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Scientific Reports May 2024Due to the high volume of wastewater produced from dairy factories, it is necessary to integrate a water recovery process with the treatment plant. Today, bipolar...
Due to the high volume of wastewater produced from dairy factories, it is necessary to integrate a water recovery process with the treatment plant. Today, bipolar membrane electrodialysis units (BMEUs) are increasingly developed for wastewater treatment and reutilizing. This article aims to develop and evaluate (technical and cost analyses) a combined BMEU/batch reverse osmosis unit (BROU) process for the recovery of chemicals and water from the dairy wastewater plant. The combined BROU/BMEU process is able to simultaneously produce water and strong base-acid, and reduce power consumption due to the injection of concentrated feed flow into the BMEU. A comprehensive comparative analysis on the performances of two combined and stand-alone BMEU configurations are developed. The proposed combined technology for dairy factory wastewater treatment is designed on a new structure and configuration that can address superior cost analysis compared to similar technologies. Further, the optimal values of permeate flux and current density as two vital and influencing parameters on the performance of the studied dairy wastewater treatment process were calculated and discussed. From the outcomes, the total cost of production in the combined configuration has been reduced by approximately 26% compared to the stand-alone configuration. Increasing the feed concentration rate using the batch reverse osmosis process for the dairy wastewater treatment process can be an ideal solution from an economic point of view. Moreover, point (current density, feed concentration rate, total unit cost) = can be considered as an optimal point for the economic performance of the studied wastewater treatment process.
PubMed: 38750120
DOI: 10.1038/s41598-024-61699-8 -
Water Science and Technology : a... May 2024Electroplating wastewater contains heavy metal ions and organic matter. These contaminants not only endanger the environment but also pose risks to human health. Despite...
Electroplating wastewater contains heavy metal ions and organic matter. These contaminants not only endanger the environment but also pose risks to human health. Despite the development of various treatment processes such as chemical precipitation MBR, electrocoagulation (EC) ceramic membrane (CM), coagulation ultrafiltration (UF) reverse osmosis (RO), and CM RO. These methods are only effective for low concentrations of heavy metals and struggle with high concentrations. To address the challenge of treating electroplating wastewater with high heavy metal content, this study focuses on the wastewater from Dongfang Aviation Machinery Processing Plant. It introduces an EC and integrated membrane (IM) treatment process for electroplating wastewater. The IM comprises microfiltration (MF) membrane, nanofiltration (NF) membrane, and RO membrane. Results indicated that under specific conditions, such as a pH of 8, current density of 5 A/dm, electrode plate spacing of 2 cm, 35 min of electrolysis time, and influent pH of 10 for the IM, removal rates of Zn, Cu, Ni, and TCr in the wastewater exceeded 99%. The removal rates of chemical oxygen demand (COD), suspended solids (SS), total phosphorus (TP), total nitrogen (TN), and petroleum in wastewater exceed 97%. Following a continuous cleaning process, the membrane flux can consistently recover to over 94.3%.
Topics: Membranes, Artificial; Wastewater; Waste Disposal, Fluid; Water Pollutants, Chemical; Electroplating; Water Purification; Metals, Heavy; Electrocoagulation
PubMed: 38747966
DOI: 10.2166/wst.2024.136 -
Water Science and Technology : a... May 2024In this study, a multi-functional layer was developed based on the commercially available cellulose triacetate (CTA) forward osmosis (FO) membrane to improve its...
In this study, a multi-functional layer was developed based on the commercially available cellulose triacetate (CTA) forward osmosis (FO) membrane to improve its antifouling property. Tannic acid/ferric ion (TA/Fe) complexes were firstly coated as a precursor layer on the membrane surface via self-assembly. Afterwards, the tannic acid/diethylenetriamine (TA/DETA) hydrophilic functional layer was further coated, following Ag/polyvinylpyrrolidone (PVP) anti-bacterial layer was formed through the reducibility of TA to obtain TA/Fe-TA/DETA-Ag/PVP-modified membrane. The optimized precursor layer was acquired by adjusting the buffer solution pH to 8, TA/Fe ratio to 4 and the number of self-assembled layers to 5. The permeability testing results illustrated that the functional layer had an insignificant effect on the membrane transport parameters. The TA/Fe-TA/DETA-Ag/PVP-modified membrane simultaneously exhibited excellent physical and chemical stability. The coated membrane also demonstrated enhanced anti-bacterial properties, achieving 98.63 and 97.30% inhibition against and , respectively. Furthermore, the dynamic fouling experiment showed a 12% higher water flux decrease for the TA/Fe-TA/DETA-Ag/PVP CTA membrane compared to the nascent CTA membrane, which proved its excellent antifouling performance. This work provides a feasible strategy to heighten the antifouling property of the CTA FO membrane.
