermore, the study illustrates that the incorporation of biochar and surfactants, along with chelating agents like EDTA, can significantly enhance treatment efficiency. However, the research acknowledges that varying environmental conditions necessitate site-specific adaptations in remediation strategies. Life Cycle Assessment (LCA) findings indicate that while high-energy methods like Steam Enhanced Extraction and Thermal Resistivity - ERH are effective, they also entail substantial environmental and financial costs. Conversely, Natural Attenuation, despite being a low-impact and cost-effective option, may require prolonged monitoring. The study advocates for an integrative approach to soil remediation, one that harmoniously balances environmental sustainability, cost-effectiveness, and the specific requirements of contaminated sites. It underscores the necessity of a holistic strategy that combines various remediation methods, tailored to meet both regulatory compliance and the long-term sustainability of decontamination efforts.
Topics: Polycyclic Aromatic Hydrocarbons; Soil Pollutants; Metals, Heavy; Biodegradation, Environmental; Soil; Artificial Intelligence; Environmental Restoration and Remediation
PubMed: 38402679
DOI: 10.1016/j.jhazmat.2024.133813