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Nature Communications Jun 2024Surface observations suggest that carbon may exist in Mercury’s interior. Under planetary mantle pressures and temperatures, carbon may be present as a stable diamond...
Surface observations suggest that carbon may exist in Mercury’s interior. Under planetary mantle pressures and temperatures, carbon may be present as a stable diamond layer which may have important implications for the physical and chemical properties of Mercury.
PubMed: 38877013
DOI: 10.1038/s41467-024-49497-2 -
PloS One 2024Magnetic MnFe2O4 nanoparticles were successfully prepared by the rapid combustion method at 500 °C for 2 h with 30 mL absolute ethanol, and were characterized by SEM,...
Magnetic MnFe2O4 nanoparticles were successfully prepared by the rapid combustion method at 500 °C for 2 h with 30 mL absolute ethanol, and were characterized by SEM, TEM, XRD, VSM, and XPS techniques, their average particle size and the saturation magnetization were about 25.3 nm and 79.53 A·m2/kg, respectively. The magnetic MnFe2O4 nanoparticles were employed in a fixed bed experimental system to investigate the adsorption capacity of Hg0 from air. The MnFe2O4 nanoparticles exhibited the large adsorption performance on Hg0 with the adsorption capacity of 16.27 μg/g at the adsorption temperature of 50 °C with the space velocity of 4.8×104 h-1. The VSM and EDS results illustrated that the prepared MnFe2O4 nanoparticles were stable before and after adsorption and successfully adsorbed Hg0. The TG curves demonstrated that the mercury compound formed after adsorption was HgO, and both physical and chemical adsorption processes were observed. Magnetic MnFe2O4 nanoparticles revealed excellent adsorbance of Hg0 in air, which suggested that MnFe2O4 nanoparticles be promising for the removal of Hg0.
Topics: Adsorption; Mercury; Manganese Compounds; Ferric Compounds; Gases; Particle Size; Temperature
PubMed: 38875253
DOI: 10.1371/journal.pone.0304333 -
Heliyon Jun 2024This study conducted in the Kyungpook National University Eco-friendly Agriculture Research Centre between 2022 and 2023 investigates the environmental implications of...
This study conducted in the Kyungpook National University Eco-friendly Agriculture Research Centre between 2022 and 2023 investigates the environmental implications of fence-type solar photovoltaic (PV) systems in diverse agricultural settings. Despite the increasing adoption of solar energy for climate change mitigation, there is a noticeable gap in research regarding the potential environmental impact of these specific PV systems. Focusing on heavy metal concentrations, including Cadmium (Cd), Copper (Cu), Arsenic (As), Mercury (Hg), Lead (Pb), Hexavalent Chromium (Cr), Zinc (Zn), and Nickel (Ni), across distinct fields, the study reveals significant fluctuations. Notably, the Rice Field experienced a substantial increase in Cd levels from 0.47 mg/kg in 2022 to 1.55 mg/kg in 2023, while Cu and Pb concentrations decreased to acceptable levels in 2023. The findings underscore the dynamic nature of heavy metal concentrations, emphasizing the importance of continuous soil quality monitoring to prevent contamination. This research provides valuable insights into the impact of fence-type solar PV system installations on agricultural soil quality, emphasizing the urgent need to secure these ecosystems through vigilant monitoring and environmental management practices.
PubMed: 38873682
DOI: 10.1016/j.heliyon.2024.e32156 -
RSC Advances Jun 2024Mercury, a widespread highly toxic environmental pollutant, poses significant risks to both human health and ecosystems. It commonly infiltrates the food chain,... (Review)
Review
Mercury, a widespread highly toxic environmental pollutant, poses significant risks to both human health and ecosystems. It commonly infiltrates the food chain, particularly through fish, and water resources multiple pathways, leading to adverse impacts on human health and the environment. To monitor and keep track of mercury ion levels various methods traditionally have been employed. However, conventional detection techniques are often hindered by limitations. In response to challenges, nano-sensors, capitalizing on the distinctive properties of nanomaterials, emerge as a promising solution. This comprehensive review provides insight into the extensive spectrum of nano-sensor development for mercury detection. It encompasses various types of nanomaterials such as silver, gold, silica, magnetic, quantum dot, carbon dot, and electrochemical variants, elucidating their sensing mechanisms and fabrication. The aim of this review is to offer an in-depth exploration to researchers, technologists, and the scientific community, and understanding of the evolving landscape in nano-sensor development for mercury sensing. Ultimately, this review aims to encourage innovation in the pursuit of efficient and reliable solutions for mercury detection, thereby contributing to advancements in environmental protection and public health.
PubMed: 38873550
DOI: 10.1039/d4ra02787f -
Frontiers in Public Health 2024Rapid urbanization a major factor affecting heavy metal contamination on suburban agricultural soils. In order to assess the dynamic contamination of heavy metals in...
Quantification of sources and potential risks of cadmium, chromium, lead, mercury and arsenic in agricultural soils in a rapidly urbanizing region of southwest China: the case of Chengdu.
