-
Journal of Materials Chemistry. A Aug 2017Superhydrophobic surface simultaneously possessing exceptional stretchability, robustness, and non-fluorination is highly desirable in applications ranging from wearable...
Superhydrophobic surface simultaneously possessing exceptional stretchability, robustness, and non-fluorination is highly desirable in applications ranging from wearable devices to artificial skins. While conventional superhydrophobic surfaces typically feature stretchability, robustness, or non-fluorination individually, co-existence of all these features still remains a great challenge. Here we report a multi-performance superhydrophobic surface achieved through incorporating hydrophilic micro-sized particles with pre-stretched silicone elastomer. The commercial silicone elastomer (Ecoflex) endowed the resulting surface with high stretchability; the densely packed micro-sized particles in multi-layers contributed to the preservation of the large surface roughness even under large strains; and the physical encapsulation of the microparticles by silicone elastomer due to the capillary dragging effect and the chemical interaction between the hydrophilic silica and the elastomer gave rise to the robust and non-fluorinated superhydrophobicity. It was demonstrated that the as-prepared fluorine-free surface could preserve the superhydrophobicity under repeated stretching-relaxing cycles. Most importantly, the surface's superhydrophobicity can be well maintained after severe rubbing process, indicating wear-resistance. Our novel superhydrophobic surface integrating multiple key properties, i.e. stretchability, robustness, and non-fluorination, is expected to provide unique advantages for a wide range of applications in biomedicine, energy, and electronics.
PubMed: 29062483
DOI: 10.1039/C6TA11133E -
Journal of Anatomy Sep 2022Biological armors derive their mechanical integrity in part from their geometric architectures, often involving tessellations: individual structural elements tiled...
Biological armors derive their mechanical integrity in part from their geometric architectures, often involving tessellations: individual structural elements tiled together to form surface shells. The carapace of boxfish, for example, is composed of mineralized polygonal plates, called scutes, arranged in a complex geometric pattern and nearly completely encasing the body. In contrast to artificial armors, the boxfish exoskeleton grows with the fish; the relationship between the tessellation and the gross structure of the armor is therefore critical to sustained protection throughout growth. To clarify whether or how the boxfish tessellation is maintained or altered with age, we quantify architectural aspects of the tessellated carapace of the longhorn cowfish Lactoria cornuta through ontogeny (across nearly an order of magnitude in standard length) and in a high-throughput fashion, using high-resolution microCT data and segmentation algorithms to characterize the hundreds of scutes that cover each individual. We show that carapace growth is canalized with little variability across individuals: rather than continually adding scutes to enlarge the carapace surface, the number of scutes is surprisingly constant, with scutes increasing in volume, thickness, and especially width with age. As cowfish and their scutes grow, scutes become comparatively thinner, with the scutes at the edges (weak points in a boxy architecture) being some of the thickest and most reinforced in younger animals and thinning most slowly across ontogeny. In contrast, smaller scutes with more variable curvature were found in the limited areas of more complex topology (e.g., around fin insertions, mouth, and anus). Measurements of Gaussian and mean curvature illustrate that cowfish are essentially tessellated boxes throughout life: predominantly zero curvature surfaces comprised of mostly flat scutes, and with scutes with sharp bends used sparingly to form box edges. Since growth of a curved, tiled surface with a fixed number of tiles would require tile restructuring to accommodate the surface's changing radius of curvature, our results therefore illustrate a previously unappreciated advantage of the odd boxfish morphology: by having predominantly flat surfaces, it is the box-like body form that in fact permits a relatively straightforward growth system of this tessellated architecture (i.e., where material is added to scute edges). Our characterization of the ontogeny and maintenance of the carapace tessellation provides insights into the potentially conflicting mechanical, geometric, and developmental constraints of this species but also perspectives into natural strategies for constructing mutable tiled architectures.
Topics: Animal Shells; Animals; Skin; Tetraodontiformes; X-Ray Microtomography
PubMed: 35638264
DOI: 10.1111/joa.13692 -
Journal of Neurophysiology Jul 2008There is ample evidence from demonstrations such as color induction and stabilized images that information from surface boundaries plays a special role in determining...
