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Environmental Science and Pollution... Oct 2023Among the largest CO emission industries, the cement industry is ranked in 2nd place. A large volume of CO is emitted at the clinker production, which is a cement...
Among the largest CO emission industries, the cement industry is ranked in 2nd place. A large volume of CO is emitted at the clinker production, which is a cement manufacturing intermediate product. Countries around the world were having difficulty reducing atmospheric emissions of greenhouse gases (GHG). Concrete is still being used more and more as the nation's infrastructure advances. The amount of CO emitted by concrete can be decreased by using less cement or substituting other materials for cement. In this study, the CO emission analysis is made on M40 grade, which is that metakaolin (MK) and alccofine (AL) are replaced to the cement in the manufacturing of concrete and is compared with the conventional concrete. The optimum cement replacement of MK and AL is 10% in the production of M40 grade concrete. MK and AL concrete have advantages and disadvantages. If proper safety precautions are taken during the manufacturing process, the toxicity level can be reduced, as well as the amount of CO released by the cement during the production of concrete. The LCA (life cycle analysis) is made for the concrete specimens, and the results were interpreted to know which concrete sample emits less and more carbon dioxide. The LCA study provided insights into the environmental aspects of metakaolin and alccofine concrete, including potential reductions in CO emissions, energy consumption and other environmental indicators. It helps identify areas of improvement and informs decision-making processes regarding sustainable material choices and construction practices. In M40 grade concrete, a 10% cement replacement with metakaolin and alccofine was found to be ideal. These results could also help in identifying the major cause of CO emission, and they can be used for further research purposes.
Topics: Construction Materials; Carbon Dioxide; Greenhouse Gases; Industry
PubMed: 37704814
DOI: 10.1007/s11356-023-29771-4 -
Analytical Chemistry Jul 2023Developing advanced tools for multicomponent analysis is an open challenge in engineering and life science. Herein, multicompartmental hydrogel microspheres with...
Developing advanced tools for multicomponent analysis is an open challenge in engineering and life science. Herein, multicompartmental hydrogel microspheres with multi-material compatibility and structural scalability are developed as a tool for multicomponent analysis at a single-particle level. Microfluidic technology endows particles with adjustable sizes and super-segmented layouts that can be used to load various analyte probes. In order to perform multicomponent analysis, these microspheres are structurally divided into identifier regions for indicating reading direction and analyte regions for detecting target molecules. The multiplex detection ability of these particles is demonstrated in microRNA bioassays with high specificity and sensitivity. The multi-target analysis is performed on a single-particle level, and the bioassay is free of conventional labeling interference. We expect these particles to reach their potential in clinical diagnostics.
Topics: Hydrogels; Microspheres; Microfluidics; MicroRNAs; Biological Assay
PubMed: 37348075
DOI: 10.1021/acs.analchem.3c01305 -
PloS One 2024Currently, the world faces an existential threat of climate change, and every government across the globe is trying to come up with strategies to tackle the severity of...
Currently, the world faces an existential threat of climate change, and every government across the globe is trying to come up with strategies to tackle the severity of climate change in every way possible. To this end, the use of clean energy rather than fossil fuel energy sources is critical, as it can reduce greenhouse gas emissions and pave the way for carbon neutrality. This study examines the impact of the energy cleanability gap on four different climate vulnerabilities, such as ecosystem, food, health, and housing vulnerabilities, considering 47 European and non-European high-income countries. The study considers samples from 2002 to 2019. This study precedes the empirical analysis in the context of a quadratic relationship between the energy cleanability gap and climate vulnerability. The study uses system-generalized methods of the moment as the main technique, while panel quantile regression is a robustness analysis. Fixed effect and random effect models have also been incorporated. The study finds that the energy cleanability gap and all four climate vulnerabilities demonstrate a U-shaped relationship in both European and non-European countries, implying that when the energy cleanability gap increases, climate vulnerability decreases, but after reaching a certain threshold, it starts to increase. Development expenditure is found to be negatively affecting food and health vulnerabilities in European nations, while it increases food vulnerability and decreases health vulnerability in non-European nations. Regarding industrialization's impact on climate vulnerabilities, the study finds opposite effects for the European and non-European economies. On the other hand, for both groups, trade openness decreases climate vulnerabilities. Based on these results, the study recommends speeding up the energy transition process from fossil fuel energy resources towards clean energy resources to obtain carbon neutrality in both European and non-European groups.