Rapid urbanization a major factor affecting heavy metal contamination on suburban agricultural soils. In order to assess the dynamic contamination of heavy metals in soil from agricultural land bordering a rapidly urbanizing area and the transfer of human health risks from contaminants in this process, 186 and 293 soil samples from agricultural land in suburban Chengdu were collected in September 2008 and September 2017, respectively. Several indicators, such as the integrated pollution index (PI) and the potential ecological risk index (RI), were employed for analyzing the heavy metal contamination levels, and the APCS-MLR receptor model were applied for analyzing the heavy metal sources. As a result, mean concentrations for five elements did not exceed the national soil pollution risk screening values in the two periods mentioned above. Nemerow's composite contamination index revealed an increase in soil contamination of arable land after 10 years of urbanization, with 3.75 and 1.02% of light and moderate sample plots, respectively, by 2017. The assessment for potential ecological risk indicated an increased level of eco-risk to high for most of the sample plots. Based on the APCS-MLR model, the origin and contribution to the five elements varied considerably between the two periods mentioned above. Among them, soil Pb changed from "industrial source" to "transportation source," soil Cr changed from "natural source" to "transportation source," and As and Hg changed from "industrial source" to "transportation source." As and Hg were associated with agricultural activities in both periods, and Cd was derived from industrial activities in both periods. The study suggests that inhalation has become a major contributor to non-cancer health risks in urbanization, unlike intake routes in previous periods, and that the increase in cancer risk is mainly due to children's consumption of agricultural products with As residues. The change in the main source of As to "transportation" also indicates a decrease in air quality during urbanization and the development of the transportation industry. This study provides a reference for the governments of rapidly urbanizing cities to formulate relevant highway and agricultural policies to safeguard the health of the people based on the current situation.
Topics: Soil Pollutants; China; Urbanization; Agriculture; Mercury; Humans; Environmental Monitoring; Cadmium; Arsenic; Lead; Risk Assessment; Metals, Heavy; Chromium; Soil
PubMed: 38873303
DOI: 10.3389/fpubh.2024.1400921 -
Ecotoxicology and Environmental Safety Jul 2024Boreal peatlands are "hotspots" of net methylmercury (MeHg) production and may become drier in the future due to climate change. This study investigates a critical gap...
Boreal peatlands are "hotspots" of net methylmercury (MeHg) production and may become drier in the future due to climate change. This study investigates a critical gap by analyzing the nuanced relationship between soil moisture content and the release of MeHg, inorganic mercury (IHg), sulfate (SO), and dissolved organic matter (DOM) in a laboratory incubation of boreal peat soils. Dried peat soils exhibited heightened releases of IHg, MeHg, and SO during re-wetting events. Both dried and saturated peat soils released more DOM than moist peat soils during re-wetting events, and DOM released from dried soils had higher bioaccessibility than that from the saturated soils (p<0.05). There was an equilibrium of IHg concentrations between peat soils and pore waters, but long-term severe drought may disrupt this equilibrium and then release more IHg to pore waters during re-wetting events. Contrary to expectations, positive relationships between IHg concentrations and SUVA did not exist in all treatments. MeHg and SO were depleted quickly because there was no external input of Hg and SO to this static system. More bioaccessible DOM than aromatic DOM was released from peat soils with different soil moisture contents after 32 weeks during the re-wetting event (p<0.05). These results imply that re-wetting of peat soils after droughts can increase the release of MeHg from peat soils and may also increase net MeHg production due to the release of SO and bioaccessible DOM from peat soils, reshaping our understanding of soil moisture's role in mercury dynamics. This novel insight into soil moisture and MeHg dynamics carries significant implications for mitigating mercury contamination in aquatic ecosystems.
Topics: Methylmercury Compounds; Soil; Mercury; Soil Pollutants; Environmental Monitoring; Water; Climate Change; Water Pollutants, Chemical
PubMed: 38870737
DOI: 10.1016/j.ecoenv.2024.116573 -
Nanomaterials (Basel, Switzerland) Jun 2024Soil plays a crucial role in human health through its impact on food and habitation. However, it often contains toxic heavy metals, with mercury being particularly...
Soil plays a crucial role in human health through its impact on food and habitation. However, it often contains toxic heavy metals, with mercury being particularly hazardous when methylated. Currently, high-sensitivity, rapid detection of mercury is achievable only through electrochemical measurements. These measurements require pretreatment of the soil sample and the preparation of a calibration curve tailored to the sample's condition. In this study, we developed a method to determine the environmental standard value of mercury content in soil by significantly reducing the pretreatment process. Our approach involves analyzing current peaks from electrodeposition times using specific electrodes and solvent settings. This method demonstrates low error rates under low concentration conditions and can detect mercury levels as low as 0.5 ppb in soil leachate and reagent dilution series. This research facilitates the determination of low mercury concentrations in solutions containing various soil micro-compounds without the need for calibration curves.
PubMed: 38869606
DOI: 10.3390/nano14110981 -
The Journal of Physical Chemistry. C,... Jun 2024Transition metal thiophosphates (MPS) are of great interest due to their layered structure and magnetic properties. Although HgPS may not exhibit magnetic properties,...
