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Water Research Jul 2022Global phosphorus reserves are under pressure of depletion in the near future due to increased consumption of primary phosphorus reservoirs and improper management of... (Review)
Review
Global phosphorus reserves are under pressure of depletion in the near future due to increased consumption of primary phosphorus reservoirs and improper management of phosphorus. At the same time, a considerable portion of global marine water bodies has been suffering from eutrophication due to excessive nutrient loading. The marine environment can be considered as a valuable phosphorus source due to nutrient rich eutrophic seawater and sediment which could potentially serve as phosphorus mines in the near future. Hence, sustainable phosphorus recovery strategies should be adapted for marine systems to provide phosphorus for the growing market demand and simultaneously control eutrophication. In this review, possible sustainable strategies for phosphorus removal and recovery from marine environments are discussed in detail. Bio-based strategies relying on natural phosphorus uptake/release metabolism of living organisms are suggested as promising options that can provide both phosphorus removal and recovery from marine waters for achieving a sustainable marine ecosystem. Among them, the utilization of microorganisms seems promising to develop novel strategies. However, the research gap for the technical applicability of these strategies is still considerably big. Therefore, future research should focus on the technical development of the strategies through laboratory and/or field studies. Coupling phosphorus mining with other valorisation pathways (i.e., metal recovery, energy production) is also suggested to improve overall sustainability and economic viability. Environmental, economic and societal challenges should altogether be well addressed prior to real scale applications.
Topics: Ecosystem; Eutrophication; Mining; Nitrogen; Phosphorus; Seawater
PubMed: 35561625
DOI: 10.1016/j.watres.2022.118505 -
Journal of Theoretical Biology Jan 2022Internal phosphorus recycling in lakes is an important nutrient source that promotes algal growth. Its persistence impedes the effort to improve water quality and thus...
Internal phosphorus recycling in lakes is an important nutrient source that promotes algal growth. Its persistence impedes the effort to improve water quality and thus poses a challenge to the management of eutrophication in lakes, especially in shallow lakes where the occurrence of internal phosphorus recycling is reportedly more common. This paper aims to provide crucial insights on the effects of internal phosphorus recycling on eutrophication dynamics for effective management of lake eutrophication. For this purpose, a mathematical model for lake eutrophication, comprising two compartments of algae and phosphorus, is first formulated for application to a eutrophic tropical lake named Tasik Harapan in Universiti Sains Malaysia. Numerical bifurcation analysis of the model is then performed to assess the combined influences of internal phosphorus recycling, algal mortality and external phosphorus loading on Tasik Harapan eutrophication dynamics. Specifically, co-dimension one bifurcation analysis of algal mortality rate is carried out by means of XPPAUT for various external phosphorus loading rates. The emergence of limit cycle for a certain range of algal mortality rate could be related to the hydra effect (i.e., algal concentration increases in response to greater algal mortality) and the paradox of enrichment (i.e., destabilization of algae in nutrient rich environment). To trace the locus of co-dimension one bifurcation, co-dimension two bifurcation analysis is performed by means of MatCont. The analysis demonstrated that the inclusion of the internal phosphorus recycling term induces rich and complex dynamics of the model. These dynamics include saddle-node bifurcation, cusp, Bogdanov-Takens bifurcation, Generalized Hopf bifurcation and limit point bifurcation of cycles. The results suggest that high internal phosphorus recycling rate promotes bistability and catastrophic shift in a shallow and tropical lake like Tasik Harapan. Hence, the key to effective management of eutrophication in shallow and tropical lakes is the control of internal phosphorus recycling.
Topics: China; Environmental Monitoring; Eutrophication; Lakes; Nutrients; Phosphorus
PubMed: 34562459
DOI: 10.1016/j.jtbi.2021.110913 -
Advances in Nutrition (Bethesda, Md.) Nov 2015
Topics: Adolescent; Adult; Aged; Child; Diet; Female; Food; Humans; Male; Middle Aged; Nutrition Policy; Nutrition Surveys; Nutritional Requirements; Phosphorus; Phosphorus, Dietary; Young Adult
PubMed: 26567206
DOI: 10.3945/an.115.008516 -
ChemistryOpen Nov 2022The substitution reaction of phosphinates with a binaphthyloxy group at the phosphorus atom with lithium alkoxides proceeded with good to high efficiencies to give...
