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Materials (Basel, Switzerland) Nov 2023The mechanical properties of polyurethane grouting materials were significantly improved when cement, sodium meta-silicate, red mud, slag, and fly ash were added....
The mechanical properties of polyurethane grouting materials were significantly improved when cement, sodium meta-silicate, red mud, slag, and fly ash were added. However, the grouting mechanisms of polyurethane composite materials are not clear. The grouting mechanisms of polyurethane composite materials in asphalt pavement subsidence were investigated. The results of computed tomography analysis show that polyurethane foam is filled with geopolymer hydration products. The results from ground penetrating radar after grouting show that mapping has no significant fluctuation or dislocation effect, which indicates that the grouting effect is strong. The high-density electrometer can also test the pavement subsidence place and distribution. The grouting mechanisms indicate that polyurethane foam acts as the consolidation structure, and the geopolymer filled with the foam pores of polyurethane and geopolymer forms a stable consolidated body. The seriflux includes under-layer seriflux (red mud, slag, water, and polyurethane composite materials) and upper-layer seriflux (polyurethane seriflux), and there exists a weak phase separation phenomenon, in which the separation phase is mainly polyurethane with little red mud-based geopolymer.
PubMed: 37959649
DOI: 10.3390/ma16217052 -
Frontiers in Bioengineering and... 2023Polyurethanes and plastics have become ubiquitous in modern society, finding use in a wide variety of applications such as clothing, automobiles, and shoes. While these...
Polyurethanes and plastics have become ubiquitous in modern society, finding use in a wide variety of applications such as clothing, automobiles, and shoes. While these materials provide numerous benefits to human life, their persistence in the environment has caused ecological imbalances. Therefore, new processes are needed to make these materials more sustainable and re-usable. In 2011, Ludwik Leibler introduced a new class of covalent adaptable network (CAN) polymers called Vitrimers. Vitrimers possess self-repairing properties and are capable of being reprocessed due to dynamic exchange or breaking/recombination of covalent bonds, similar to thermoset materials. This study explores the synthesis of Vitrimers using waste polyurethane or plastics as feedstock. The raw materials were glycolysed to obtain the glycolysate, which was then used as a reagent for the Vitrimers synthesis. The main objective of this study was to achieve the maximum self-repairable rate of the prepared sample. The Taguchi orthogonal analysis was employed to guide the experiments. The optimized experimental conditions for polyurethane glycolysis were determined to be under ethylene glycol and catalyzed by sodium hydroxide at 180°C for 1 h, resulting in the highest hydroxyl concentration in the glycolysate. In the second stage of the experiment, the ratio of hexamethylene diisocyanate (HDI) to solvent was set to 2, HDI trimer to solvent was 2, and PGE/glycolysate was 0.5, with equal amounts of PEG and glycolysate used as the solvent. The reaction was carried out at 80°C for 1 h, achieving a self-repair ability of 47.5% in the prepared sample. The results of this study show that waste polyurethane or plastics can be effectively recycled and transformed into vitrimers with self-repairing properties. The use of glycolysis as a feedstock is a promising method for the sustainable recycling of polyurethane waste. The Taguchi orthogonal analysis is an effective approach for optimizing experimental conditions and improving the reproducibility of the results.
PubMed: 37555078
DOI: 10.3389/fbioe.2023.1209294 -
Journal of Endodontics Aug 2023Shrinkage and lack of interfacial adaptation between endodontic sealers and root canal walls may jeopardize the root canal treatment outcome. This study aimed to...
INTRODUCTION
Shrinkage and lack of interfacial adaptation between endodontic sealers and root canal walls may jeopardize the root canal treatment outcome. This study aimed to evaluate the volume and power of expansion (and the relationship between the two) of three novel root canal sealers (polyurethane expandable sealer [PES], zeolite + PES [ZPES], and elastomeric polyurethane sealer [EPS]) in comparison with an epoxy-resin based sealer (AH Plus) and a calcium silicate-based sealer (EndoSequence BC).
METHODS
This study utilized 36 cylinders (30 plastic graduated cylinders for volume of expansion and 6 steel cylinders for power of expansion) (4 × 10 mm) filled with PES, ZPES, EPS, AH Plus, EndoSequence BC, or water (n = 5/group). The plastic graduated cylinders were inserted inside a customized Linear Swell Meter apparatus to measure the percentage of volumetric expansion. The steel cylinders were placed inside a Linear Swell Meter apparatus mounted onto a universal testing machine to measure the maximum pressure in psi. Specimens were tested for 72 hours for both volume and power of expansion tests. Data were analyzed using Kolmogorov-Smirnov, one-way ANOVA, Post Hoc Tukey, and Pearson correlation tests (P < .05).
RESULTS
The volume of expansion of PES, ZPES, and EPS was significantly higher than in AH Plus and EndoSequence BC (P < .05). For the power of expansion, no significant differences were found between the root-filling materials (P > .05). No correlation was seen between the volume and power of expansion (P > .05).
