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International Journal of Molecular... Dec 2020This review presents the latest developments in (bio)degradable approaches and functional aliphatic polyesters and polycarbonates prepared by typical ring-opening... (Review)
Review
This review presents the latest developments in (bio)degradable approaches and functional aliphatic polyesters and polycarbonates prepared by typical ring-opening polymerization (ROP) of lactones and trimethylene carbonates. It also considers several recent innovative synthetic methods including radical ring-opening polymerization (RROP), atom transfer radical polyaddition (ATRPA), and simultaneous chain- and step-growth radical polymerization (SCSRP) that produce aliphatic polyesters. With regard to (bio)degradable approaches, we have summarized several representative cleavable linkages that make it possible to obtain cleavable polymers. In the section on functional aliphatic polyesters, we explore the syntheses of specific functional lactones, which can be performed by ring-opening copolymerization of typical lactone/lactide monomers. Last but not the least, in the recent innovative methods section, three interesting synthetic methodologies, RROP, ATRPA, and SCSRP are discussed in detail with regard to their reaction mechanisms and polymer functionalities.
Topics: Biodegradable Plastics; Chemistry Techniques, Synthetic; Polyesters; Polymerization
PubMed: 33339183
DOI: 10.3390/ijms21249581 -
Dental Materials Journal Nov 2022This study investigated transmittance changes during photo-polymerization of composites in real-time. The transmittance changes of one conventional micro-hybrid, three...
This study investigated transmittance changes during photo-polymerization of composites in real-time. The transmittance changes of one conventional micro-hybrid, three conventional nano-hybrid, and four bulk-fill composites were measured before, during, and after photo-polymerization, and the maximum rate of transmittance change was compared with that of polymerization shrinkage. A significant difference in transmittance of composite between before and after photo-polymerization was observed. The transmittance of composites except for one bulk-fill composite increased during photo-polymerization. There was a correlation between the maximum rate of transmittance change and the maximum rate of polymerization shrinkage. The transmittance analysis of composites gives very important information to know for the final aesthetic restoration and allows to evaluate polymerization kinetics.
Topics: Polymerization; Composite Resins; Materials Testing; Esthetics, Dental; Kinetics
PubMed: 35858790
DOI: 10.4012/dmj.2022-009 -
Indian Journal of Dental Research :... 2019The study aimed to compare the effect of different materials, thicknesses, and polymerization methods and cycles, on the surface porosity of acrylic denture base resins.
PURPOSE
The study aimed to compare the effect of different materials, thicknesses, and polymerization methods and cycles, on the surface porosity of acrylic denture base resins.
MATERIALS AND METHODS
Conventional heat-polymerized polymethyl methacrylate (PMMA) and specially designed acrylic resin (Acron MC) were used to make 84 rectangular samples. They were divided into three groups to evaluate and compare the polymerization techniques, curing cycles, and thicknesses of the two denture base materials (28 samples each). Group A contained PMMA samples polymerized using water bath method (control group); Group B contained Acron MC samples polymerized by microwave method, and Group C contained PMMA samples polymerized by microwave method. Each group was further divided based on sample thickness and polymerization cycles. Each sample was scanned for surface porosity and area of each pore was measured using optical microscope. Data was analyzed using ANOVA, Bonferroni, and student t-tests. Unpaired student t-test was performed to compare the means of surface porosity with polymerization cycles and thicknesses among the groups. The power of study was kept at 80%.
RESULTS
Group C showed highest mean % of porosity depending on method of polymerization, different polymerization cycles (short and long) and polymerization cycles within the group. Group B showed the highest mean % of porosity depending on thickness and thickness within the groups.
CONCLUSIONS
Microwavable acrylic resin polymerized by microwave energy exhibited statistically insignificant increase in porosity when compared to conventional heat cured acrylic resin by water bath method. Conventional acrylic resin polymerized by microwave energy exhibited high statistically significant porosity irrespective of sample thickness. There was statistically insignificant increase in porosity depending on sample thickness irrespective of material and method of polymerization.
