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Polymers Dec 2022Herein we report the synthesis and characterization of novel castor oil-based polyurethane (PU) foam functionalized with octadecyltrichlorosilane (C18)-modified...
Biobased Castor Oil-Based Polyurethane Foams Grafted with Octadecylsilane-Modified Diatomite for Use as Eco-Friendly and Low-Cost Sorbents for Crude Oil Clean-Up Applications.
Herein we report the synthesis and characterization of novel castor oil-based polyurethane (PU) foam functionalized with octadecyltrichlorosilane (C18)-modified diatomaceous earth (DE) particles, exhibiting superior hydrophobicity and oil adsorption, and poor water absorption, for use in effective clean-up of crude oil spillage in water bodies. High-performance and low-cost sorbents have a tremendous attraction in oil spill clean-up applications. Recent studies have focused on the use of castor oil as a significant polyol that can be used as a biodegradable and eco-friendly raw material for the synthesis of PU. However, biobased in-house synthesis of foam modified with C18-DE particles has not yet been reported. This study involves the synthesis of PU using castor oil, further modification of castor oil-based PU using C18 silane, characterization studies and elucidation of oil adsorption capacity. The FTIR analysis confirmed the fusion of C18 silane particles inside the PU skeleton by adding the new functional group, and the XRD study signified the inclusion of crystalline peaks in amorphous pristine PU foam owing to the silane cross-link structure. Thermogravimetric analysis indicated improvement in thermal stability and high residual content after chemical modification with alkyl chain moieties. The SEM and EDX analyses showed the surface's roughness and the incorporation of inorganic and organic elements into pristine PU foam. The contact angle analysis showed increased hydrophobicity of the modified PU foams treated with C18-DE particles. The oil absorption studies showed that the C18-DE-modified PU foam, in comparison with the unmodified one, exhibited a 2.91-fold increase in the oil adsorption capacity and a 3.44-fold decrease in the water absorbing nature. From these studies, it is understood that this novel foam can be considered as a potential candidate for cleaning up oil spillage on water bodies.
PubMed: 36501710
DOI: 10.3390/polym14235310 -
Polymers Dec 2022One of the key factors of supporting the rapidly expanding seafood product industry in terms of quality control is the utilization of active packaging materials....
One of the key factors of supporting the rapidly expanding seafood product industry in terms of quality control is the utilization of active packaging materials. Microorganisms are primarily responsible for the perishability and rapid disintegration of seafood. The incorporation of an inorganic compound, such as silica-based diatomaceous earth (DE), and a metal oxide, such as zinc oxide (ZnO), is proposed to develop active packaging materials with excellent antibacterial activity, minimized fishy odor, and brittleness at subzero temperatures. The mechanical, morphological, and physicochemical properties of these materials were investigated. The results show that the addition of DE/ZnO improved the antibacterial activity of high-density polyethylene (HDPE) samples by up to approximately 95% against both gram-positive and -negative bacteria. Additionally, it enhanced the Izod strength and stability at subzero temperatures of the samples. The odor evaporation test revealed that trimethylamine can be minimized in proportion to increasing DE/ZnO composite concentration. As a result, the development of active packaging materials from DE/ZnO composites is an emerging polymeric packaging technology for seafood products, wherein packaging and seafood quality are linked.
PubMed: 36501622
DOI: 10.3390/polym14235228 -
Nanomaterials (Basel, Switzerland) Dec 2022A new catalyst, copper oxide/graphene oxide-diatomaceous earth (CuO/GO-DE), was prepared by the ultrasonic impregnation method. The optimal conditions for catalyst...
A new catalyst, copper oxide/graphene oxide-diatomaceous earth (CuO/GO-DE), was prepared by the ultrasonic impregnation method. The optimal conditions for catalyst preparation were explored, and its structure and morphology were characterized by BET, XRD, SEM, TEM, FTIR, Raman and XPS. By taking ciprofloxacin as the target pollutant, the performance and reusability of CuO/GO-DE to degrade antibiotic wastewater was evaluated, and the optimal operating conditions were obtained. The main oxidizing substances in the catalytic system under different pH conditions were analyzed, as well as the synergistic catalytic oxidation mechanism. The intermediate products of ciprofloxacin degradation were identified by LC-MS, and the possible degradation process of ciprofloxacin was proposed.
PubMed: 36500928
DOI: 10.3390/nano12234305 -
Molecules (Basel, Switzerland) Nov 2022Frequent monitoring of sea food, especially shellfish samples, for the presence of biotoxins serves not only as a valuable strategy to mitigate adulteration associated...
