-
Polymers Jun 2024Fouling and biofouling remain significant challenges in seawater desalination plants. One practical approach to address these issues is to develop anti-biofouling...
Fouling and biofouling remain significant challenges in seawater desalination plants. One practical approach to address these issues is to develop anti-biofouling membranes. Therefore, novel hybrid zinc phthalocyanine/polyvinylidene fluoride-co-hexafluoropropylene (Zn(4-PPOx)Pc/PVDF-HFP) membranes were prepared by electrospinning to evaluate their properties against biofouling. The hybrid nanofiber membrane was characterized by atomic force microscopy (AFM), attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle measurements. The theoretical calculations of PVDF-HFP, Zn(4-PPOx)Pc), and Zn(4-PPOx)Pc/PVDF-HFP nanofibers were performed using a hybrid functional RB3LYP and the 6-31 G (d,p) basis set, employing Gaussian 09. DFT calculations illustrated that the calculated physical and electronic parameters ensured the feasibility of the interaction of PVDF-HFP with Zn(4-PPOx)Pc via a halogen-hydrogen bond, resulting in a highly stable and remarkably reactive structure. Moreover, molecular electrostatic potential (MEP) maps were drawn to identify the reactive regions of the Zn(4-PPOx)4Pc and PVDF-HFP/Zn(4-PPOx)4Pc nanofibers. Molecular docking analysis revealed that Zn(4-PPOx)Pc has highest binding affinity (-8.56 kcal/mol) with protein from (1N67) mainly with ten amino acids (ASP405, LYS374, GLU446, ASN406, ALA441, TYR372, LYS371, TYR448, LYS374, and ALA442). These findings highlight the promising potential of Zn(4-PPOx) Pc/PVDF-HFP nanocomposite membranes in improving the efficiency of water desalination by reducing biofouling and providing antibacterial properties.
PubMed: 38932087
DOI: 10.3390/polym16121738 -
Polymers Jun 2024In this study, we report an easy approach for the production of aqueous dispersions of C fullerene with good stability. Maleic acid copolymers, poly(styrene--maleic...
In this study, we report an easy approach for the production of aqueous dispersions of C fullerene with good stability. Maleic acid copolymers, poly(styrene--maleic acid) (SM), poly(N-vinyl-2-pyrrolidone--maleic acid) (VM) and poly(ethylene--maleic acid) (EM) were used to stabilize C fullerene molecules in an aqueous environment by forming non-covalent complexes. Polymer conjugates were prepared by mixing a solution of fullerene in N-methylpyrrolidone (NMP) with an aqueous solution of the copolymer, followed by exhaustive dialysis against water. The molar ratios of maleic acid residues in the copolymer and C were 5/1 for SM and VM and 10/1 for EM. The volume ratio of NMP and water used was 1:1.2-1.6. Water-soluble complexes (composites) dried lyophilically retained solubility in NMP and water but were practically insoluble in non-polar solvents. The optical and physical properties of the preparations were characterized by UV-Vis spectroscopy, FTIR, DLS, TGA and XPS. The average diameter of the composites in water was 120-200 nm, and the ξ-potential ranged from -16 to -20 mV. The bactericidal properties of the obtained nanostructures were studied. Toxic reagents and time-consuming procedures were not used in the preparation of water-soluble C nanocomposites stabilized by the proposed copolymers.
PubMed: 38932086
DOI: 10.3390/polym16121736 -
Polymers Jun 2024Biodegradable poly(butylene succinate--2-methyl succinate) (PBSMS)/cellulose nanocrystals (CNC) composites were successfully prepared at low CNC loadings with the aims...
Biodegradable poly(butylene succinate--2-methyl succinate) (PBSMS)/cellulose nanocrystals (CNC) composites were successfully prepared at low CNC loadings with the aims of improving crystallization and mechanical properties and extending the practical application of PBSMS. CNC is finely dispersed in the PBSMS matrix without obvious aggregations. The low content of CNC obviously promoted the crystallization behavior of PBSMS under different conditions. The spherulitic morphology study revealed that CNC, as an effective heterogeneous nucleating agent, provided more nucleation sites during the melt crystallization process. In addition, the nucleation effect of CNC was quantitatively evaluated by the following two parameters, i.e., nucleation activity and nucleation efficiency. The crystal structure and crystallization mechanism of PBSMS remained unchanged in the composites. In addition, as a reinforcing nanofiller, CNC significantly increased Young's modulus and the yield strength of PBSMS. The crystallization behavior and mechanical properties of PBSMS were significantly improved by the low content of CNC, which should be interesting and essential from the perspective of biodegradable polymer composites.