Topics: Membranes, Artificial; Osmosis; Biofouling; Staphylococcus aureus; Escherichia coli; Tannins; Phenols; Anti-Bacterial Agents; Water Purification
PubMed: 38747962
DOI: 10.2166/wst.2024.129 -
Water Science and Technology : a... May 2024In the face of growing global freshwater scarcity, the imperative to recycle and reuse water becomes increasingly apparent across industrial, agricultural, and domestic... (Review)
Review
In the face of growing global freshwater scarcity, the imperative to recycle and reuse water becomes increasingly apparent across industrial, agricultural, and domestic sectors. Eliminating a range of organic pollutants in wastewater, from pesticides to industrial byproducts, presents a formidable challenge. Among the potential solutions, membrane technologies emerge as promising contenders for treating diverse organic contaminants from industrial, agricultural, and household origins. This paper explores cutting-edge membrane-based approaches, including reverse osmosis, nanofiltration, ultrafiltration, microfiltration, gas separation membranes, and pervaporation. Each technology's efficacy in removing distinct organic pollutants while producing purified water is scrutinized. This review delves into membrane fouling, discussing its influencing factors and preventative strategies. It sheds light on the merits, limitations, and prospects of these various membrane techniques, contributing to the advancement of wastewater treatment. It advocates for future research in membrane technology with a focus on fouling control and the development of energy-efficient devices. Interdisciplinary collaboration among researchers, engineers, policymakers, and industry players is vital for shaping water purification innovation. Ongoing research and collaboration position us to fulfill the promise of accessible, clean water for all.
Topics: Membranes, Artificial; Water Purification; Water Pollutants, Chemical; Waste Disposal, Fluid; Filtration; Ultrafiltration; Organic Chemicals
PubMed: 38747950
DOI: 10.2166/wst.2024.117 -
Global Challenges (Hoboken, NJ) May 2024The acute water and electricity shortages in Gaza necessitate comprehensive solutions that recognize the interconnected nature of these vital resources. This article...
The acute water and electricity shortages in Gaza necessitate comprehensive solutions that recognize the interconnected nature of these vital resources. This article presents pragmatic solutions to align supply with fundamental needs in both domains, offering viable pathways for achieving strategic water-energy security in Gaza. Baseline data reveals a deficit in the current water supply, falling below the international minimum of 100 L per capita per day, while the reported 137-189 MW per day electricity supply significantly lags behind the estimated 390 MW per day peak demand. To meet projected 2024 residential, commercial, and industrial demands, this study proposes actionable measures including expanding wastewater treatment to enable over 150 MCM per year tertiary effluents for agricultural reuse and adopting energy-efficient forward osmosis-reverse osmosis and osmotically assisted reverse osmosis desalination methods to increase potable water supply to 150 MCM per year. Electricity supply strategies include scaling renewable capacity towards 110 MW per day, exploring regional cooperation to unlock over 360 MW of power per day, and potentially recovering up to 60 MW per day through system efficiencies. These recommendations aim to prevent exacerbated scarcity and alleviate hardships in Gaza.