The substitution reaction of phosphinates with a binaphthyloxy group at the phosphorus atom with lithium alkoxides proceeded with good to high efficiencies to give P-chirogenic phosphinates with a high enantiomeric ratio. As alcohols, primary, secondary, and tertiary alcohols could be used, and the use of tert-butyl alcohol yielded the products with a higher enantiomeric ratio. A substrate with two different alkyl groups on the phosphorus atom could also participate in the substitution reaction to give the corresponding products in good yields with excellent selectivity. The molecular structures of one of the substrates and the corresponding products, determined by X-ray analyses, proved that the substitution reaction at the phosphorus atom proceeded with inversion of the absolute configuration. The usefulness of the reaction was demonstrated by using it to prepare a drug candidate for Duchenne muscular dystrophy. Finally, thionation of the resulting phosphinates was carried out to form P-chirogenic phosphinothioates.
Topics: Stereoisomerism; Molecular Structure; Alcohols; Phosphorus; Esterification
PubMed: 35261188
DOI: 10.1002/open.202100294 -
The Science of the Total Environment Aug 2022Phosphorus (P) is essential for all life on Earth and sustains food production. Yet, the easily accessible deposits of phosphate-rich rock, which underpin the green... (Review)
Review
Phosphorus (P) is essential for all life on Earth and sustains food production. Yet, the easily accessible deposits of phosphate-rich rock, which underpin the green revolution are becoming rarer. Here we propose a mechanism to help alleviate the problem of "peak phosphorus". In the past, wild animals played a large role in returning P from ocean depths back to the continental interiors. In doing so, they collectively retained and redistributed P within the biosphere, supporting a more fertile planet. However, species extinctions and population reductions have reduced animal-mediated P transport >90% over the past 12,000 years. Recently a 5R strategy was developed to Realign P inputs, Reduce P losses, Recycle P in bio-resources, Recover P in wastes, and Redefine P in food systems. Here, we suggest a sixth R, to Revitalize the Natural Phosphorus Pump (RNPP). Countries are starting to mandate P recycling and we propose a P-trading scheme based on REDD+, where a country could partially achieve its recycling goals by restoring past animal-mediated P pathways. Accrued money from this scheme could be used to restore or conserve wild animal populations, while increasing natural P recycling.
Topics: Animals; Conservation of Natural Resources; Earth, Planet; Ecosystem; Extinction, Biological; Food; Phosphorus
PubMed: 35390369
DOI: 10.1016/j.scitotenv.2022.155023 -
Chemosphere Jan 2023Black phosphorus nanosheets (BPNSs) are a new member of the nanomaterial family, and they have good development potential in electrochemistry, electronics,... (Review)
Review
Black phosphorus nanosheets (BPNSs) are a new member of the nanomaterial family, and they have good development potential in electrochemistry, electronics, optoelectronics, environmental protection, biomedical, and other fields because of their bandgap width, high anisotropy, broad optical absorption, high carrier mobility and many other features. Although many articles have been published about the preparation and application of BPNSs, these aspects have not been elucidated, and we aimed to fill this knowledge gap in this review. First, we used VOSviewer software to sort out articles published in the past 5 years and drew a literature map, which allowed us to sort out the relationship between various studies related to BPNSs, and reflect on the research focus in recent years. Because BPNSs must be made from black phosphorus (BP), and BPNSs are a nano form of BP, the collation of the BP preparation scheme was also helpful for the related research on BPNSs. This paper introduces the preparation of bulk BP and BPNSs, analyzes and compares the advantages and disadvantages of each method, and points out the most promising methods in the future. Then, we propose improvement directions for this method. We also introduce the characterization of BPNSs and combine it with the subsequent photocatalytic application of BPNSs. As a new material, the effect of BPNSs on the environment is still unknown; thus, an end treatment scheme for BPNSs is summarized according to existing methods. Based on the experience of nanomaterial treatment, this paper proposes a research focus for the end treatment of BPNSs in the future, providing a reference scheme for the end treatment of other nanomaterials. Finally, we summarize the full text and propose recommended methods and improvement plans.
