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Journal of Environmental Management Jul 2024This paper presents the synthesis of visible light-responsive ternary nanocomposites composed of cuprous oxide (CuO), tungsten trioxide (WO), and titanium dioxide (TiO)...
This paper presents the synthesis of visible light-responsive ternary nanocomposites composed of cuprous oxide (CuO), tungsten trioxide (WO), and titanium dioxide (TiO) with varying weight percentages (wt.%) of the CuO. The resulting CuO/WO/TiO (CWT) nanocomposites exhibited band gap energy ranging from 2.35 to 2.90 eV. Electrochemical and photoelectrochemical (PEC) studies confirmed a reduced recombination rate of photoexcited charge carriers in the CWT nanocomposites, facilitated by a direct Z-scheme heterojunction. The 0.50CWT nanocomposite demonstrated superior photodegradation activity (2.29 × 10 min) against Reactive Black 5 (RB5) dye under visible light activation. Furthermore, the 0.50CWT nanocomposite exhibited excellent stability with 80.51% RB5 photodegradation retention after five cycles. The 0.50CWT electrode achieved a maximum specific capacitance of 66.32 F/g at 10 mA/g current density, with a capacitance retention of 95.17% after 1000 charge-discharge cycles, affirming its stable and efficient supercapacitor performance. This was supported by well-defined peaks in cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) curves, indicating pseudocapacitive properties.
Topics: Nanocomposites; Titanium; Electrodes; Tungsten; Copper; Light; Catalysis; Oxides
PubMed: 38850906
DOI: 10.1016/j.jenvman.2024.121332 -
International Journal of Biological... Jun 2024Chitosan films containing different amounts of pistachio hull methanol extract (PHE) (2 %, 4 %, 8 % w/v) were produced. LC-MS/MS analysis demonstrated that tannic...
Chitosan films containing different amounts of pistachio hull methanol extract (PHE) (2 %, 4 %, 8 % w/v) were produced. LC-MS/MS analysis demonstrated that tannic acid (207.74 mg/g PHE), gallic acid (46.63 mg/g PHE), protocatechuic acid (27.79 mg/g PHE), quinic acid (16.41 mg/g PHE), isoquercitrin (15.2 mg/g PHE) were the most abundant phenolic compounds in PHE. The biological activity test results indicated that PHE enhanced the antioxidant and antibacterial activities of chitosan films. Chitosan-based films with 8 % PHE showed significant antimicrobial activity on all microorganisms tested. Chitosan films containing even the lowest concentration of PHE effectively inhibited DPPH free radicals, indicating a significant antioxidant activity. The increase in the amount of PHE caused a decrease in the L* value and an increase in the a* and b* values. It was found that the tensile strength and elongation at break of the films containing PHE were higher than those of the control film. Chitosan film with 4 % PHE exhibited the highest values of tensile strength (10.72 ± 1.06 MPa) and elongation at break (198.57 ± 10.34 %). FTIR analysis showed that PHE modified the intermolecular interactions in the film matrix, leading to the expansion of the CC bond and an increase in the intensity of the CO bands. Thermal analysis displayed that chitosan films incorporating PHE exhibited higher thermal stability compared to control films. PHE can be used as a bioactive supportive material in food packaging.
Topics: Chitosan; Food Packaging; Pistacia; Antioxidants; Anti-Bacterial Agents; Plant Extracts; Tensile Strength
PubMed: 38844283
DOI: 10.1016/j.ijbiomac.2024.132866 -
IEEE Transactions on Neural Systems and... 2024Motor imagery (MI) is a high-level cognitive process that has been widely applied to clinical rehabilitation and brain-computer interfaces (BCIs). However, the decoding...
Motor imagery (MI) is a high-level cognitive process that has been widely applied to clinical rehabilitation and brain-computer interfaces (BCIs). However, the decoding of MI tasks still faces challenges, and the neural mechanisms underlying its application are unclear, which seriously hinders the development of MI-based clinical applications and BCIs. Here, we combined EEG source reconstruction and Bayesian nonnegative matrix factorization (NMF) methods to construct large-scale cortical networks of left-hand and right-hand MI tasks. Compared to right-hand MI, the results showed that the significantly increased functional network connectivities (FNCs) mainly located among the visual network (VN), sensorimotor network (SMN), right temporal network, right central executive network, and right parietal network in the left-hand MI at the β (13-30Hz) and all (8-30Hz) frequency bands. For the network properties analysis, we found that the clustering coefficient, global efficiency, and local efficiency were significantly increased and characteristic path length was significantly decreased in left-hand MI compared to right-hand MI at the β and all frequency bands. These network pattern differences indicated that the left-hand MI may need more modulation of multiple large-scale networks (i.e., VN and SMN) mainly located in the right hemisphere. Finally, based on the spatial pattern network of FNC and network properties, we propose a classification model. The proposed model achieves a top classification accuracy of 78.2% in cross-subject two-class MI-BCI tasks. Overall, our findings provide new insights into the neural mechanisms of MI and a potential network biomarker to identify MI-BCI tasks.