Frequent monitoring of sea food, especially shellfish samples, for the presence of biotoxins serves not only as a valuable strategy to mitigate adulteration associated health risks, but could also be used to develop predictive models to understand algal explosion and toxin trends. Periodic toxin assessment is often restricted due to poor sensitivity, multifarious cleaning/extraction protocols and high operational costs of conventional detection methods. Through this work, a simplistic approach to quantitatively assess the presence of a representative marine neurotoxin, Domoic acid (DA), from spiked water and crab meat samples is presented. DA sensing was performed based on surface-enhanced Raman scattering (SERS) using silver nanoparticle enriched diatomaceous earth—a biological photonic crystal material in nature. Distinctive optical features of the quasi-ordered pore patterns in diatom skeleton with sporadic yet uniform functionalization of silver nanoparticles act as excellent SERS substrates with improved DA signals. Different concentrations of DA were tested on the substrates with the lowest detectable concentration being 1 ppm that falls well below the regulatory DA levels in seafood (>20 ppm). All the measurements were rapid and were performed within a measurement time of 1 min. Utilizing the measurement results, a standard calibration curve between SERS signal intensity and DA concentration was developed. The calibration curve was later utilized to predict the DA concentration from spiked Dungeness crab meat samples. SERS based quantitative assessment was further complemented with principal component analysis and partial least square regression studies. The tested methodology aims to bring forth a sensitive yet simple, economical and an extraction free routine to assess biotoxin presence in sea food samples onsite.
Topics: Silver; Metal Nanoparticles; Kainic Acid; Spectrum Analysis, Raman; Seafood
PubMed: 36500455
DOI: 10.3390/molecules27238364 -
Journal of Pesticide Science Aug 2022The common pistachio psylla, , is a serious global pest menacing pistachio orchards. Considering the dangers of using excessive chemical pesticides, it seems that using...
The common pistachio psylla, , is a serious global pest menacing pistachio orchards. Considering the dangers of using excessive chemical pesticides, it seems that using natural insecticides such as diatomaceous earth is a suitable way to lower the residual amount of highly hazardous pesticides. In this study, the effects of diatomaceous earth with different additives, including dipotassium hydrogen phosphate, polyurethane glue as a wood adhesive, and potassium silicate, were investigated in several concentrations over two years in orchard conditions. Although all treatments showed significant effects, the most effective treatments were (diatomaceous earth+dipotassium hydrogen phosphate) and (diatomaceous earth+polyurethane glue). Therefore, the use of diatomaceous earth combined with the additive materials mentioned can potentially be a safe method for the integrated management of the common pistachio psylla.
PubMed: 36479454
DOI: 10.1584/jpestics.D22-019 -
Marine Drugs Nov 2022Ocean resources are a priceless repository of unique species and bioactive compounds with denouement properties that can be used in the fabrication of advanced...
Ocean resources are a priceless repository of unique species and bioactive compounds with denouement properties that can be used in the fabrication of advanced biomaterials as new templates for supporting the cell culture envisaging tissue engineering approaches. The collagen of marine origin can be sustainably isolated from the underrated fish processing industry by-products, while silica and related materials can be found in the spicules of marine sponges and diatoms frustules. Aiming to address the potential of biomaterials composed from marine collagen and silica-based materials in the context of bone regeneration, four different 3D porous structure formulations (COL, COL:BG, COL:D.E, and COL:BS) were fabricated by freeze-drying. The skins of Atlantic cod () were used as raw materials for the collagen (COL) isolation, which was successfully characterized by SDS-PAGE, FTIR, CD, and amino acid analyses, and identified as a type I collagen, produced with a 1.5% yield and a preserved characteristic triple helix conformation. Bioactive glass 45S5 bioglass (BG), diatomaceous earth (D.E.) powder, and biosilica (BS) isolated from the sponge were chosen as silica-based materials, which were obtained as microparticles and characterized by distinct morphological features. The biomaterials revealed microporous structures, showing a porosity higher than 85%, a mean pore size range of 138-315 μm depending on their composition, with 70% interconnectivity which can be favorable for cell migration and ensure the needed nutrient supply. In vitro, biological assays were conducted by culturing L929 fibroblast-like cells, which confirmed not only the non-toxic nature of the developed biomaterials but also their capability to support cell adhesion and proliferation, particularly the COL:BS biomaterials, as observed by calcein-AM staining upon seven days of culture. Moreover, phalloidin and DAPI staining revealed well-spread cells, populating the entire construct. This study established marine collagen/silica biocomposites as potential scaffolds for tissue engineering, setting the basis for future studies, particularly envisaging the regeneration of non-load-bearing bone tissues.
Topics: Animals; Silicon Dioxide; Tissue Scaffolds; Collagen; Bone and Bones; Bone Regeneration; Biocompatible Materials; Porifera
PubMed: 36421996
DOI: 10.3390/md20110718 -
Hua Xi Kou Qiang Yi Xue Za Zhi = Huaxi... Dec 2022This work aimed to synthesize a novel injectable alginate impression material and evaluate its accuracy.
OBJECTIVES
This work aimed to synthesize a novel injectable alginate impression material and evaluate its accuracy.
METHODS
Certain proportions of sodium alginate, trisodium phosphate dodecahydrate, potassium fluorotitanate, diatomaceous earth, and other ingredients were dissolved in water and mixed evenly with a planetary centrifugal mixer to obtain a certain viscosity base paste. Certain proportions of calcium sulfate hemihydrate, magnesium oxide, glycerin, and polyethylene glycol (PEG) 400 were mixed evenly with a planetary centrifugal mixer to obtain the reactor paste with the same viscosity as the base paste. The base and reactor pastes were poured into a two-cylinder cartridge at a 2∶1 volume ratio. A gun device was used to accomplish mixing by compressing materials into a mixing tip. The samples were divided into three groups: injectable alginate impression materials (IA group) as the experimental group, and Jeltrate alginate impression materials (JA group) and Silagum-putty/light addition silicone rubber impression materials (SI group) as the two control groups.