There is ample evidence from demonstrations such as color induction and stabilized images that information from surface boundaries plays a special role in determining the perception of surface interiors. Surface interiors appear to "fill-in." Psychophysical experiments also show that surface perception involves a slow scale-dependent process distinct from mechanisms involved in contour perception. The present experiments aimed to test the hypothesis that surface perception is associated with relatively slow scale-dependent neural filling-in. We found that responses in macaque primary visual cortex (V1) are slower to surface interiors than responses to optimal bar stimuli. Moreover, we found that the response to a surface interior is delayed relative to the response to the surface's border and the extent of the delay is proportional to the distance between a receptive field and the border. These findings are consistent with some forms of neural filling-in and suggest that V1 may provide the neural substrate for perceptual filling-in.
Topics: Action Potentials; Analysis of Variance; Animals; Form Perception; Macaca mulatta; Pattern Recognition, Visual; Photic Stimulation; Psychophysics; Reaction Time; Visual Cortex; Visual Fields
PubMed: 18509081
DOI: 10.1152/jn.00997.2007 -
American Journal of Botany Jul 2022Pollination in many aquatic plants takes place on the water surface, and the male flowers or stamens often produce gas bubbles underwater; however, the generation...
PREMISE
Pollination in many aquatic plants takes place on the water surface, and the male flowers or stamens often produce gas bubbles underwater; however, the generation mechanism and function of these bubbles are unknown.
METHODS
A common submerged plant, Hydrilla verticillata, was used as experimental material to observe the structure of male flowers, analyze the process of bubble generation, and simulate the movement process of the male flower with attached gas bubble in water.
RESULTS
The aerenchyma inside the male plants of H. verticillata transported the gas produced by the plant's branches during photosynthesis to the male flower, and the formed gas bubbles became attached to the edge of the perianth. The gas accumulation rate in the attached bubbles increased with light intensity. Once the bubble diameter increased to approximately 3.3 mm, the male flowers with the bubble detached from the plant and floated to the water surface. The removal of the attached bubbles did not affect the male flower detached from the plant; however, the surfacing of male flowers without gas bubbles was easily prevented by the plant's branches in the water, and they could not reach the water surface to complete pollen dispersal.
CONCLUSIONS
The gas bubbles produced by male flowers of H. verticillata came from the gas produced by branches under light. These bubbles can help ascending male flowers bypass the obstacles in water and reach the surface to complete pollination.
Topics: Flowers; Hydrocharitaceae; Plants; Pollen; Pollination; Water
PubMed: 35686633
DOI: 10.1002/ajb2.16022 -
Materials Today. Bio Feb 2023Superhydrophobicity is a well-known wetting phenomenon found in numerous plants and insects. It is achieved by the combination of the surface's chemical properties and...
Superhydrophobicity is a well-known wetting phenomenon found in numerous plants and insects. It is achieved by the combination of the surface's chemical properties and its surface roughness. Inspired by nature, numerous synthetic superhydrophobic surfaces have been developed for various applications. Designated surface coating is one of the fabrication routes to achieve the superhydrophobicity. Yet, many of these coatings, such as fluorine-based formulations, may pose severe health and environmental risks, limiting their applicability. Herein, we present a new family of superhydrophobic coatings comprised of natural saturated fatty acids, which are not only a part of our daily diet, but can be produced from renewable feedstock, providing a safe and sustainable alternative to the existing state-of-the-art. These crystalline coatings are readily fabricated via single-step deposition routes, namely thermal deposition or spray-coating. The fatty acids self-assemble into highly hierarchical crystalline structures exhibiting a water contact angle of ∼165° and contact angle hysteresis lower than 6°, while their properties and morphology depend on the specific fatty acid used as well as on the deposition technique. Moreover, the fatty acid coatings demonstrate excellent thermal stability. Importantly, this new family of coatings displays excellent anti-biofouling and antimicrobial properties against and , used as relevant model Gram-negative and Gram-positive bacteria, respectively. These multifunctional coatings hold immense potential for application in numerous fields, ranging from food safety to biomedicine, offering sustainable and safe solutions.
PubMed: 36569590
DOI: 10.1016/j.mtbio.2022.100516 -
Molecules (Basel, Switzerland) May 2022Particle deposition on the surface of a drying chamber is the main drawback in the spray drying process, reducing product recovery and affecting the quality of the...