Topics: Humans; Brain-Computer Interfaces; Bayes Theorem; Male; Imagination; Electroencephalography; Young Adult; Adult; Female; Algorithms; Nerve Net; Hand; Cerebral Cortex; Functional Laterality; Movement
PubMed: 38837930
DOI: 10.1109/TNSRE.2024.3409872 -
Applied Microbiology and Biotechnology Jun 2024Lactobacillus delbrueckii subsp. bulgaricus and Lactiplantibacillus plantarum are two lactic acid bacteria (LAB) widely used in the food industry. The objective of this...
Lactobacillus delbrueckii subsp. bulgaricus and Lactiplantibacillus plantarum are two lactic acid bacteria (LAB) widely used in the food industry. The objective of this work was to assess the resistance of these bacteria to freeze- and spray-drying and study the mechanisms involved in their loss of activity. The culturability and acidifying activity were measured to determine the specific acidifying activity, while membrane integrity was studied by flow cytometry. The glass transitions temperature and the water activity of the dried bacterial suspensions were also determined. Fourier transform infrared (FTIR) micro-spectroscopy was used to study the biochemical composition of cells in an aqueous environment. All experiments were performed after freezing, drying and storage at 4, 23 and 37 °C. The results showed that Lb. bulgaricus CFL1 was sensitive to osmotic, mechanical, and thermal stresses, while Lpb. plantarum WCFS1 tolerated better the first two types of stress but was more sensitive to thermal stress. Moreover, FTIR results suggested that the sensitivity of Lb. bulgaricus CFL1 to freeze-drying could be attributed to membrane and cell wall degradation, whereas changes in nucleic acids and proteins would be responsible of heat inactivation of both strains associated with spray-drying. According to the activation energy values (47-85 kJ/mol), the functionality loss during storage is a chemically limited reaction. Still, the physical properties of the glassy matrix played a fundamental role in the rates of loss of activity and showed that a glass transition temperature 40 °C above the storage temperature is needed to reach good preservation during storage. KEY POINTS: • Specific FTIR bands are proposed as markers of osmotic, mechanic and thermal stress • Lb. bulgaricus CFL1 was sensitive to all three stresses, Lpb. plantarum WCFS1 to thermal stress only • Activation energy revealed chemically limited reactions ruled the activity loss in storage.
Topics: Freeze Drying; Spectroscopy, Fourier Transform Infrared; Spray Drying; Microbial Viability; Lactobacillus plantarum; Lactobacillus delbrueckii; Lactobacillales; Desiccation
PubMed: 38837050
DOI: 10.1007/s00253-024-13186-3 -
Journal of Colloid and Interface Science May 2024Developing sustainable metal-free carbon-based electrocatalysts is essential for the deployment of metal-air batteries such as zinc-air batteries (ZABs), among which...
Developing sustainable metal-free carbon-based electrocatalysts is essential for the deployment of metal-air batteries such as zinc-air batteries (ZABs), among which doping of heteroatoms has attracted tremendous interest over the past decade. However, the effect of the heteroatom covalent bonds in carbon matrix on catalysis was neglected in most studies. Here, an efficient metal-free oxygen reduction reaction (ORR) catalyst is demonstrated by the N-P bonds anchored carbon (termed N,P-C-1000). The N,P-C-1000 catalyst exhibits superior specific surface area of 1362 m g and ORR activity with a half-wave potential of 0.83 V, close to that of 20 wt% Pt/C. Theoretical computations reveal that the p-band center for C-2p orbit in N,P-C-1000 has higher interaction strength with the intermediates, thus reducing the overall reaction energy barrier. The N,P-C-1000 assembled primary ZAB can attain a large peak power density of 121.9 mW cm and a steady discharge platform of ∼1.20 V throughout 120 h. Besides, when served as the cathodic catalyst in a solid-state ZAB, the battery shows flexibility, conspicuous open circuit potential (1.423 V), and high peak power density (85.8 mW cm). Our findings offer a strategy to tune the intrinsic structure of carbon-based catalysts for improved electrocatalytic performance and shed light on future catalysts design for energy storage technologies beyond batteries.
PubMed: 38833730
DOI: 10.1016/j.jcis.2024.05.221 -
Journal of Oral Biosciences Jun 2024Extracellular matrix components play a significant role in maintaining tissue integrity and pathological processes of the temporomandibular joint (TMJ). This study aimed...
OBJECTIVES
Extracellular matrix components play a significant role in maintaining tissue integrity and pathological processes of the temporomandibular joint (TMJ). This study aimed to evaluate the influence of a soft diet on the mRNA expression of proteoglycans and glycosaminoglycans (GAGs) linked to proteoglycan core proteins in rat TMJ discs.
METHODS
Thirty 4-week-old male Wistar rats were assigned to one of two groups: a control group fed a regular pellet diet and a soft diet group fed a powdered diet for 4 weeks. The mRNA expression levels of 12 proteoglycans in TMJ discs were evaluated using real-time polymerase chain reaction (PCR). In addition, histomorphometric and biochemical analyses were performed to evaluate the thickness and deoxyribonucleic acid (DNA), GAG, and water content of the TMJ discs.