Topics: Developed Countries; Ecosystem; Greenhouse Gases; Economic Development; Fossil Fuels; Carbon; Carbon Dioxide; Renewable Energy
PubMed: 38578792
DOI: 10.1371/journal.pone.0297529 -
Environmental Pollution (Barking, Essex... Jan 2024Infectious diseases are a part of everyday life, and acute respiratory diseases are the most common. Many agents carrying out respiratory infections are transmitted as... (Meta-Analysis)
Meta-Analysis Review
Infectious diseases are a part of everyday life, and acute respiratory diseases are the most common. Many agents carrying out respiratory infections are transmitted as bioaerosols through the air, usually, particulate matter containing living organisms. The purpose of the study is to conduct a systematic review and meta-analysis to assess the likelihood that people exposed to bioaerosols may experience severe respiratory diseases. Nine digital databases and bibliographies were assessed for papers conducted between January 1960 and April 2021. A total of 35 health and exposure studies were included from 825 studies for the systematic review, while only 17 contented the meta-inclusion analysis's criteria. This systematic review found higher bacterial bioaerosol concentrations in poultry farms, waste dumpsites, composting plants, and paper industries. The meta-analysis's Standard Mean Difference (SMD) measurement indicates a substantially positive association between bioaerosol exposure and respiratory disease outcomes in targeted populations. The value is 0.955 [95% CI, range 0.673-1.238; p < 0.001]. As per the Risk of Bias (ROB) findings, most of findings (30 out of 35 [85.71%]) were judged to have low ROB. From the random effect probit model, the total relative risk is 1.477 (95% CI, range 0.987-2.211), indicating a higher risk of respiratory diseases from bioaerosol exposure than the control groups. The total risk difference is 0.121 (95% CI, -0.0229 to 0.264), which means intervention groups may have a higher risk of respiratory diseases from continuous bioaerosol exposure than the control groups. The dose-response relationship revealed a strong positive linear coefficient correlation between bacterial & fungal bioaerosol exposure to respiratory health. Based on self-reported outcomes in those studies, The systematic review and meta-analysis stated that bioaerosol exposure had an effect on pulmonary health.
Topics: Humans; Respiratory Aerosols and Droplets; Particulate Matter; Composting; Risk; Respiratory Tract Infections
PubMed: 37984479
DOI: 10.1016/j.envpol.2023.122972 -
Huan Jing Ke Xue= Huanjing Kexue May 2024It is a new approach to identify legal or illegal use of morphine through information on municipal wastewater. However, the sources of morphine in wastewater are...
It is a new approach to identify legal or illegal use of morphine through information on municipal wastewater. However, the sources of morphine in wastewater are complex, and distinguishing the contribution of different sources has become a key issue. A total of 262 influent samples from 61 representative wastewater treatment plants in a typical city were collected from October 2022 to March 2023. The concentrations of morphine, codeine, thebaine, papaverine, noscapine, and monoacetylmorphine were analyzed in wastewater and poppy straws. Combined with the proportion of alkaloids in poppy straws, the source analysis of alkaloids in wastewater was analyzed using the ratio method and positive matrix factorization model (PMF). Only five alkaloids were detected in wastewater, and monoacetylmorphine, a metabolite of heroin, was not detected. The concentrations of morphine and codeine were significantly higher than those of noscapine, papaverine, and thebaine. By constructing the ratios of codeine/(morphine + codeine) and noscapine/(noscapine + codeine), the source of poppy straw could be qualitatively distinguished. The PMF results showed that three sources of morphine for medical use, poppy straw, and codeine contributed 44.9%, 43.7%, and 9.4%, respectively. The different sources varied in these months due to the COVID-19 and influenza A outbreaks, in which the use of drugs containing poppy straws and codeine was the main source, whereas the use of morphine analgesics remained relatively stable. Inventory analysis further demonstrated the reliability of the source contributions from the PMF model, and morphine was not abused in this city.
Topics: Morphine; Wastewater; Papaverine; Thebaine; Noscapine; Reproducibility of Results; Codeine; Morphine Derivatives; Alkaloids; Papaver
PubMed: 38629538
DOI: 10.13227/j.hjkx.202306005 -
Environmental Pollution (Barking, Essex... Mar 2024Biosolids are rich in organic matter and other nutrients that contribute to environmental and agricultural sustainability by improving soil textural and biological...