Transition metal thiophosphates (MPS) are of great interest due to their layered structure and magnetic properties. Although HgPS may not exhibit magnetic properties, its uniqueness lies in its triclinic crystal structure and in the substantial mass of mercury, rendering it a compelling subject for exploration in terms of fundamental properties. In this work, we present comprehensive experimental and theoretical studies of the electronic band structure and optical properties for the HgPS crystal and mechanically exfoliated layers from a solid crystal. Based on absorption, reflectance and photoluminescence measurements supported by theoretical calculations, it is shown that the HgPS crystal has an indirect gap of 2.68 eV at room temperature. The direct gap is identified at the Γ point of the Brillouin zone (BZ) ≈ 50 meV above the indirect gap. The optical transition at the Γ point is forbidden due to selection rules, but the oscillator strength near the Γ point increases rapidly and therefore the direct optical transitions are visible in the reflectance spectra approximately at 60-120 meV above the absorption edge, across the temperature range of 40 to 300 K. The indirect nature of the bandgap and the selection rules for Γ point contribute to the absence of near-bandgap emission in HgPS. Consequently, the photoluminescence spectrum is primarily governed by defect-related emission. The electronic band structure of HgPS undergoes significant changes when the crystal thickness is reduced to tri- and bilayers, resulting in a direct bandgap. Interestingly, in the monolayer regime, the fundamental transition is again indirect. The layered structure of the HgPS crystal was confirmed by scanning electron microscopy (SEM) and by mechanical exfoliation.
PubMed: 38864003
DOI: 10.1021/acs.jpcc.4c00562 -
NPJ Microgravity Jun 2024Short-term spaceflight is commonly perceived as posing minimal risk to human health and performance. However, despite their duration, short-term flights potentially...
Short-term spaceflight is commonly perceived as posing minimal risk to human health and performance. However, despite their duration, short-term flights potentially induce acute physiological changes that create risk to crews. One such change is dehydration (primarily body water loss) due to a heat-stressed environment. Such loss, if severe and prolonged, can lead to decrements in performance as well as increase the risk of more serious medical conditions. Though the general mechanisms of dehydration are broadly understood, the rate and extent of dehydration in short-term spaceflight has not been characterized. Combining data from the six spaceflights of the US Mercury program with a causal diagram illustrating the mechanisms of dehydration, we fit a path model to estimate the causal effects for all pathways in the causal model. Results demonstrate that Mercury astronauts experienced some degree of dehydration across the range of suited time and that the relationship between suited time and dehydration appears to be logarithmic. We discuss causal interpretations of the results and how the results from this and similar analyses can inform countermeasure development for short-term spaceflight.
PubMed: 38862554
DOI: 10.1038/s41526-024-00374-8 -
Pharmacological Research Jul 2024Nonalcoholic fatty liver disease (NAFLD) is one of the leading causes of chronic liver disease worldwide. Epidemiological studies have reported that exposure of the... (Meta-Analysis)
Meta-Analysis Review
Nonalcoholic fatty liver disease (NAFLD) is one of the leading causes of chronic liver disease worldwide. Epidemiological studies have reported that exposure of the population to environmental endocrine-disrupting chemicals (EDCs) is associated with NAFLD. However, EDCs are of different types, and there are inconsistencies in the relevant evidence and descriptions, which have not been systematically summarized so far. Therefore, this study aimed to determine the association between population exposure to EDCs and NAFLD. Three databases, including PubMed, Web of science, and Embase were searched, and 27 articles were included in this study. Methodological quality, heterogeneity, and publication bias of the included studies were assessed using the Newcastle-Ottawa scale, I statistics, Begg's test, and Egger's test. The estimated effect sizes of the included studies were pooled and evaluated using the random-effects model (I > 50 %) and the fixed-effects model ( I < 50 %). The pooled-estimate effect sizes showed that population exposure to Phthalates (PAEs) (OR = 1.18, 95 % CI:1.03-1.34), cadmium (Cd) (OR = 1.37, 95 % CI:1.09-1.72), and bisphenol A (OR = 1.43, 95 % CI:1.24-1.65) were positively correlated with the risk of NAFLD. Exposure to mercury (OR =1.46, 95 % CI:1.17-1.84) and Cd increased the risk of "elevated alanine aminotransferase". On the contrary, no significant association was identified between perfluoroalkyl substances (OR =0.99, 95 % CI:0.93-1.06) and NAFLD. However, female exposure to perfluorooctanoic acid (OR =1.82, 95 % CI:1.01-3.26) led to a higher risk of NAFLD than male exposure. In conclusion, this study revealed that EDCs were risk factors for NAFLD. Nonetheless, the sensitivity analysis results of some of the meta-analyses were not stable and demonstrated high heterogeneity. The evidence for these associations is limited, and more large-scale population-based studies are required to confirm these findings.
Topics: Non-alcoholic Fatty Liver Disease; Humans; Endocrine Disruptors; Phthalic Acids; Environmental Pollutants; Phenols; Benzhydryl Compounds; Cadmium; Fluorocarbons
PubMed: 38862070
DOI: 10.1016/j.phrs.2024.107251