Particle deposition on the surface of a drying chamber is the main drawback in the spray drying process, reducing product recovery and affecting the quality of the product. In view of this, the potential application of chemical surface modification to produce a hydrophobic surface that reduces the powder adhesion (biofouling) on the wall of the drying chamber is investigated in this study. A hydrophobic polydimethylsiloxane (PDMS) solution was used in the vertical dipping method at room temperature to determine the optimum coating parameters on borosilicate glass and stainless steel substrates, which were used to mimic the wall surface of the drying chamber, to achieve highly hydrophobic surfaces. A single-factor experiment was used to define the range of the PDMS concentration and treatment duration using the Response Surface Methodology (RSM). The Central Composite Rotatable Design (CCRD) was used to study the effects of the concentration of the PDMS solution (X, %) and the treatment duration (X, h) on the contact angle of the substrates (°), which reflected the hydrophobicity of the surface. A three-dimensional response surface was constructed to examine the influence of the PDMS concentration and treatment duration on contact angle readings, which serve as an indicator of the surface's hydrophobic characteristics. Based on the optimisation study, the PDMS coating for the borosilicate glass achieved an optimum contact angle of 99.33° through the combination of a PDMS concentration of X = 1% (/) and treatment time of X = 4.94 h, while the PDMS coating for the stainless steel substrate achieved an optimum contact angle of 98.31° with a PDMS concentration of X = 1% (/) and treatment time of X = 1 h. Additionally, the infrared spectra identified several new peaks that appeared on the PDMS-treated surfaces, which represented the presence of Si-O-Si, Si-CH, CH, and CH functional groups for the substrates coated with PDMS. Furthermore, the surface morphology analysis using the Field Emission Scanning Electron Microscopy (FESEM) showed the presence of significant roughness and a uniform nanostructure on the surface of the PDMS-treated substrates, which indicates the reduction in wettability and the potential effect of unwanted biofouling on the spray drying chamber. The application of PDMS and PTFE on the optimally coated substrates successfully reduced the amount of full cream milk particles that adhered to the surface. The low surface energy of the treated surface (19-27 mJ/m) and the slightly higher surface tension of the full cream milk (54-59 mJ/m) resulted in a high contact angle (102-103°) and reduced the adhesion work on the treated substrates (41-46 mJ/m) as compared to the native substrates.
Topics: Dimethylpolysiloxanes; Hydrophobic and Hydrophilic Interactions; Stainless Steel; Surface Properties; Wettability
PubMed: 35684326
DOI: 10.3390/molecules27113388 -
Progress in Orthodontics Dec 2016The effects of surface roughness and carboxyl functionalization of multi-walled carbon nanotubes (MWCNTs) mixed with collagen coated onto titanium (Ti) substrates on...
BACKGROUND
The effects of surface roughness and carboxyl functionalization of multi-walled carbon nanotubes (MWCNTs) mixed with collagen coated onto titanium (Ti) substrates on MC3T3-E1 osteoblasts were evaluated.
METHODS
The proliferation, differentiation, and matrix mineralization were investigated using (1) smooth-surfaced Ti discs, (2) Ti discs coated with collagen and MWCNT (Ti-MWCNT), and (3) Ti discs coated with collagen and MWCNT-COOH (Ti-MWCNT-COOH) for applications in orthodontic mini screw implants (MSIs). The coatings were uniform when analyzed using scanning electron microscopy (SEM), and surface roughness was evaluated by surface profilometry that demonstrated similar surface roughness (R a , mean ± SD) in the MWCNT (0.83 ± 0.02 μm) and MWCNT-COOH (0.84 ± 0.01 μm) groups. MTT (3-(4,5-dimethylthiazol-2-Yl)-2,5-diphenyltetrazolium bromide) assay was performed after days 1, 3, and 7 to assess proliferation. Alkaline phosphatase (ALP)-specific activity was assessed after day 7 to quantify differentiation. Alizarin red staining was measured after day 28 to quantify matrix mineralization. All data were analyzed with JMP Pro11 software (SAS, USA) with a statistical significance of p < 0.05.
RESULTS
Surface profilometry demonstrated similar surface roughness (R a , mean ± SD) in the MWCNT (0.83 ± 0.02 μm) and MWCNT-COOH (0.84 ± 0.01 μm) groups. On day 7, ALP assay showed that MWCNT-COOH (mean ± SD 0.98 ± 0.26 U/μg of protein) enhanced cell differentiation when compared to the uncoated group (p = 0.05). Alizarin red staining after 28 days of cell culture revealed that MWCNT-COOH (mean ± SD 1.5 ± 0.2 OD405) increased (p = 0.03) matrix mineralization when compared to the uncoated group (0.9 ± 0.09 OD405).