Biosolids are rich in organic matter and other nutrients that contribute to environmental and agricultural sustainability by improving soil textural and biological properties and enhancing plant growth when applied to agricultural crops. Land application of biosolids encourages resource recovery and circumvents drawbacks associated with landfilling or incineration. However, biosolids contain numerous chemicals at trace levels, and quantitative analysis of such mixtures in this complex matrix is crucial for understanding and managing application risks. There are currently few analytical methods available that are capable of extracting and quantifying a large range of the emerging contaminants found in biosolids. In this study, a simplified, rapid, and robust method of analysis was developed and validated for a high-priority organic contaminant mixture of 44 endocrine disrupting compounds known to occur in biosolids. Analytes consisted of chemicals from many classes with a wide range of physiochemical properties (e.g., log K values from -1.4 to 8.9). The biosolids extraction and cleanup protocol was validated for 42 of the targeted compounds. The UPLC-MS parameters were validated for all 44 organic contaminants targeted for study. From the two batches of biosolids tested using this analytical method, most of the targeted contaminants (86%) were detected with 100% frequency at concentrations ranging from 0.036 to 10,226 μg/kg dw. Performance results highlighted that internal standards alone could not negate biosolids matrix effects; thus, internal standards and the standard addition method were used for residue quantification. This was the first study to detect and quantify 6PPD-q in biosolids, and the first to quantify lidocaine and 11 other chemicals in biosolids using a single analytical method. This method may be expanded for analysis of additional chemicals in biosolids and comparable matrices.
Topics: Biosolids; Environmental Monitoring; Soil Pollutants; Chromatography, Liquid; Tandem Mass Spectrometry; Soil
PubMed: 38346636
DOI: 10.1016/j.envpol.2024.123517 -
Chemosphere Apr 2024Historical pesticide use in agriculture and trace metal accumulation have long term impact on soil, sediment, and water quality. This research quantifies legacy and...
Historical pesticide use in agriculture and trace metal accumulation have long term impact on soil, sediment, and water quality. This research quantifies legacy and current-use pesticides and trace metals, assessing their occurrence and toxicological implications on a watershed scale in the Sogamoso River basin, tributary of the Magdalena River in Colombia. Organochlorine pesticides (22), organophosphates (7), and azole fungicides (5), as well as trace metals cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn) were analyzed in croplands and along the river. Toxic units (TU) and hazard quotients (HQ) were calculated to assess the mixture toxicity. Organochlorines were detected in 84% of soils, 100% of sediments, and 80% of water samples. Organophosphates were found in 100% of soil and sediment samples, as well as in 70% of water samples. Azole fungicides were present in 79% of soils, 60% of sediments, and in 10% of water samples. Total pesticide concentrations ranged from 214.2 to 8497.7 μg/kg in soils, 569.6-12768.2 μg/kg in sediments, and 0.2-4.1 μg/L in water. In addition, the use of partition coefficient (K) and organic carbon fraction (f) allowed the distribution analysis for most of the pesticides in sediments, suspended particulate matter (SPM), and water systems, but not for soils. Concentrations of trace metals Cu, Zn, Pb, and Zn exceeded international quality guidelines for agricultural soils in 16% of the samples. Furthermore, Cu and Zn concentrations exceeded sediment quality guidelines in 50 and 90% of the samples, respectively. These findings demonstrate the broad distribution of complex mixtures of trace metals, legacy organochlorines, and current-use pesticides across the basin, indicating that conventional agriculture is a significant source of diffuse pollution. Sustainable agricultural practices are needed to mitigate adverse impacts on ecosystems and human health.
Topics: Humans; Soil; Metals, Heavy; Pesticides; Ecosystem; Rivers; Fungicides, Industrial; Colombia; Lead; Environmental Monitoring; Trace Elements; Agriculture; Zinc; Azoles; Organophosphates; Geologic Sediments; Risk Assessment; China
PubMed: 38490613
DOI: 10.1016/j.chemosphere.2024.141713 -
Nutrients May 2024Meat and meat products are among the most nutrient-dense food sources in the human diet [...].
Meat and meat products are among the most nutrient-dense food sources in the human diet [...].