Topics: Phosphorus; Nanostructures
PubMed: 36347351
DOI: 10.1016/j.chemosphere.2022.137161 -
Current Medicinal Chemistry 2019Ascribe to the unique two-dimensional planar nanostructure with exceptional physical and chemical properties, black phosphorous (BP) as the emerging inorganic... (Review)
Review
Ascribe to the unique two-dimensional planar nanostructure with exceptional physical and chemical properties, black phosphorous (BP) as the emerging inorganic twodimensional nanomaterial with high biocompatibility and degradability has been becoming one of the most promising materials of great potentials in biomedicine. The exfoliated BP sheets possess ultra-high surface area available for valid bio-conjugation and molecular loading for chemotherapy. Utilizing the intrinsic near-infrared optical absorbance, BPbased photothermal therapy in vivo, photodynamic therapy and biomedical imaging has been realized, achieving unprecedented anti-tumor therapeutic efficacy in animal experiments. Additionally, the BP nanosheets can strongly react with oxygen and water, and finally degrade to non-toxic phosphate and phosphonate in the aqueous solution. This manuscript aimed to summarize the preliminary progresses on theranostic application of BP and its derivatives black phosphorus quantum dots (BPQDs), and discussed the prospects and the state-of-art unsolved critical issues of using BP-based material for theranostic applications.
Topics: Animals; Biosensing Techniques; Cell Line, Tumor; Drug Carriers; Humans; Light; Neoplasms; Optical Imaging; Phosphorus; Quantum Dots; Theranostic Nanomedicine
PubMed: 28933294
DOI: 10.2174/0929867324666170920152529 -
Nutrition in Clinical Practice :... Feb 2015Phosphorus (P) and calcium (Ca) serve vital roles in the human body and are essential components of nutrition support therapy. Regulation of P and regulation of Ca in... (Review)
Review
Phosphorus (P) and calcium (Ca) serve vital roles in the human body and are essential components of nutrition support therapy. Regulation of P and regulation of Ca in the body are closely interrelated, and P and Ca homeostasis can be affected by several factors, including disease states, clinical condition, severity of illness, and medications. Nutrition support clinicians must understand these factors to prevent and treat P and Ca disorders in patients receiving nutrition support therapy. This review provides an overview of P and Ca for the adult nutrition support clinician, with some emphasis on the hospitalized inpatient.
Topics: Adult; Calcium; Homeostasis; Humans; Nutritional Support; Phosphorus; Practice Guidelines as Topic
PubMed: 25550328
DOI: 10.1177/0884533614565251 -
Small (Weinheim An Der Bergstrasse,... Feb 2018As a new kind of 2D material, black phosphorus has gained increased attention in the past three years. Although few-layered black phosphorus nanosheets (BPs) degrade... (Review)
Review
As a new kind of 2D material, black phosphorus has gained increased attention in the past three years. Although few-layered black phosphorus nanosheets (BPs) degrade quickly under ambient conditions to phosphate anions, which greatly hampers their optical and electronic applications, this property also makes BPs highly biocompatible and biodegradable, and is regarded as an advantage for various biomedical applications. This Concept summarizes the state-of-art progresses of BPs, from fabrication and surface modification to biomedical applications. It is expected that BPs with such fascinating properties will encourage more scientists to engage in expanding its biomedical applications by tackling the scientific challenges involved in their development.
Topics: Biocompatible Materials; Biomedical Research; Phosphorus
PubMed: 29219239
DOI: 10.1002/smll.201702830 -
BMC Plant Biology Feb 2023Low phosphorus (P) is one of the limiting factors in sustainable cotton production. However, little is known about the performance of contrasting low P tolerant cotton...
Low phosphorus (P) is one of the limiting factors in sustainable cotton production. However, little is known about the performance of contrasting low P tolerant cotton genotypes that might be a possible option to grow in low P condition. In the current study, we characterized the response of two cotton genotypes, Jimian169 a strong low P tolerant, and DES926 a weak low P tolerant genotypes under low and normal P conditions. The results showed that low P greatly inhibited growth, dry matter production, photosynthesis, and enzymatic activities related to antioxidant system and carbohydrate metabolism and the inhibition was more in DES926 as compared to Jimian169. In contrast, low P improved root morphology, carbohydrate accumulation, and P metabolism, especially in Jimian169, whereas the opposite responses were observed for DES926. The strong low P tolerance in Jimian169 is linked with a better root system and enhanced P and carbohydrate metabolism, suggesting that Jimian169 is a model genotype for cotton breeding. Results thus indicate that the Jimian169, compared with DES926, tolerates low P by enhancing carbohydrate metabolism and by inducing the activity of several enzymes related to P metabolism. This apparently causes rapid P turnover and enables the Jimian169 to use P more efficiently. Moreover, the transcript level of the key genes could provide useful information to study the molecular mechanism of low P tolerance in cotton.
Topics: Phosphorus; Plant Breeding; Carbohydrate Metabolism; Photosynthesis; Genotype
PubMed: 36792994
DOI: 10.1186/s12870-023-04100-6