PubMed: 38932085
DOI: 10.3390/polym16121735 -
Polymers Jun 2024The antifungal agent, ketoconazole, and the anti-inflammatory drug, piroxicam, were incorporated into matrices of xanthan or oleic acid-esterified xanthan (Xn) and...
The antifungal agent, ketoconazole, and the anti-inflammatory drug, piroxicam, were incorporated into matrices of xanthan or oleic acid-esterified xanthan (Xn) and polyurethane (PU), to develop topical drug delivery systems. Compared to matrices without bioactive compounds, which only showed a nominal compressive stress of 32.18 kPa (sample xanthan-polyurethane) at a strain of 71.26%, the compressive resilience of the biomaterials increased to nearly 50.04 kPa (sample xanthan-polyurethane-ketoconazole) at a strain of 71.34%. The compressive strength decreased to around 30.67 kPa upon encapsulating a second drug within the xanthan-polyurethane framework (sample xanthan-polyurethane-piroxicam/ketoconazole), while the peak sustainable strain increased to 87.21%. The Weibull model provided the most suitable fit for the drug release kinetics. Unlike the materials based on xanthan-polyurethane, those made with oleic acid-esterified xanthan-polyurethane released the active ingredients more slowly (the release rate constant showed lower values). All the materials demonstrated antimicrobial effectiveness. Furthermore, a higher volume of piroxicam was released from oleic acid-esterified xanthan-polyurethane-piroxicam (64%) as compared to xanthan-polyurethane-piroxicam (44%). Considering these results, materials that include polyurethane and either modified or unmodified xanthan showed promise as topical drug delivery systems for releasing piroxicam and ketoconazole.
PubMed: 38932084
DOI: 10.3390/polym16121734 -
Polymers Jun 2024The bearing capacity of fiber-reinforced plastic (FRP) helical screw piles is determined by the lesser of the breaking load at the bolted joint and the resistance...
The bearing capacity of fiber-reinforced plastic (FRP) helical screw piles is determined by the lesser of the breaking load at the bolted joint and the resistance provided by the screw tip area. In this study, compression and tensile tests were performed with the number of bolts and edge distance as variables. It showed similar strength when compared to the failure stress derived from material testing. In addition, considering load resistance performance, the optimal screw cross section was obtained through parametric analysis. Considering the structural behavior of the screw, a prediction equation was presented to design the screw cross-section as a tapered cross-section using a theoretical method. As a result of comparing the screw cross-section with the finite element analysis results, it was confirmed that the design stress and analysis stress showed an error of 1.1 MPa and were within the allowable stress of 80 MPa.
PubMed: 38932083
DOI: 10.3390/polym16121733 -
Polymers Jun 2024The semiconductor-sensitized thermal cell (STC) is a new thermoelectric conversion technology. The development of nonliquid electrolytes is the top priority for the...
The semiconductor-sensitized thermal cell (STC) is a new thermoelectric conversion technology. The development of nonliquid electrolytes is the top priority for the practical application of the STC. In this study, a novel gel polymer electrolyte (PH-based GPE) composed of poly(vinylidenefluoride--hexafluoropropylene) (PH), 1-Methyl-2-pyrrolidone (NMP), and Cu ions was synthesized and applied to the STC system. The PH-based GPE synthesized at 45 °C showed higher open-circuit voltage (-0.3 V), short-circuit current density (59 μA cm) and diffusion coefficient (7.82 × 10 m s), indicating that a well-balanced structure among the NMP molecules was formed to generate a high-efficiency conduction path of the Cu ions. Moreover, the ion diffusion lengths decreased with decreasing content rates of NMP for the PH-based GPEs, indicating that the NMP plays an important role in the diffusion of Cu ions. Furthermore, the activation energy was calculated to be 107 kJ mol, and that was smaller compared to 150 kJ mol for the poly(ethylene glycol)-based liquid electrolyte. These results play an important reference role in the development of electrolytes for STC systems. At the same time, they also provide a new avenue and reference indicator for the synthesis of high-performance and safe GPEs.
PubMed: 38932082
DOI: 10.3390/polym16121732 -
Polymers Jun 2024Silver-based metal-organic decomposition inks composed of silver salts, complexing agents and volatile solvents are now the subject of much research due to the...
Silver-based metal-organic decomposition inks composed of silver salts, complexing agents and volatile solvents are now the subject of much research due to the simplicity and variability of their preparation, their high stability and their relatively low sintering temperature. The use of this type of ink in inkjet printing allows for improved cost-effective and environmentally friendly technology for the production of electrical devices, including flexible electronics. An approach to producing a silver salt-based reactive ink for jet printing has been developed. The test images were printed with an inkjet printer onto polyimide substrates, and two-stage thermal sintering was carried out at temperatures of 60 °C and 100-180 °C. The structure and electrical properties of the obtained conductive lines were investigated. As a result, under optimal conditions an electrically conductive film with low surface resistance of approximately 3 Ω/square can be formed.