Topics: Denture Bases; Humans; Materials Testing; Polymerization; Polymethyl Methacrylate; Porosity
PubMed: 31745057
DOI: 10.4103/ijdr.IJDR_170_16 -
Molecules (Basel, Switzerland) Oct 2023Molecularly imprinted polymers (MIPs) have gained significant attention as artificial receptors due to their low cost, mild operating conditions, and excellent... (Review)
Review
Molecularly imprinted polymers (MIPs) have gained significant attention as artificial receptors due to their low cost, mild operating conditions, and excellent selectivity. To optimize the synthesis process and enhance the recognition performance, various support materials for molecular imprinting have been explored as a crucial research direction. Yeast, a biological material, offers advantages such as being green and environmentally friendly, low cost, and easy availability, making it a promising supporting substrate in the molecular imprinting process. We focus on the preparation of different types of MIPs involving yeast and elaborate on the specific roles it plays in each case. Additionally, we discuss the advantages and limitations of yeast in the preparation of MIPs and conclude with the challenges and future development trends of yeast in molecular imprinting research.
Topics: Molecularly Imprinted Polymers; Saccharomyces cerevisiae; Polymers; Polymerization; Molecular Imprinting
PubMed: 37894582
DOI: 10.3390/molecules28207103 -
International Journal of Molecular... May 2022Amidst growing technological advancements, newer denture base materials and polymerization methods have been introduced. During fabrication, certain mechanical... (Review)
Review
Amidst growing technological advancements, newer denture base materials and polymerization methods have been introduced. During fabrication, certain mechanical properties are vital for the clinical longevity of the denture base. This systematic review aimed to explore the effect of newer denture base materials and/or polymerization methods on the mechanical properties of the denture base. An electronic database search of English peer-reviewed published papers was conducted using related keywords from 1 January 2011, up until 31 December 2021. This systematic review was based on guidelines proposed by the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA). The search identified 579 papers. However, the inclusion criteria recognized 22 papers for eligibility. The risk of bias was moderate in all studies except in two where it was observed as low. Heat cure polymethyl methacrylate (PMMA) and compression moulding using a water bath is still a widely used base material and polymerization technique, respectively. However, chemically modified PMMA using monomers, oligomers, copolymers and cross-linking agents may have a promising result. Although chemically modified PMMA resin might enhance the mechanical properties of denture base material, no clear inferences can be drawn about the superiority of any polymerization method other than the conventional compression moulding technique.
Topics: Denture Bases; Materials Testing; Polymerization; Polymers; Polymethyl Methacrylate
PubMed: 35628546
DOI: 10.3390/ijms23105737 -
Brazilian Oral Research Aug 2017This systematic review assessed the literature to evaluate the efficiency of polymerization of bulk-fill composite resins at 4 mm restoration depth. PubMed, Cochrane,... (Review)
Review
This systematic review assessed the literature to evaluate the efficiency of polymerization of bulk-fill composite resins at 4 mm restoration depth. PubMed, Cochrane, Scopus and Web of Science databases were searched with no restrictions on year, publication status, or article's language. Selection criteria included studies that evaluated bulk-fill composite resin when inserted in a minimum thickness of 4 mm, followed by curing according to the manufacturers' instructions; presented sound statistical data; and comparison with a control group and/or a reference measurement of quality of polymerization. The evidence level was evaluated by qualitative scoring system and classified as high-, moderate- and low- evidence level. A total of 534 articles were retrieved in the initial search. After the review process, only 10 full-text articles met the inclusion criteria. Most articles included (80%) were classified as high evidence level. Among several techniques, microhardness was the most frequently method performed by the studies included in this systematic review. Irrespective to the "in vitro" method performed, bulk fill RBCs were partially likely to fulfill the important requirement regarding properly curing in 4 mm of cavity depth measured by depth of cure and / or degree of conversion. In general, low viscosities BFCs performed better regarding polymerization efficiency compared to the high viscosities BFCs.
Topics: Composite Resins; Curing Lights, Dental; Hardness; Materials Testing; Polymerization; Radiation Dosage; Time Factors
PubMed: 28902239
DOI: 10.1590/1807-3107BOR-2017.vol31.0059 -
Molecules (Basel, Switzerland) Oct 2020In recent years, molecularly imprinted polymers (MIPs) have become an excellent solution to the selective and sensitive determination of target molecules in complex... (Review)
Review
In recent years, molecularly imprinted polymers (MIPs) have become an excellent solution to the selective and sensitive determination of target molecules in complex matrices where other similar and relative structural compounds could coexist. Although MIPs show the inherent properties of the polymers, including stability, robustness, and easy/cheap synthesis, some of their characteristics can be enhanced, or new functionalities can be obtained when nanoparticles are incorporated in their polymeric structure. The great variety of nanoparticles available significantly increase the possibility of finding the adequate design of nanostructured MIP for each analytical problem. Moreover, different structures (i.e., monolithic solids or MIPs micro/nanoparticles) can be produced depending on the used synthesis approach. This review aims to summarize and describe the most recent and innovative strategies since 2015, based on the combination of MIPs with nanoparticles. The role of the nanoparticles in the polymerization, as well as in the imprinting and adsorption efficiency, is also discussed through the review.