PubMed: 38745562
DOI: 10.1002/gch2.202300304 -
Food Chemistry Sep 2024Fish protein hydrolysates (FPH) are inherently unstable in their liquid form, necessitating either freezing or dewatering for stabilization. Gentle methods such as... (Review)
Review
Fish protein hydrolysates (FPH) are inherently unstable in their liquid form, necessitating either freezing or dewatering for stabilization. Gentle methods such as freeze concentration can be used to remove water, this can be achieved by freezing water in solution by decreasing the bulk temperature below freezing point and separating pure ice crystals from concentrated solution. This approach serves as an alternative to techniques like evaporation and reverse osmosis for concentrating solutions that have high water content, significant nutritional value, and thermolabile compounds. This is crucial as many bioactive compounds degrade when exposed to elevated temperatures. Another notable advantage of this technology is its potential to reduce energy consumption by up to 40% when integrated into the FPH drying process. Although this technology is currently industrialized primarily for juices, it can achieve concentrations of up to 60°Brix and manage viscosities up to 400 mPa.s. Numerous studies have been dedicated to enhancing design and processes, leading to a 35% reduction in the system's capital cost and a 20% reduction in energy consumption. Moreover, freeze concentration can synergize with other concentration techniques, creating more efficient hybrid processes. This review aims to introduce freeze concentration as a superior option for preserving fish protein hydrolysates, enhancing their stability, and maintaining their nutritional and bioactive qualities.
Topics: Protein Hydrolysates; Freezing; Fish Proteins; Animals; Fishes; Protein Stability; Food Handling
PubMed: 38744134
DOI: 10.1016/j.foodchem.2024.139559 -
Water Research Jun 2024The human urine metabolome is complex, containing a wide range of organic metabolites that affect treatment of urine collected in resource-oriented sanitation systems....
The human urine metabolome is complex, containing a wide range of organic metabolites that affect treatment of urine collected in resource-oriented sanitation systems. In this study, an advanced oxidation process involving heat-activated peroxydisulphate was used to selectively oxidise organic metabolites in urine over urea and chloride. Initial experiments evaluated optimal conditions (peroxydisulphate dose, temperature, time, pH) for activation of peroxydisulphate in unconcentrated, non-hydrolysed synthetic urine and real urine acidified to pH 3.0. Subsequent experiments determined the fate of 268 endogenous organic metabolites (OMs) and removal of COD from unconcentrated and concentrated real urine (80-90% mass reduced by evaporation). The results revealed >90% activation of 60 mM peroxydisulphate in real unconcentrated urine heated to 90 °C for 1 h, resulting in 43% ΣOMs degradation, 22% COD removal and 56% total organic carbon removal, while >94% of total nitrogen and >97% of urea in real unconcentrated urine were recovered. The mechanism of urea degradation was identified to be chemical hydrolysis to ammonia, with the rate constant for this reaction determined to be 1.9 × 10 s at pH 3.0 and 90 °C. Treating concentrated real urine resulted in similar removal of COD, ΣOMs degradation and total nitrogen loss as observed for unconcentrated urine, but with significantly higher chloride oxidation and chemical hydrolysis of urea. Targeted metabolomic analysis revealed that peroxydisulphate treatment degraded 157 organic metabolites in urine, of which 67 metabolites were degraded by >80%. The rate constant for the reaction of sulphate radicals with oxidisable endogenous organic metabolites in urine was estimated to exceed 10 M s. These metabolites were preferentially oxidised over chloride and urea in acidified, non-hydrolysed urine treated with peroxydisulphate. Overall, the findings support the development of emerging urine recycling technologies, including alkaline/acid dehydration and reverse osmosis, where the presence of endogenous organic urine metabolites significantly influences treatment parameters such as energy demand and product purity.
Topics: Humans; Oxidation-Reduction; Urine; Sulfates; Hydrogen-Ion Concentration; Urea
PubMed: 38744062
DOI: 10.1016/j.watres.2024.121751 -
The Science of the Total Environment Jul 2024The use of water purifiers is intensively catching up and disposing of reverse osmosis reject water is of great concern. Reject water management using conventional...