Topics: Humans; Nutritive Value; Meat; Meat Products; Diet; Animals
PubMed: 38794684
DOI: 10.3390/nu16101446 -
Environmental Pollution (Barking, Essex... Oct 2023Secondary micro(nano)plastics generated from the degradation of plastics pose a major threat to environmental and human health. Amid the growing research on... (Meta-Analysis)
Meta-Analysis Review
Secondary micro(nano)plastics generated from the degradation of plastics pose a major threat to environmental and human health. Amid the growing research on microplastics to date, the detection of secondary micro(nano)plastics is hampered by inadequate analytical instrumentation in terms of accuracy, validation, and repeatability. Given that, the current review provides a critical evaluation of the research trends in instrumental methods developed so far for the qualitative and quantitative determination of micro(nano)plastics with an emphasis on the evolution, new trends, missing links, and future directions. We conducted a meta-analysis of the growing literature surveying over 800 journal articles published from 2004 to 2022 based on the Web of Science database. The significance of this review is associated with the proposed novel classification framework to identify three main research trends, viz. (i) preliminary investigations, (ii) current progression, and (iii) novel advances in sampling, characterization, and quantification targeting both micro- and nano-sized plastics. Field Flow Fractionation (FFF) and Hydrodynamic Chromatography (HDC) were found to be the latest techniques for sampling and extraction of microplastics. Fluorescent Molecular Rotor (FMR) and Thermal Desorption-Proton Transfer Reaction-Mass Spectrometry (TD-PTR-MS) were recognized as the modern developments in the identification and quantification of polymer units in micro(nano)plastics. Powerful imaging techniques, viz. Digital Holographic Imaging (DHI) and Fluorescence Lifetime Imaging Microscopy (FLIM) offered nanoscale analysis of the surface topography of nanoplastics. Machine learning provided fast and less labor-intensive analytical protocols for accurate classification of plastic types in environmental samples. Although the existing analytical methods are justifiable merely for microplastics, they are not fully standardized for nanoplastics. Future research needs to be more inclined towards secondary nanoplastics for their effective and selective analysis targeting a broad range of environmental and biological matrices.
Topics: Humans; Plastics; Microplastics; Environmental Monitoring; Water Pollutants, Chemical; Mass Spectrometry
PubMed: 37544402
DOI: 10.1016/j.envpol.2023.122320 -
The Science of the Total Environment Mar 2024Current techniques for microplastics (MPs) analysis are diverse. However, most techniques have individual limitations like the detection limit of spatial resolution,...
Current techniques for microplastics (MPs) analysis are diverse. However, most techniques have individual limitations like the detection limit of spatial resolution, susceptibility, high cost, and time-consuming detection. In this study, we proposed a multi-spectroscopy method coupling μ-FTIR and μ-Raman analysis for one-stop MPs detection, in which barium fluoride was used as the substrate alternative to the filter membrane. Compared with commonly used filter membranes (alumina, silver, PTFE and nylon membranes), the barium fluoride substrate showed better spectroscopic detection performance on microscopic observation, broader transmittable wavenumber range for μ-FTIR (750-4000 cm) and μ-Raman (250-4000 cm) detection, thus suitable for the multi-spectroscopy analysis of spiked samples. Further, the real environmental and biological samples (indoor air, bottled water and human exhaled breath) were collected and detected to verify the applicability of the developed multi-spectroscopy method. The results indicated that the average content of detected MPs could be increased by 30.4 ± 29.9 % for indoor air, 17.1 ± 13.2 % for bottled water and 38.4 ± 16.0 % for human exhaled breath, respectively in comparison with widely used μ-Raman detection, which suggested that MPs exposure might be underestimated using single spectroscopy detection. Moreover, the majority of underestimated MPs were colored and smaller sized (<50 μm) MPs, which could pose higher risks to human body. In addition, the proposed method consumed lower sample pre-treatment costs and was environmental-friendly since the barium fluoride substrate could be used repeatedly after being cleaned by organic solvent with reliable results (n = 10, CV = 10 %, ICC = 0.961), which reduced the cost of MPs detection by at least 2.49 times compared with traditional methods using silver membrane.
Topics: Humans; Microplastics; Plastics; Spectroscopy, Fourier Transform Infrared; Drinking Water; Silver; Environmental Monitoring; Water Pollutants, Chemical; Fluorides; Barium Compounds
PubMed: 38301783
DOI: 10.1016/j.scitotenv.2024.170396