RESULTS
Scanning electron microscopy (SEM) showed that the injectable alginate impression materials had a denser structure and fewer bubbles than the commercial alginate impression material. The accuracy of the three kinds of impression materials was evaluated by 3D image superposition. The deviations between the three test group models and the standard model (trueness) were 49.58 μm±1.453 μm (IA group), 54.75 μm±7.264 μm (JA group), and 30.92 μm±1.013 μm (SI group). The deviations of the models within each test group (precision) were 85.79 μm±8.191 μm (IA group), 97.65 μm±11.060 μm (JA group), and 56.51 μm±4.995 μm (SI group). Significant differences in trueness and precision were found among the three kinds of impression materials (<0.05).
CONCLUSIONS
The accuracy of the new injectable alginate impression material was better than that of the traditional powder-type alginate impression material but worse than that of the addition silicone rubber impression materials. The novel injec-table alginate impression material demonstrated good operation performance and impression accuracy, showing broad application prospect.
Topics: Alginates; Silicone Elastomers; Dental Impression Materials; Powders
PubMed: 36416318
DOI: 10.7518/hxkq.2022.06.006 -
Waste Management & Research : the... Apr 2023The treatment of used vegetable oil (UVO) with seven different adsorbents and through two different procedures (stirring and gravity filtration) was explored. Important...
The treatment of used vegetable oil (UVO) with seven different adsorbents and through two different procedures (stirring and gravity filtration) was explored. Important differences in terms of density, turbidity, electrical resistance, free fatty acids (FFAs) content and relative fatty acid distribution were observed. Different outcomes were shown depending both on the adsorbent and on the procedure. Lower values of density and FFAs were registered for oils treated by gravity filtration with portland (respectively 0.6% and 0.81 g/ml) and celite (respectively 0.7% and 0.72 g/ml). Considering the undesired leaching from the powder to the oil, related to the turbidity, the celite resulted more suitable for the oil recycling (241 Nephelometric Turbidity Unit (NTU) for portland vs 184 NTU for celite). In addition, Fourier-transform infrared spectroscopy combined with multivariate analysis allowed to determine a chemical fingerprint relative characteristic of vegetable oils recycled by gravity or by adsorption by stirring.
Topics: Plant Oils; Powders; Adsorption; Diatomaceous Earth; Fatty Acids; Spectroscopy, Fourier Transform Infrared
PubMed: 36382767
DOI: 10.1177/0734242X221135336 -
Polymers Oct 2022Increasing contamination risk from oil/organic liquid leakage creates strong demand for the development of absorbents with excellent hydrophobicity and absorption...
Increasing contamination risk from oil/organic liquid leakage creates strong demand for the development of absorbents with excellent hydrophobicity and absorption capacity. Herein, bagasse was carbonized to form porous char with a special structure of array-style and vertically perforated channels, and then the activation process enlarged the pore volume of the char. With the cooperation of low-surface-energy polydimethylsiloxane and diatomaceous earth particles, the modified activated carbon aerogel (MACA) was fabricated by modifying the surface coating and mastoid structure on the bagasse char. Moreover, the MACA demonstrates high porosity oil-water separation, hydrophobicity, and considerable absorption capacity (4.06-12.31 /) for gasoline and various organic solvents. This work converts agricultural waste into an efficient porous adsorbent, offering a scalable and commercially feasible solution to solving the leakages of oil/organic solvents.
PubMed: 36365572
DOI: 10.3390/polym14214579 -
Electrophoresis Feb 2023The analysis of low-abundant compounds with capillary zone electrophoresis-drift-tube ion mobility spectrometry-mass spectrometry (CZE-DTIMS-MS) is compromised due to...
The analysis of low-abundant compounds with capillary zone electrophoresis-drift-tube ion mobility spectrometry-mass spectrometry (CZE-DTIMS-MS) is compromised due to the low injectable sample volumes in CZE and low duty cycle in DTIMS. Fritless packed in-line trap columns, using solid-phase extraction sorbent particles, have been used to increase injection volumes in CZE, but these columns are difficult to prepare and exhibit rapidly increasing back pressures. To provide smooth and complete filling of trap columns as well as to ensure higher and sustained flow rates though the columns, blends of cation and anion exchange particles with diatomite were used. The application of diatomite blends ensured the use of trap columns for at least 100 injections, with maximum injection volumes over 10 µl, which corresponds to an enrichment factor of more than 1000 over conventional injections in CZE-MS, enabling the detection of low nM concentrations of N-glycans with CZE-IMS-MS.
Topics: Proteomics; Mass Spectrometry; Electrophoresis, Capillary; Diatomaceous Earth
PubMed: 36333917
DOI: 10.1002/elps.202200189