CONCLUSION
Although polyurethane-based sealers showed a significantly higher volume of expansion compared to AH Plus and EndoSequence BC, their power of expansion did not increase significantly.
Topics: Root Canal Filling Materials; Polyurethanes; Materials Testing; Epoxy Resins; Silicates
PubMed: 37276958
DOI: 10.1016/j.joen.2023.05.019 -
Chinese Medical Sciences Journal =... Dec 2023As the number of patients suffering from cardiovascular diseases and peripheral vascular diseases rises, the constraints of autologous transplantation remain... (Review)
Review
As the number of patients suffering from cardiovascular diseases and peripheral vascular diseases rises, the constraints of autologous transplantation remain unavoidable. As a result, artificial vascular grafts must be developed. Adhesion of proteins, platelets and bacteria on implants can result in stenosis, thrombus formation, and postoperative infection, which can be fatal for an implantation. Polyurethane, as a commonly used biomaterial, has been modified in various ways to deal with the adhesions of proteins, platelets, and bacteria and to stimulate endothelium adhesion. In this review, we briefly summarize the mechanisms behind adhesions, overview the current strategies of surface modifications of polyurethane biomaterials used in vascular grafts, and highlight the challenges that need to be addressed in future studies, aiming to gain a more profound understanding of how to develop artificial polyurethane vascular grafts with an enhanced implantation success rate and reduced side effect.
Topics: Humans; Polyurethanes; Biocompatible Materials; Blood Vessel Prosthesis; Cardiovascular Diseases
PubMed: 37503722
DOI: 10.24920/004178 -
Surgical Innovation Aug 2023Vacuum Assisted Closure (VAC) has changed how physicians treat complex and chronic wounds. For over 20 years, we have studied the mechanism of action of these devices... (Review)
Review
Vacuum Assisted Closure (VAC) has changed how physicians treat complex and chronic wounds. For over 20 years, we have studied the mechanism of action of these devices in both an academic based research laboratory and in an industry-based laboratory.We performed a literature review of the theoretical and pre-clinical published studies from the two labs which related to the biomechanics of open pore reticulated polyurethane interfaces.The VAC device applies a direct mechanical interface to the wound surface. The interaction of the foam under suction with the wound surface causes surface deformation and cell stretch. The suction removes fluid from the tissues. There are increases in angiogenesis with better vessel morphology than standard dressings. The effect is dependent on the pore size of the foam, the pressure of application and the waveform of application. Undoubtedly, patient factors such as age, diabetes and radiation affect the response.Pre-clinical studies can help in the design and optimization of mechanical-based wound healing devices. Current work on the effects of these devices on lymphatics and scarring are areas of active investigation.
Topics: Humans; Negative-Pressure Wound Therapy; Wound Healing; Cicatrix; Suction; Polyurethanes
PubMed: 36446390
DOI: 10.1177/15533506221142690 -
Polymers Dec 2023This paper describes the synthesis of NIPU by using cardanol as starting material. A cardanol formaldehyde oligomer was first prepared through the reaction of cardanol...
This paper describes the synthesis of NIPU by using cardanol as starting material. A cardanol formaldehyde oligomer was first prepared through the reaction of cardanol and formaldehyde, catalyzed by citric acid. The resulting oligomer was then subjected to epoxidation with m-chloroperbenzoic acid to obtain an epoxide compound, which was subsequently used to fix carbon dioxide (CO) and form a cyclic carbonate. Using this cyclic carbonate, along with an amine, cardanol-based isocyanate polyurethane (NIPU) was prepared. Different characterization methods, such as Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), and thermogravimetric analysis (TGA), were used to confirm the synthesis of the four intermediate products and NIPU in the reaction process. This study highlights the promise of bio-based NIPU as a sustainable alternative in a number of applications while offering insightful information on the synthesis and characterization of the material.
PubMed: 38139934
DOI: 10.3390/polym15244683 -
Molecules (Basel, Switzerland) Nov 2023The amplified employment of rigid polyurethane foam (RPUF) has accentuated the importance of its flame-retardant properties in stimulating demand. Thus, a compelling... (Review)
Review
The amplified employment of rigid polyurethane foam (RPUF) has accentuated the importance of its flame-retardant properties in stimulating demand. Thus, a compelling research report is essential to scrutinize the recent progression in the field of the flame retardancy and smoke toxicity reduction of RPUF. This comprehensive analysis delves into the conventional and innovative trends in flame-retardant (FR) systems, comprising reactive-type FRs, additive-type FRs, inorganic nanoparticles, and protective coatings for flame resistance, and summarizes their impacts on the thermal stability, mechanical properties, and smoke toxicity suppression of the resultant foams. Nevertheless, there are still several challenges that require attention, such as the migration of additives, the insufficient interfacial compatibility between flame-retardant polyols or flame retardants and the RPUF matrix, and the complexity of achieving both flame retardancy and mechanical properties simultaneously. Moreover, future research should focus on utilizing functionalized precursors and developing biodegradable RPUF to promote sustainability and to expand the applications of polyurethane foam.