The use of water purifiers is intensively catching up and disposing of reverse osmosis reject water is of great concern. Reject water management using conventional methods is costly and harmful to the environment. To address this issue, the present study aims to utilize reverse osmosis reject wastewater using an eco-friendly approach. Juncus rigidus was treated with reject wastewater containing different salinity levels. Wastewater-treated plant dry biomass increased with increasing reject water salinity, and 625.3 g dry biomass recovered in treatment-B (~18,520 ppm). However, ~23,220 ppm wastewater salinity was lethal to the plants. The cellulose was extracted by alkali hydrolysis. The cellulose content in the wastewater-treated biomass was significantly higher in Treatment-B compared to both the control and Treatment-A (~12,744 ppm). The water salinity enhanced the cellulose (26.49 %) production in J. rigidus. Cellulose purity was confirmed using spectroscopic and thermogravimetric means. XRD shows highest crystallinity Index (77.29) with a d-spacing of 4.7 Å and 5.7 nm crystallite size in treatment-B. FTIR results reveal well-defined relevant peaks for OH, CH, CO, CH, C-O-C, CO groups in treatment-B cellulose. Salinity impacts carboxyl groups in treatment B cellulose with a sharper and intense peak at 1644 cm responsible for water absorption. Treatment-B exhibits higher thermal stability due to increased crystallinity. DSC shows endothermic depolymerization of cellulose with distinct peaks for different treatments. Morphological traits got better with increasing salinity with no adverse effect on cellulose. Salinity moderately affected the water absorption capacity of cellulose. All cellulose samples were devoid of gram-negative bacteria known by microbial test. This pioneering work underscores the plant's remarkable capacity not only to accomplish the circular economy by the valorization of wastewater obtained from various water purifiers for Juncus cultivation for cellulose production for diverse applications but also to generate income from wastewater.
Topics: Cellulose; Wastewater; Biomass; Waste Disposal, Fluid; Salinity; Salt Stress
PubMed: 38734100
DOI: 10.1016/j.scitotenv.2024.173076 -
Foods (Basel, Switzerland) Apr 2024Mushroom production and consumption are gaining increased interest due to their unique flavor and nutritional value. However, in the mushroom industry, large amounts of...
Mushroom production and consumption are gaining increased interest due to their unique flavor and nutritional value. However, in the mushroom industry, large amounts of by-products are generated, which have a high negative environmental and economic impact. In this study, an osmotic dehydration process followed by hot-air-drying was applied to mushroom stems to produce dried mushrooms as the end product. The osmotic dehydration conditions (concentration of hypertonic solution, specifically, 10-30% maltodextrin and 20-40% oligofructose; a treatment time of 40-80 min; and a temperature range of 30-50 °C) were optimized using response surface methodology (RSM). The results showed that a four-factor three-level Box-Behnken experimental design was effectively implemented to evaluate the effect of the process parameters and identify the optimal osmotic dehydration conditions for producing osmotically dehydrated mushrooms. The main factor affecting mass transfer was the osmosis temperature, and the optimal conditions were found to be 38 °C, 40% oligofructose and 19.3% maltodextrin as the osmotic agents, and 80 min of immersion time. Moreover, the results showed that osmotic pretreatment, in the optimal conditions, significantly reduced the required drying time of the by-products compared to traditional hot-air-drying, especially at milder drying temperatures. Consequently, the required energy was also reduced by at least 40% at 50 °C.
PubMed: 38731710
DOI: 10.3390/foods13091339 -
Water Research Jun 2024This study designs a novel electroneutralization desalination cell using reaction heat from acidic-alkaline wastewater neutralization to desalinate wastewater and...
This study designs a novel electroneutralization desalination cell using reaction heat from acidic-alkaline wastewater neutralization to desalinate wastewater and generates chemoelectric power. Several key performance indicators are measured in terms of the energy, environmental and economic aspects of the system, including the ionic flux, the electrical energy produced, the electrical energy consumption for desalination, parasitic losses, overall energy conversion efficiency and desalination performance. The maximum peak power density is ∼31.5 mW/cm at 83.5 mA/cm and the desalination efficiency is 62 % using brine. The overall energy conversion efficiency is ∼81.8 % and the desalination followed the zero-order reaction. Assuming a 1.5 million litres per day treatment capacity integrated with reverse osmosis, the system has environmental and economic benefits, with 44.5 kg-CO₂eq greenhouse gas emissions per cubic meter of treated brine, and a discounted payback period of 4.2 years. This study demonstrates a pioneering electroneutralization technique for self-sufficient brine valorization and wastewater reclamation.
Topics: Water Purification; Wastewater; Salinity; Electricity; Waste Disposal, Fluid; Salts; Osmosis
PubMed: 38728780
DOI: 10.1016/j.watres.2024.121720