CONCLUSIONS
This study showed that coatings containing MWCNT-COOH (increased hydrophilic surface chemistry) influence osteoblast proliferation, differentiation, and matrix mineralization and should be further studied for applications in orthodontic MSIs.
Topics: Alkaline Phosphatase; Animals; Anthraquinones; Calcification, Physiologic; Cell Differentiation; Cell Line; Cell Proliferation; Cells, Cultured; Collagen; Materials Testing; Mice; Microscopy, Electron, Scanning; Nanotubes, Carbon; Osteoblasts; Surface Properties; Tetrazolium Salts; Thiazoles; Titanium
PubMed: 27459973
DOI: 10.1186/s40510-016-0136-y -
ACS Omega Aug 2023Carbon nanotubes can be used as ultrafast liquid transporters for water purification and drug delivery applications. In this study, we mathematically model the...
Carbon nanotubes can be used as ultrafast liquid transporters for water purification and drug delivery applications. In this study, we mathematically model the interaction between water clusters and carbon nanotubes using a continuum approach with the Lennard-Jones potential. Since the structure of water clusters depends on the confining material, this paper models the cluster as a cylindrical column of water molecules located inside a carbon nanotube. By assuming the system of two concentric cylinders, we derive analytical expressions for the interaction energy and force, which are used to determine the mechanics and physical parameters that optimize water transport in the nanotubes. Additionally, we adopt Verlet algorithm to investigate the ultrahigh-speed dynamics of water clusters inside carbon nanotubes. For a given carbon nanotube, we find that the cluster's length and the surface's wettability are important factors in controlling the dynamics of water transport. Our findings here demonstrate the possibility of using carbon nanotubes as effective nanopumps in water purification and nanomedical devices.
PubMed: 37546606
DOI: 10.1021/acsomega.3c02632 -
Scientific Reports Jun 2022A continuum mechanics framework is used herein to model the strains induced in a micromechanical structure by surface phenomena such as adsorption. The resulting picture...
A continuum mechanics framework is used herein to model the strains induced in a micromechanical structure by surface phenomena such as adsorption. The resulting picture significantly differs from those of a liquid under surface tension. Considering a solid isotropic elastic material, it is shown that a sphere undergoes a non uniform deformation under surface adsorption. The direction of the surface's displacement is additionally shown to depend on both the material and the sphere's radius. It is also shown that modeling surface effects with an elastic membrane surrounding a Cauchy elastic material, the elastic energy is usually misestimated. The reported results also reveal that the overall response of a mechanical structure to surface adsorption strongly depends, at a given scaling, of the higher-grade elastic behavior of the material.
PubMed: 35739296
DOI: 10.1038/s41598-022-14709-6 -
International Journal of Environmental... Apr 2022With the rapid development and widespread application of wearable inertial sensors in the field of human motion capture, the low-cost and non-invasive accelerometer...
With the rapid development and widespread application of wearable inertial sensors in the field of human motion capture, the low-cost and non-invasive accelerometer (ACC) based measures have been widely used for working postural stability assessment. This study systematically investigated the abilities of ACC-based measures to assess the stability of working postures in terms of the ability to detect the effects of work-related factors and the ability to classify stable and unstable working postures. Thirty young males participated in this study and performed twenty-four load-holding tasks (six working postures × two standing surfaces × two holding loads), and forty-three ACC-based measures were derived from the ACC data obtained by using a 17 inertial sensors-based motion capture system. ANOVAs, t-tests and machine learning (ML) methods were adopted to study the factors’ effects detection ability and the postural stability classification ability. The results show that almost all forty-three ACC-based measures could (p < 0.05) detect the main effects of Working Posture and Load Carriage, and their interaction effects. However, most of them failed in (p ≥ 0.05) detecting Standing Surface’s main or interaction effects. Five measures could detect both main and interaction effects of all the three factors, which are recommended for working postural stability assessment. The performance in postural stability classification based on ML was also good, and the feature set exerted a greater influence on the classification accuracy than sensor configuration (i.e., sensor placement locations). The results show that the pelvis and lower legs are recommended locations overall, in which the pelvis is the first choice. The findings of this study have proved that wearable ACC-based measures could assess the stability of working postures, including the work-related factors’ effects detection ability and stable-unstable working postures classification ability. However, researchers should pay more attention to the measure selection, sensors placement, feature selection and extraction in practical applications.
Topics: Accelerometry; Humans; Male; Postural Balance; Posture; Standing Position; Wearable Electronic Devices
PubMed: 35457561
DOI: 10.3390/ijerph19084695