PubMed: 38005271
DOI: 10.3390/molecules28227549 -
Microbial Ecology Dec 2023Plastic waste is a global environmental burden and long-lasting plastic polymers, including ubiquitous and toxic polyurethanes (PUs), rapidly accumulate in the water...
Plastic waste is a global environmental burden and long-lasting plastic polymers, including ubiquitous and toxic polyurethanes (PUs), rapidly accumulate in the water environments. In this study, samples were collected from the three alkaline groundwater occurrences in the geotectonic regions of the Pannonian basin of northern Serbia (Torda and Slankamen Banja) and Inner Dinarides of western Serbia (Mokra Gora) with aim to isolate and identify bacteria with plastic- and lignocellulose-degrading potential, that could be applied to reduce the burden of environmental plastic pollution. The investigated occurrences belong to cold, mildly alkaline (pH: 7.6-7.9) brackish and hyperalkaline (pH: 11.5) fresh groundwaters of the SO - Na + K, Cl - Na + K and OH, Cl - Ca, Na + K genetic type. Full-length 16S rDNA sequencing, using Oxford Nanopore sequencing device, was performed with DNA extracted from colonies obtained by cultivation of all groundwater samples, as well as with DNA extracted directly from one groundwater sample. The most abundant genera belong to Pseudomonas, Acidovorax, Kocuria and Methylotenera. All screened isolates (100%) had the ability to grow on at least 3 of the tested plastic and lignocellulosic substrates, with 53.9% isolates degrading plastic substrate Impranil® DLN-SD (SD), a model compound for PUs degradation. Isolates degrading SD that were identified by partial 16S rDNA sequencing belong to the Stenotrophomonas, Pseudomonas, Paraburkholderia, Aeromonas, Vibrio and Acidovorax genera. Taking into account that plastics, including commonly produced PUs, are widespread in groundwater, identification of PUs-degrading bacteria may have potential applications in bioremediation of groundwater polluted with this polymer.
Topics: Humans; Polyurethanes; Comamonadaceae; DNA, Ribosomal; Groundwater; Pseudomonas; Suppuration
PubMed: 38153543
DOI: 10.1007/s00248-023-02338-z -
Advances in Colloid and Interface... Mar 2024Synthetic polymers, particularly polyurethanes (PUs), have revolutionized bioengineering and biomedical devices due to their customizable mechanical properties and... (Review)
Review
Synthetic polymers, particularly polyurethanes (PUs), have revolutionized bioengineering and biomedical devices due to their customizable mechanical properties and long-term stability. However, the inherent hydrophobic nature of PU surfaces arises common issues such as high friction, strong protein adsorption, and thrombosis, especially in the physiological environment of blood contact. To overcome these issues, researchers have explored various modification techniques to improve the surface biofunctionality of PUs. In this review, we have systematically summarized several typical surface modification methods including surface plasma modification, surface oxidation-induced grafting polymerization, isocyanate-based chemistry coupling, UV-induced surface grafting polymerization, adhesives-assisted attachment strategy, small molecules-bridge grafting, solvent evaporation technique, and hydrogen bonding interaction. Correspondingly, the advantages, limitations, and future prospects of these surface modification methods were discussed. This review provides an important guidance or tool for developing surface functionalized PUs in the fields of bioengineering and medical devices.
PubMed: 38330882
DOI: 10.1016/j.cis.2024.103100 -
The Science of the Total Environment Aug 2023To recycle polyurethane and extend the service life of polyurethane-modified emulsified asphalt, this study developed novel perspectives for a lower carbon-footprint and...
To recycle polyurethane and extend the service life of polyurethane-modified emulsified asphalt, this study developed novel perspectives for a lower carbon-footprint and cleaner preparation of recyclable polyurethane (RWPU) and its modified emulsified asphalt (RPUA-x) by using self-emulsification and dual dynamic bonds. Particle dispersion and zeta potential tests reflected that the emulsions of RWPU and RPUA-x existed excellent dispersion and storage stability. Microscopic and thermal analyses indicated that RWPU possessed dynamic bonds and maintained thermal stability below 250 °C as anticipated. Concurrently, RWPU provided RPUA-x with a strong physical cross-linking network, and a homogeneous phase was observed in RPUA-x after drying. Self-healing and mechanical evaluation results revealed that the regeneration efficiencies of RWPU were 72.3 % (stress) and 100 % (strain), respectively, and the stress-strain healing efficiency of RPUA-x was >73 %. The energy dissipation performance and plastic damage principle of RWPU were investigated using cyclic tensile loading. The multiple self-healing mechanisms of RPUA-x were revealed through microexamination. Furthermore, the viscoelasticity of RPUA-x and variations in flow activation energy were determined based on Arrhenius fitting from dynamic shear rheometer tests. In conclusion, disulfide bonds and hydrogen bonds endow RWPU with remarkable regenerative properties and grant RPUA-x with both asphalt diffusion self-healing and dynamic reversible self-healing capabilities.
PubMed: 37149186
DOI: 10.1016/j.scitotenv.2023.163915