Topics: Adsorption; Molecular Imprinting; Molecularly Imprinted Polymers; Nanoparticles; Polymerization; Polymers
PubMed: 33076552
DOI: 10.3390/molecules25204740 -
Nature Communications Sep 2022Unbleached wood fibers and nanofibers are environmentally friendly bio-based candidates for material production, in particular, as reinforcements in polymer matrix...
Unbleached wood fibers and nanofibers are environmentally friendly bio-based candidates for material production, in particular, as reinforcements in polymer matrix biocomposites due to their low density and potential as carbon sink during the materials production phase. However, producing high reinforcement content biocomposites with degradable or chemically recyclable matrices is troublesome. Here, we address this issue with a new concept for facile and scalable in-situ polymerization of polyester matrices based on functionally balanced oligomers in pre-formed lignocellulosic networks. The idea enabled us to create high reinforcement biocomposites with well-dispersed mechanically undamaged fibers or nanocellulose. These degradable biocomposites have much higher mechanical properties than analogs in the literature. Reinforcement geometry (fibers at 30 µm or fibrils at 10-1000 nm diameter) influenced the polymerization and degradation of the polyester matrix. Overall, this work opens up new pathways toward environmentally benign materials in the context of a circular bioeconomy.
Topics: Lignin; Polyesters; Polymerization; Polymers
PubMed: 36167843
DOI: 10.1038/s41467-022-33283-z -
Chemistry, An Asian Journal Sep 2022Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters with a wide range of applications; in particular, they currently stand as promising... (Review)
Review
Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters with a wide range of applications; in particular, they currently stand as promising alternatives to conventional polyolefin-based "plastics". The introduction of sulfur atoms within the PHAs backbone can endow the resulting polythioesters (PTEs) with differentiated, sometimes enhanced thermal, optical and mechanical properties, thereby widening their versatility and use. Hence, PTEs have been gaining increasing attention over the past half-decade. This review highlights recent advances towards the synthesis of well-defined PTEs by ring-opening polymerization (ROP) of cyclic thioesters - namely thiolactones - as well as of S-carboxyanhydrides and thionolactones; it also covers the ring-opening copolymerization (ROCOP) of cyclic thioanhydrides or thiolactones with epoxides or episulfides. Most of the ROP reactions described are of anionic type, mediated by inorganic, organic or organometallic initiators/catalysts, along with a few enzymatic reactions as well. Emphasis is placed on the reactivity of the thio monomers, in relation to their ring-size ranging from 4- to 5-, 6- and 7-membered cycles, the nature of the catalyst/initiating systems implemented and their efficiency in terms of activity and control over the PTE molar mass, dispersity, topology, and microstructure.
Topics: Catalysis; Molecular Weight; Polyesters; Polymerization
PubMed: 35816010
DOI: 10.1002/asia.202200641 -
Biomacromolecules Dec 2021Inverse vulcanization is a bulk polymerization method for synthesizing high sulfur content polymers from elemental sulfur, a byproduct of the petrochemical industry,...
Inverse vulcanization is a bulk polymerization method for synthesizing high sulfur content polymers from elemental sulfur, a byproduct of the petrochemical industry, with vinylic comonomers. There is growing interest in polysulfides as novel antimicrobial agents due to the antimicrobial activity of natural polysulfides found in garlic and onions (Tsao et al. , , 665-670). Herein, we report the antibacterial properties of several inverse vulcanized polymers against Gram-positive and Gram-negative , two common causes of nosocomial infection and pathogens identified by the World Health Organization as priorities for antimicrobial development. High sulfur content polymers were synthesized with different divinyl comonomers and at different sulfur/comonomer ratios, to determine the effect of such variables on the antibacterial properties of the resulting materials. Furthermore, polymers were tested for their potential as antibacterial materials at different temperatures. It was found that the test temperature influenced the antibacterial efficacy of the polymers and could be related to the glass transition temperature of the polymer. These findings provide further understanding of the antibacterial properties of inverse vulcanized polymers and show that such polymers have the potential to be used as antibacterial surfaces.
Topics: Anti-Bacterial Agents; Polymerization; Polymers; Staphylococcus aureus; Sulfur
PubMed: 34784205
DOI: 10.1021/acs.biomac.1c01138