PubMed: 38932081
DOI: 10.3390/polym16121731 -
Polymers Jun 2024Car manufacturers are currently challenged with increasing the sustainability of their products and production to comply with sustainability requirements and...
Car manufacturers are currently challenged with increasing the sustainability of their products and production to comply with sustainability requirements and legislation. One way to enhance product sustainability is by reducing the carbon footprint of fossil-based plastic parts. Particle foams are a promising solution to achieve the goal of using lightweight parts with minimal material input. Ongoing developments involve the use of expanded particle foam beads made from engineering plastics such as polyamide (EPA). To achieve this, a simulated life cycle was carried out on virgin EPA, including mechanical recycling. The virgin material was processed into specimens using a steam-free method. One series was artificially aged to replicate automotive life cycle stresses, while the other series was not. The mechanical recycling and re-foaming of the minipellets were then carried out, resulting in an EPA particle foam with 100% recycled content. Finally, the thermal and chemical material properties were comparatively analysed. The study shows that the recycled EPA beads underwent polymer degradation during the simulated life cycle, as evidenced by their material properties. For instance, the recycled beads showed a more heterogeneous molecular weight distribution (an increase in PDI from two to three), contained carbonyl groups, and exhibited an increase in the degree of crystallization from approximately 24% to 36%.
PubMed: 38932080
DOI: 10.3390/polym16121730 -
Polymers Jun 2024This study addresses the need for enhanced antimicrobial properties of electrospun membranes, either through surface modifications or the incorporation of antimicrobial...
This study addresses the need for enhanced antimicrobial properties of electrospun membranes, either through surface modifications or the incorporation of antimicrobial agents, which are crucial for improved clinical outcomes. In this context, chitosan-a biopolymer lauded for its biocompatibility and extracellular matrix-mimicking properties-emerges as an excellent candidate for tissue regeneration. However, fabricating chitosan nanofibers via electrospinning often challenges the preservation of their structural integrity. This research innovatively develops a chitosan/polycaprolactone (CH/PCL) composite nanofibrous membrane by employing a layer-by-layer electrospinning technique, enhanced with silver nanoparticles (AgNPs) synthesized through a wet chemical process. The antibacterial efficacy, adhesive properties, and cytotoxicity of electrospun chitosan membranes were evaluated, while also analyzing their hydrophilicity and nanofibrous structure using SEM. The resulting CH/PCL-AgNPs composite membranes retain a porous framework, achieve balanced hydrophilicity, display commendable biocompatibility, and exert broad-spectrum antibacterial activity against both Gram-negative and Gram-positive bacteria, with their efficacy correlating to the AgNP concentration. Furthermore, our data suggest that the antimicrobial efficiency of these membranes is influenced by the timed release of silver ions during the incubation period. Membranes incorporated starting with AgNPs at a concentration of 50 µg/mL effectively suppressed the growth of both microorganisms during the early stages up to 8 h of incubation. These insights underscore the potential of the developed electrospun composite membranes, with their superior antibacterial qualities, to serve as innovative solutions in the field of tissue engineering.
PubMed: 38932079
DOI: 10.3390/polym16121729 -
Polymers Jun 2024With the increasing application of electrospun PVDF webs in piezoelectric sensors and energy-harvesting devices, it is crucial to understand their responses under...
With the increasing application of electrospun PVDF webs in piezoelectric sensors and energy-harvesting devices, it is crucial to understand their responses under complex mechanical excitations. However, the dependence of the piezoelectric effect on mechanical excitation properties is not fully comprehended. This study aims to investigate the piezoelectric output of randomly oriented electrospun PVDF nanofiber webs fabricated through different electrospinning processes at various mechanical excitation frequencies. The electrospun PVDF web was sandwiched between two textile electrodes, and its piezoelectric output as a full-textile sensor was measured across a frequency range from 0.1 Hz to 10 Hz. The experimental results revealed that the piezoelectric output of the electrospun PVDF web exhibited a nearly linear increase at excitation frequencies below 1.0 Hz and then reached an almost constant value thereafter up to 10 Hz, which is different from the hybrid PVDF or its copolymer web. Furthermore, the dependency of the piezoelectric output on the excitation frequency was found to be influenced by the specific electrospinning process employed, which determined the crystalline structure of electrospun PVDF nanofibers. These findings suggest that determining an appropriate working frequency for randomly oriented electrospun PVDF nanofiber webs is essential before practical implementation, and the piezoelectric response mode in different mechanical activation frequency ranges can be used to detect different human physiological behaviors.
PubMed: 38932078
DOI: 10.3390/polym16121728