RESULTS
The TMJ disc thickness in the anterior, intermediate, and posterior bands decreased significantly in the soft diet group. The GAG content decreased significantly in the soft-diet group, whereas no significant differences in DNA content or water content ratio were observed between the groups. Real-time PCR indicated that the expression levels of aggrecan, versican, biglycan, decorin, fibromodulin, lumican, and chondroadherin decreased in the soft diet group. The expression levels of all versican isoforms decreased in the soft diet group.
CONCLUSIONS
These results indicate that the biomechanical environment of the TMJ caused by a soft diet is closely related to the expression of proteoglycans in TMJ discs, which may eventually increase the fragility of the TMJ discs.
PubMed: 38830403
DOI: 10.1016/j.job.2024.05.009 -
Physical Review Letters May 2024We extend the notion of topologically protected semi-metallic band crossings to hyperbolic lattices in a negatively curved plane. Because of their distinct translation...
We extend the notion of topologically protected semi-metallic band crossings to hyperbolic lattices in a negatively curved plane. Because of their distinct translation group structure, such lattices are associated with a high-dimensional reciprocal space. In addition, they support non-Abelian Bloch states which, unlike conventional Bloch states, acquire a matrix-valued Bloch factor under lattice translations. Combining diverse numerical and analytical approaches, we uncover an unconventional scaling in the density of states at low energies, and illuminate a nodal manifold of codimension five in the reciprocal space. The nodal manifold is topologically protected by a nonzero second Chern number, reminiscent of the characterization of Weyl nodes by the first Chern number.
PubMed: 38829096
DOI: 10.1103/PhysRevLett.132.206601 -
The Journal of Chemical Physics Jun 2024Static and time-dependent quantum-mechanical approaches have been employed in the literature to characterize the physics of light-emitting molecules and nanostructures....
Static and time-dependent quantum-mechanical approaches have been employed in the literature to characterize the physics of light-emitting molecules and nanostructures. However, the electromagnetic emission induced by an input current has remained beyond the realm of molecular simulations. This is the challenge addressed here with the help of an equation of motion for the density matrix coupled to a photon bath based on a Redfield formulation. This equation is evolved within the framework of the driven-Liouville von Neumann approach, which incorporates open boundaries by introducing an applied bias and a circulating current. The dissipated electromagnetic power can be computed in this context from the time derivative of the energy. This scheme is applied in combination with a self-consistent tight-binding Hamiltonian to investigate the effects of bias and molecular size on the electroluminescence of metallic and semiconducting chains. For the latter, a complex interplay between bias and molecular length is observed: there is an optimal number of atoms that maximizes the emitted power at high voltages but not at low ones. This unanticipated behavior can be understood in terms of the band bending produced along the semiconducting chain, a phenomenon that is captured by the self-consistency of the method. A simple analytical model is proposed that explains the main features revealed by the simulations. The methodology, applied here at a self-consistent tight-binding level but extendable to more sophisticated Hamiltonians such as density functional tight binding and time dependent density functional theory, promises to be helpful for quantifying the power and quantum efficiency of nanoscale electroluminescent devices.
PubMed: 38828814
DOI: 10.1063/5.0201447 -
Journal of International Society of... 2024The success of composite restorations relies on material selection and practitioner-related factors that shape the overall outcome. This study explores the practices of...
AIM
The success of composite restorations relies on material selection and practitioner-related factors that shape the overall outcome. This study explores the practices of Palestinian general dental practitioners in placing posterior composites, examining the impact of work sector, experience, and gender on their choices.
MATERIALS AND METHODS
The study was conducted as an online cross-sectional questionnaire and involved 351 participants, with a response rate of 69.8%. The survey comprised 18 closed-ended questions covering demographics, material selection, and composite placement in special cases, techniques, and factors influencing the choices. Statistical analyses included descriptive statistics, chi-squared tests, and Fisher's exact tests.
RESULTS
Composite was the predominant choice for small-size (83.7%) and large-size posterior cavities (60.4%). Practitioners commonly opted for composite restorations in cases involving occlusal parafunctional activity (60%), poor oral hygiene (78%), and subgingival cavities (72.2%). Only 19.6% and 5.3% reported occlusal and gingival beveling, respectively. Rubber dams for isolation stood at 30%, one-step self-etch adhesives at 44.9%, and the oblique layering technique at 51%. Light-emitting diode curing units were popular (97.55%), but monitoring output with a radiometer was infrequent (93.5%). Tofflemire metal matrix usage was 46.1%, whereas a sectional matrix system was employed by 29.8%. A 2 mm layer exposure to light curing for 20 s was reported by 62%, and 27.75% utilized additional light-curing postmatrix band removal.
CONCLUSION
The study highlights the need for Palestinian dental professionals to update their clinical approaches in placing composite restorations in posterior teeth. Gender, work sector, and experience influence practitioners' choices, emphasizing the importance of tailored continuing education programs for improving clinical practices.
PubMed: 38827352
DOI: 10.4103/jispcd.jispcd_157_23